收稿日期: 2009-04-13
修回日期: 2009-05-14
网络出版日期: 2009-08-10
基金资助
中国石油天然气科技股份有限公司2007重大专项项目(编号:07-02Z-01-01)；国家自然科学基金项目（编号40572085）；教育部新世纪优秀人才支持计划项目（编号：NCET-06-0204）联合资助.
Current Situation and Problems of Simulation Experiment Approach of Hydrocarbon Generation
Received date: 2009-04-13
Revised date: 2009-05-14
Online published: 2009-08-10
王治朝, 米敬奎, 李贤庆, 颉保亮, 李学专 . 生烃模拟实验方法现状与存在问题[J]. 天然气地球科学, 2009 , 20(4) : 592 -597 . DOI: 10.11764/j.issn.1672-1926.2009.04.592
Hydrocarbon generation experiment of organic source rocks is an important technical means in resource assessment and oil and gas source correlation. With technological advances in recent years, the simulation methods of hydrocarbon generation experiment have improved. According to the extent of isolation, hydrocarbon generation experiments could be divided into open system, semi opened system and closed system. Different systems have different advantages and disadvantages. The accuracy of reaction temperature has a great influence on the application of experiment results. The accuracy of reaction temperature is mostly determined by frame of the simulation apparatus during experiment. Hydrocarbon generation experiments for different source rocks in the same system with different pressures have important significances in discussing the influence of temperature and pressure on the hydrocarbon generating ability of source rocks.
［1］Connan J. Time-temperature relation in oil genesis［J］.AAPG Bulletin, 1974, 58: 2516-2521.
［2］Waples D. Time and temperature in petroleum formation : application of Lopatin's method to petroleum exploration［J］.AAPG Bulletin, 1980, 64(7): 916-926.
［3］卢家烂. 干酪根成烃模拟实验及其应用［M］//傅家谟，秦匡宗. 干酪根地球化学.广州：广东科技出版社, 1995:471-519.
［4］ 高岗. 油气生成模拟方法及其石油地质意义［J］.天然气地球科学, 2000, 11(2):25-29. ［5］邹艳荣,帅燕华,孔枫,等. 油气生成过程实验研究的思考与展望［J］.石油实验地质, 2004, 26(4):375-382.
［6］李贤庆,周强,汪为孝,等. 库车坳陷三叠-侏罗纪烃源岩生气特征与生气模式［J］.煤田地质与勘探，2007, 35(6):18-22.
［7］米敬奎,戴金星,张水昌,等. 煤在2种不同体系的生气能力研究［J］.天然气地球科学, 2007, 18(2):245-248.
［8］Eisma E，Jurg J W. Fundamental aspects of the diagenesis of organic matter and the formation of hydrocarbons［C］// Proceedings of 7th world Petroleum Congress. London：Applied Sciece Pub, 1967, 2： 61-72.
［9］Henderson W, Eglinton G, Simmods P， et al. Thermal alteration as a contributory process to the genesis of petroleum［J］.Nature, 1968, 219(5158):1012-1016.
［10］Brooks J D，Smith J W. The diagenesis of plant lipids during the formation of coal, petroleum and natural gas; Ⅱ, Coalification and the formation of oil and gas in the Gippsland Basin［J］.Geochimica et Cosmochimica Acta, 1969, 33(10):1183-1194.
［11］Tissot B P, Welte D H. Petroleum Formation and Occurrence: a New Appoach to Oil and Gas Exploration［M］.Berlin-Heidebery-New York：Springer-Verlag.1978.
［12］Hunt J M. Petroleum geochemistry and geology［M］.San Francisco, Calif., United States,W.H. Freeman and Co., 1979:1-615.
［13］Durand B, Monin J C. Elemental analysis of kerogens[M]//Durand B.Kerogen: Insoluble Organic Matter from Sedimentary Rocks.Paris,France:Technip, 1980:113-142.
［14］ 汪本善,刘德汉,张丽洁,等. 渤海湾盆地黄骅拗陷石油演化特征及人工模拟实验研究［J］.石油学报, 1980, 1(1):43-51.
［15］刘德汉,周中毅,贾蓉芬,等. 碳酸盐生油岩中沥青变质程度和沥青热变质实验［J］.地球化学, 1982 (3):237-243.
［16］傅家谟,徐世平,盛国英,等. 抚顺煤树脂体成烃的初步研究(Ⅱ)［M］//中国科学院地球化学研究所有机地球化学开放研究实验室研究年报.北京：科学出版社，1987:13-22.
［17］刘德汉,傅家谟,戴童谟,等. 煤成气和煤成油产出阶段和特征的初步研究［M］//中国科学院地球化学研究所年报.贵州：贵州人民出版社，1986：185-196.
［18］张惠之,德汉,傅家谟,等. 不同煤岩组分的热解成气实验研究［M］//中国科学院地球化学研究所年报.贵州：贵州人民出版社, 1986：150-152.
［19］Cramer B, Faber E, Gerling P, et al. Reaction kinetics of stable carbon isotope in natural gas-insights from dry, open system pyrolysis experiments［J］.Energy,Fuels, 2001, 15: 517-532.
［20］Berner U, Faber E,Stahl W. Mathematical simulation of the carbon isotopic fraction between huminitic coals and related methane［J］.Chemical Geology, 1992, 94: 315-39.
［21］Berner U, Fabe E, Scheeder G, et al. Primary cracking of algal and landplant kerogens: kinetic models of isotope variations in methane, ethane and propane［J］.Chemical Geology, 1995, 126: 233-245.
［22］刘全有,Krooss B M,金之钧,等. 塔里木盆地煤及其显微组分超高温开放体系热模拟实验气态产物对比研究［J］.天然气地球科学，2008，19(6):748-753.
［23］肖芝华,胡国艺,李志生. 从烃源岩热模拟实验讨论其生烃特征［J］.天然气地球科学, 2008，19(4):544-548.
［24］刘全有,刘文汇,孟仟祥. 塔里木盆地煤岩在不同介质条件下热模拟实验中烷烃系列有机地球化学特征［J］.天然气地球化学，2006，17(3):313-318.
［25］肖芝华，胡国艺，李志生.封闭体系下压力变化对烃源岩产气率的影响［J］.天然气地球科学，2007，18(2):284-288.
［26］刘金钟，唐永春. 用干酪根生烃动力学方法预测甲烷生烃量之一例［J］.科学通报，1998，43(11)：1187-1191.
［27］付少英,彭平安,张文正,等. 鄂尔多斯盆地上古生界煤的生烃动力学研究［J］.中国科学:D辑，2002，32(10):812-818.
［28］Braun R L, Brurnham A K, Reynolds J G, et al. Methamatical model of oil generation, degradation and expulsion［J］.Energy & Fuels, 1990, 4:132-146.
［29］ 刘德汉,付金华,郑聪斌,等. 鄂尔多斯盆地奥陶系海相碳酸盐岩生烃性能与中部长庆气田气源成因研究［J ］.地质学报, 2004，78(4):542-550.
［30］Monthioux M, Landais P, Durand B. Comparison between extractsfrom natural and artificial maturation series of Mahakam deltacoals［J］.Organic Geochemistry, 1986, 10(3): 299-311.
［31］Braun R L, Burnham A K. Mathematical model of oil generation,degradation and expulsion［J］.Energy & Fuels, 1990, 4(1): 132-146.
［32］ McTavish R A. Pressure retardation of vitrinite diagenesis,offshore northwest Europe［J］.Nature, 1978, 271: 648-650.
［33］Connan J, Montel F, Blanc P H, et al. Experimental study of expulsion of HCs from shaley source rocks［J］. Organic.Geochemistry, 1992,19(1):14-15.
［34］郝芳，姜建群，邹华耀,等.超压对有机质热演化的差异抑制作用及层次［J］.中国科学:D辑，2004，34 (5):443-451.
［35］Price L C, Wenger L M. The influence of pressure on petroleum generation and maturation as suggested by aqueous pyrolysis［J］.Organic. Geochemistry, 1992, 19(1): 141-159.
［36］Dalla T M, Mahlmann R F, Ernst W G. Experimental study on the pressure dependence of vitrinite maturation［J］.Geochimica et Cosmochimica Acta, 1997, 61(14): 2921-2928.
/
| 〈 |
|
〉 |
甘公网安备 62010202000678号