天然气地球科学

• 天然气地球化学 • 上一篇    下一篇

Mango轻烃参数在塔里木盆地大宛齐油田中的应用

杨禄1,2,张春明3,李美俊1,2,卞龙4,余兴4   

  1. 1.中国石油大学(北京)油气资源与探测国家重点实验室,北京 102249;
    2.中国石油大学(北京)地球科学学院,北京 102249;
    3.长江大学油气资源与勘探技术教育部重点实验室,湖北 武汉 430100;
    4.中国石油新疆油田分公司,新疆 克拉玛依 834000
  • 收稿日期:2015-11-25 修回日期:2016-03-21 出版日期:2016-08-10 发布日期:2016-08-10
  • 通讯作者: 张春明(1963-),男,湖北红安人,教授,博士生导师,主要从事有机地球化学研究和教学工作. E-mail:zhangcm@126.com.
  • 作者简介:杨禄(1988-),男,山东济宁人,博士研究生,主要从事油藏地球化学研究. E-mail:younglu1988@163.com.
  • 基金资助:
    国家自然科学基金项目(编号:41272158;41172136);油气资源与探测国家重点实验室项目(编号:PRP/indep-2-1302)联合资助.

Application of Mango’s light hydrocarbon parameters in Dawanqi Oilfield,Tarim Basin,China

Yang Lu1,2,Zhang Chun-ming3,Li Mei-jun1,2,Bian Long4,Yu Xing4   

  1. 1.State Key Laboratory of Petroleum Resources and Prospecting,China University of Petroleum,Beijing 102249,China;
    2.College of Geosciences,China University of Petroleum,Beijing 102249,China;
    3.Key Laboratory of Exploration Technologies for Oil and Gas Resources,Ministry of Education,Yangtze University,
    Wuhan 430100,China;4.Xinjiang Oilfield Company,CNPC,Karamay 834000,China
  • Received:2015-11-25 Revised:2016-03-21 Online:2016-08-10 Published:2016-08-10

摘要: 塔里木盆地大宛齐油田的部分原油经受了不同程度的微生物降解作用,其原油的分子组成变化能较好地反映微生物降解作用对Mango轻烃参数的影响。对大宛齐原油轻烃组成分析发现,主体原油的Mango相关轻烃参数均呈现出陆相来源的分布特征,K1值、K2值基本保持一致,原油来源相近;随微生物降解程度的增加,Mango轻烃参数K1值减小、K2值增大,N61/N51值和(N61+N51)/(P2+P3+N2)值整体上也呈现出减小的趋势。在大宛齐主体原油中,DW1区的N61/N2值、P2/P3值较高,DMCYC5/MCYC6值和MCYC5/CYC6值较低;而DW105西区的N61/N2值、P2/P3值则偏低,DMCYC5/MCYC6值和MCYC5/CYC6值却较高,这个区域性的分布特征可能预示大宛齐地区存在来自北部和西部的2股油气的汇入。

关键词: Mango轻烃参数, 塔里木盆地, 大宛齐油田, 微生物降解, 原油

Abstract: Oil samples from Dawanqi Oilfield in the Tarim Basin,NW China,some of which have been biodegraded to different extents,were analyzed in order to investigate the effect of biodegradation on Mango’s light hydrocarbon (LH) parameters.According to the analytical results of Mango’s LH parameters,Dawanqi oils show characteristics of terrigenous organic matter input and belong to the same oil family.With increasing degree of biodegradation,Mango’s LH parameters from Dawanqi crude oils such as the values of K1,N61/N51 and (N61+N51)/(P2+P3+N2) decrease,and K2 values increase.In non-biodegraded oils,DW1 block are characterized by high values of N6 1/N2 and P2/P3,and low values of DMCYC5/MCYC6 and MCYC5/CYC6,while DW105-west block are characterized by low values of N61/N2 and P2/P3,and high values of DMCYC5/MCYC6 and MCYC5/CYC6,which implied that there are at least two oil-charging orientations from the north and west of the study area.

Key words: Mango’s light hydrocarbon parameters, Tarim Basin, Dawanqi Oilfield, Biodegradation, Crude oils

中图分类号: 

  • TE122.1+13

[1]Philippi G T.The deep subsurface temperature controlled origin of the gaseous and gasoline range hydrocarbons of petroleum[J].Geochimica et Cosmochimica Acta,1975,39(10):1353-1373.
[2]Thompson K F M.Light hydrocarbons in subsurface sediments[J].Geochimica et Cosmochimica Acta,1979,43(5):657-672.
[3]Thompson K F M.Classification and thermal history of petroleum based on light hydrocarbons[J].Geochimica et Cosmochimica Acta,1983,47(2):303-316.
[4]Duan Yi,Zhao Yang,Yao Jingli,et al.Research advance and tendency of light hydrocarbon geochemistry[J].Natural Gas Geoscience,2014,25(12):1875-1887.[段毅,赵阳,姚泾利,等.轻烃地球化学研究进展及发展趋势[J].天然气地球科学,2014,25(12):1875-1887.]
[5]Mango F D.An invariance in the isoheptanes of petroleum[J].Science,1987,237(4814):514-517.
[6]Mango F D.The origin of light hydrocarbons in petroleum:A kinetic test of the steady-state catalytic hypothesis[J].Geochimica et Cosmochimica Acta,1990,54:5(5):1315-1323.
[7]Mango F D.The origin of light cycloalkanes in petroleum[J].Geochimica et Cosmochimica Acta,1990,54(1):23-27.
[8]Mango F D.Transition metal catalysis in the generation of petroleum:A genetic anomaly in Ordovician oils[J].Geochimica et Cosmochimica Acta,1992,56(10):3851-3854.
[9]Mango F D.The origin of light hydrocarbons in petroleum:Ring preference in the closure of carbocyclic rings[J].Geochimica et Cosmochimica Acta,1994,58(2):895-901.
[10]Hu Tilin,Ge Baoxiong,Zhang Yigang,et al.The development and application of fingerprint parameters for hydrocarbons absorbed by source rocks and light hydrocarbons in natural gas[J].Petroleum Geology and Experiment,1990,12(4):375-393.[胡惕麟,戈葆雄,张义纲,等.源岩吸附烃和天然气轻烃指纹参数的开发和应用[J].石油实验地质,1990,12(4):375-393.]
[11]Dai Jinxing.Identification of coal formed gas and oil type gas by light hydrocarbons[J].Petroleum Exploration and Development,1993,20(5):26-32.[戴金星.利用轻烃鉴别煤成气和油型气[J].石油勘探与开发,1993,20(5):26-32.]
[12]Halpern H.Development and applications of light-hydrocarbon-based star diagrams[J].AAPG Bulletin,1995,79(6):801-815.
[13]Haven H L T.Applications and limitations of Mango’s light hydrocarbon parameters in petroleum correlation studies[J].Organic Geochemistry,1996,24(10):957-976.
[14]Chung H M,Walters C C,Buck S,et al.Mixed signals of the source and thermal maturity for petroleum accumulations from light hydrocarbons:An example of the Beryl field[J].Organic Geochemistry,1998,29(98):381-396.
[15]Wang Peirong,Zhang Dajiang,Xiao Tingrong,et al.Geochemical characteristics of the light hydrocarbons in Jianghan Basin,China[J].Petroleum Exploration and Development,2005,32(3):45-47.[王培荣,张大江,肖廷荣,等.江汉盆地原油轻烃的地球化学特征[J].石油勘探与开发,2005,32(3):45-47.]
[16]Zhang Chunming.The origin and application of light hydrocarbons in petroleum[J].Journal of Oil and Gas Technology,2005,27(2):146-148.[张春明.石油中轻烃的成因及其应用[J].石油天然气学报,2005,27(2):146-148.]
[17]Zhang Chunming,Li Sitian,Zhao Hongjing,et al.Applications of Mango’s light hydrocarbon parameters to petroleum from Tarim Basin,NW China[J].Applied Geochemistry,2005,20(3):545-551.
[18]Shen Zhongmin,Jiang Min,Liu Sibing,et al.Partition and contrast on genetic type of continental natural gas in the Sichuan Basin[J].Petroleum Geology and Experiment,2010,32(6):560-565.[沈忠民,姜敏,刘四兵,等.四川盆地陆相天然气成因类型划分与对比[J].石油实验地质,2010,32(6):560-565.]
[19]Hu Guoyi,Zhang Shuichang.Characterization of low molecular weight hydrocarbons in Jingbian Gasfield and its application to gas sources identification[J].Energy Exploration and Exploitation,2011,29(6):777-796.
[20]Rubinstein I,Strausz O P,Spyckerelle C,et al.The origin of the oil sand bitumens of Alberta:A chemical and a microbiological simulation study[J].Geochimica et Cosmochimica Acta,1977,41(9):1341-1353.
[21]Connan J.Biodegradation of crude oils in reservoirs[J].Advances in Petroleum Geochemistry,1984,1:299-335.
[22]Bailey N,Jobson A,Rogers M.Bacterial degradation of crude oil:comparison of field and experimental data[J].Chemical Geology,1973,11(3):203-221.
[23]George S C,Boreham C J,Minifie S A,et al.The effect of minor to moderate biodegradation on C5 to C9 hydrocarbons in crude oils[J].Organic Geochemistry,2002,33(12):1293-1317.
[24]Yang Lu,Zhang Chunming,Li Meijun,et al.Influence of slight biodegradation on C7 hydrocarbons in crude oils:A case study of Dawanqi Oilfield in Tarim Basin[J].Geochimica,2015,44(5):485-492.[杨禄,张春明,李美俊,等.轻度微生物降解作用对原油中C7轻烃的影响:以大宛齐油田为例[J].地球化学,2015,44(5):485-492.]
[25]Yang Lu,Zhang Chunming,Li Meijun,et al.The effect of slight to minor biodegradation on C6 to C7 light hydrocarbons in crude oils:A case study from Dawanqi Oilfield in the Tarim Basin,NW China[J].Acta Geochimica,2016,35(2):203-214.
[26]Welte D H,Kratochvil H,Rullktter J,et al.Organic geochemistry of crude oils from the Vienna Basin and an assessment of their origin[J].Chemical Geology,1982,35(1/2):33-68.
[27]Bement W O,Levey R A,Mango F D.The temperature of oil generation as defined with C7 chemistry maturity parameter (2,4-DMP/2,3-DMP ratio)[C]//Grimalt J O,Dorronsoro C.Organic geochemistry:Development and applications in energy,climate,environment and human history.Spain:Donostia-San Sebastian,1995:505-507.
[28]Wang Peirong,Xu Guanjun,Zhang Dajiang,et al.Problems with application of heptane and isoheptane values as light hydrocarbon parameters[J].Petroleum Exploration and Development,2010,37(1):121-128.
[29]Liu Wenhui,Zhang Dianwei,Zheng Jianjing,et al.A preliminary discussion on geochemical dynamic tracing of oil/gas reservoiring process:Taking Dawanqi structure in Kuqa Depression as an example[J].Oil and Gas Geology,2005,26(6):717-723,729.[刘文汇,张殿伟,郑建京,等.地球化学动态示踪油气成藏过程初探—以库车坳陷大宛齐构造为例[J].石油与天然气地质,2005,26(6):717-723,729.]
[30]Feng Songbao,Wang Hongzhi.Geochemical characteristics of natural gas in overpressured large gasfield of Kelasu tectonic belt in Kuqa Depression[J].Natural Gas Geoscience,2013,24(4):784-789.[冯松宝,汪宏志.库车坳陷克拉苏构造带超高压大气田天然气地球化学特征[J].天然气地球科学,2013,24(4):784-789.]
[31]Zhao Mengjun,Song Yan,Liu Shaobo,et al.The diffusion influence on gas pool:Dawanqi oilfield as an example[J].Natural Gas Geoscience,2003,14(5):393-397.[赵孟军,宋岩,柳少波,等.扩散作用对天然气成藏后的影响——以大宛齐油田为例[J].天然气地球科学,2003,14(5):393-397.]
[32]Jiang Zhenxue,Li Lianxia,Song Yan,et al.Control of neotectonic movement on hydrocarbon accumulation in the Kuqa Foreland Basin,west China[J].Petroleum Science,2010,1(1):49-58.
[33]Liang Digang,Zhang Shuichang,Zhao Mengjun,et al.Oil and gas hydrocarbon accumulation period of Kuqa Depression[J].Chinese Science Bulletin,2002,47(supplement 1):56-63.[梁狄刚,张水昌,赵孟军,等.库车拗陷的油气成藏期[J].科学通报,2002,47(增刊1):56-63.]
[34]Xiao Zhongyao,Huang Guanghui,Lu Yuhong,et al.Rearranged hopanes in oils from the Quele 1 Well,Tarim Basin,and the significance for oil correlation[J].Petroleum Exploration and Development,2004,31(2):35-37.[肖中尧,黄光辉,卢玉红,等.库车坳陷却勒1井原油的重排藿烷系列及油源对比[J].石油勘探与开发,2004,31(2):35-37.]
[35]Zhan Zhaowen,Bao Jianping,Zhu Cuishan,et al.Geochemical characteristics and origins of crude oil from Quele-1 reservoir in Kuqa Depression[J].Journal of Oil and Gas Technology,2011,33(5):22-26.[詹兆文,包建平,朱翠山,等.库车坳陷却勒1油藏原油地球化学特征与来源研究[J].石油天然气学报,2011,33(5):22-26.]
[36]Zhuo Qingong,Zhao Mengjun,Xie Huiwen,et al.Relationship between reservoir bitumen and hydrocarbon migration in Dabei region,Kuqa Foreland Basin[J].Petroleum Geology and Experiment,2011,33(2):193-196.[卓勤功,赵孟军,谢会文,等.库车前陆盆地大北地区储层沥青与油气运聚关系[J].石油实验地质,2011,33(2):193-196.]
[37]Zhuo Qingong,Li Yong,Lu Xuesong,et al.Condensate characteristics and its significance for hydrocarbon accumulation in the Kelasu structural belt[J].Natural Gas Geoscience,2012,23(6):1097-1103.[卓勤功,李勇,鲁雪松,等.克拉苏构造带凝析油特征及其对油气成藏的指示意义[J].天然气地球科学,2012,23(6):1097-1103.]
[38]Tissot B P,Welte D H.Petroleum Formation and Occurrence[M].Heicleberg,New York,London:Springer-Verlag,1984.
[39][KG*6/7]Lin Renzi,Zhang Min.Compositional characteristics of light hydrocarbons and their genetic types of crude oils in the Tarim Basin[J].Geological Review,2012,42 (supplement):26-30.[林壬子,张敏.塔里木盆地原油轻烃组成特征和成因类型[J].地质论评,2012,42(增刊):26-30.]
[40]Zhang Chunming,Jin Diwei.Characteristics of light hydrocarbons in Tazhong area and its significance[J].Oil and Gas Geology,1997,18(4),332-334.[张春明,金迪威.塔中地区轻烃特征及其意义[J].石油与天然气地质,1997,18(4):332-334.]
[41]Wang Peirong,Zhu Junzhang,Fang Xiaolin,et al.A new classification of crude oils on light hydrocarbons:The classification and geochemical feature of crude oils from Tarim Basin[J].Acta Petrolei Sinica,1998,19(1):24-28.[王培荣,朱俊章,方孝林,等.一种新的原油轻烃分类法—塔里木盆地原油分类及其地化特征[J].石油学报,1998,19(1):24-28.]
[42]Zhang Min,Zhang Jun.Development and application of Mango’s light hydrocarbon parameters[J].Petroleum Exploration and Development,1998,25(6):26-28.[张敏,张俊.Mango轻烃参数的开发与应用[J].石油勘探与开发,1998,25(6):26-28.]
[43]Zhu Yangming,Zhang Chunming.Application of Mango’s light hydrocarbon parameters in classification of oils from Tarim Basin[J].Geochimica,1999,28(1):26-33.[朱扬明,张春明.Mango轻烃参数在塔里木原油分类中的应用[J].地球化学,1999,28(1):26-33.]
[44]Zhu Junzhang,Bao Jianping,Wang Peirong.Classification on light hydrocarbons and origin of crude oils in Tarim Basin [J].Marine Origin Petroleum Geology,2005,6(1):36-39.[朱俊章,包建平,王培荣.塔里木盆地原油的轻烃分类及成因研究[J].海相油气地质,2005,6(1):36-39.]

[1] 戴金星, 洪峰, 倪云燕, 廖凤蓉. 塔里木盆地英吉苏凹陷煤成气前景良好[J]. 天然气地球科学, 2019, 30(6): 771-782.
[2] 贾爱林, 唐海发, 韩永新, 吕志凯, 刘群明, 张永忠, 孙贺东, 黄伟岗, 王泽龙. 塔里木盆地库车坳陷深层大气田气水分布与开发对策[J]. 天然气地球科学, 2019, 30(6): 908-918.
[3] 陈永权, 严威, 韩长伟, 闫磊, 冉启贵, 亢茜, 何皓, 马源. 塔里木盆地寒武纪/前寒武纪构造—沉积转换及其勘探意义[J]. 天然气地球科学, 2019, 30(1): 39-50.
[4] 王强, 张大勇, 王杰, 陶成, 腾格尔, 刘文汇. 烃类与非烃综合判识干酪根与原油裂解气[J]. 天然气地球科学, 2018, 29(9): 1231-1239.
[5] 李梦茹, 唐友军, 刘岩, 胡辉, 贺其川. 江陵凹陷不同地区原油地球化学特征及油源对比[J]. 天然气地球科学, 2018, 29(9): 1240-1251.
[6] 张荣虎, 王珂, 王俊鹏, 孙雄伟, 李君, 杨学君, 周露. 塔里木盆地库车坳陷克深构造带克深8区块裂缝性低孔砂岩储层地质模型[J]. 天然气地球科学, 2018, 29(9): 1264-1273.
[7] 王清龙, 林畅松, 李浩, 韩剑发, 孙彦达, 何海全. 塔里木盆地西北缘中下奥陶统碳酸盐岩沉积微相特征及演化[J]. 天然气地球科学, 2018, 29(9): 1274-1288.
[8] 朱光有, 曹颖辉, 闫磊, 杨海军, 孙崇浩, 张志遥, 李婷婷, 陈永权. 塔里木盆地8 000m以深超深层海相油气勘探潜力与方向[J]. 天然气地球科学, 2018, 29(6): 755-772.
[9] 周波, 曹颖辉, 齐井顺, 黄世伟, 刘策, 贾进华, 陈秀艳. 塔里木盆地古城地区下奥陶统储层发育机制[J]. 天然气地球科学, 2018, 29(6): 773-783.
[10] 王珊, 曹颖辉, 杜德道, 王石, 李洪辉, 董洪奎, 严威, 白莹. 塔里木盆地柯坪—巴楚地区肖尔布拉克组储层特征与主控因素[J]. 天然气地球科学, 2018, 29(6): 784-795.
[11] 曹颖辉, 李洪辉, 闫磊, 王洪江, 张君龙, 杨敏, 赵一民. 塔里木盆地满西地区寒武系台缘带分段演化特征及其对生储盖组合的影响[J]. 天然气地球科学, 2018, 29(6): 796-806.
[12] 闫磊, 李洪辉, 曹颖辉, 杨敏, 赵一民. 塔里木盆地满西地区寒武系台缘带演化及其分段特征[J]. 天然气地球科学, 2018, 29(6): 807-816.
[13] 杨敏, 赵一民, 闫磊, 李洪辉, 张欣欣, 徐振平, 罗浩渝. 塔里木盆地东秋里塔格构造带构造特征及其油气地质意义[J]. 天然气地球科学, 2018, 29(6): 826-833.
[14] 陈斐然, 张义杰, 朱光有, 张宝收, 卢玉红, 张志遥. 塔里木盆地台盆区深层天然气地球化学特征及成藏演化[J]. 天然气地球科学, 2018, 29(6): 880-891.
[15] 黄少英, 杨文静, 卢玉红, 张科, 赵青, 凡闪. 塔里木盆地天然气地质条件、资源潜力及勘探方向[J]. 天然气地球科学, 2018, 29(10): 1497-1505.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
[1] 邵荣;叶加仁;陈章玉;. 流体包裹体在断陷盆地含油气系统研究中的应用概述[J]. 天然气地球科学, 2000, 11(6): 11 -14 .
[2] 曹华;龚晶晶;汪贵锋;. 超压的成因及其与油气成藏的关系[J]. 天然气地球科学, 2006, 17(3): 422 -425 .
[3] 李在光;杨占龙;李琳;郭精义;黄云峰;吴青鹏;李红哲;. 胜北地区油气分布规律[J]. 天然气地球科学, 2006, 17(1): 94 -96 .
[4] 王杰,刘文汇,秦建中,张隽. 中国东部幔源气藏存在的现实性与聚集成藏的规律性[J]. 天然气地球科学, 2007, 18(1): 19 -26 .
[5] 杜乐天. 国外天然气地球科学研究成果介绍与分析-----以索科洛夫的著作为主线[J]. 天然气地球科学, 2007, 18(1): 1 -18 .
[6] 尹太举,张昌民,王寿平,李中超 . 濮53块开发概念模拟[J]. 天然气地球科学, 2006, 17(2): 201 -205 .
[7] 朱光有;. “低熟气、生物气富集规律与资源评价技术”项目成果及学术交流会在合肥召开[J]. 天然气地球科学, 2006, 17(3): 299 .
[8] 赵孟军;宋岩;柳少波;秦胜飞;洪峰;傅国友;达江;. 中国中西部前陆盆地成藏特征的初步分析[J]. 天然气地球科学, 2006, 17(4): 445 -451 .
[9] 姚亚明;周继军;何明喜;付代国;陈建军;. 对焉耆盆地油气地质条件的认识[J]. 天然气地球科学, 2006, 17(4): 463 -467 .
[10] 江文荣;李允;蔡东升;. 秦皇岛27/33区块三维地震精细解释及储层预测[J]. 天然气地球科学, 2006, 17(4): 502 -509 .