贾智彬, 侯读杰, 孙德强, 姜玉涵, 张自鸣, 洪梅 . 贵州地区牛蹄塘组底部烃源岩地球化学特征[J]. 天然气地球科学, 2018 , 29(7) : 1031 -1041 . DOI: 10.11764/j.issn.1672-1926.2018.05.008

［1］Chen Xianpei,Gao Jiyuan,Chen Duofu,et al.The concept of hydrothermal sedimentation and its petrological criteria[J].Acta Sedimentologica Sinica,1992,10(3):124-132.
陈先沛,高计元,陈多福,等.热水沉积作用的概念和几个岩石学标志[J].沉积学报,1992,10(3):124-132.
[2]Zhong Dakang,Jiang Zhenchang,Guo Qiang,et al.A review about research history,situation and prospects of hydrothermal sedimentation[J].Journal of Palaeogeography,2015,17(3):285-296.
钟大康,姜振昌,郭强,等.热水沉积作用的研究历史、现状及展望[J].古地理学报,2015,17(3):285-296.
[3]Jia Zhibin,Hou Dujie,Sun Deqiang,et al.Hydrothermal sedimentary discrimination criteria and its coupling relationship with the source rocks[J].Natural Gas Geoscience,2016,27(6):1025-1034.
贾智彬,侯读杰,孙德强,等.热水沉积判别标志及与烃源岩的耦合关系[J].天然气地球科学,2016,27(6):1025-1034.
[4]Taylor S R,McLennan S M,Armstrong R L.The composition and evolution of the continental crust:rare earth element evidence from sedimentary rocks[J].Philosophical Transactions of the Royal Society of London,1981,301(1461):381-399.
[5]Liu Yingjun,Cao Liming,Li Zhaolin,et al.Elemental Geochemistry[M].Beijing:Science Press,1984.
刘英俊，曹励明，李兆麟，等.元素地球化学[M].北京：科学出版社，1984.
[6]Gan Yuan,Yu Linsong,He Mingyou,et al.REE geochemistry of claystone at the Permian- Triassic boundary in the Jiangyou- Guangyuanarea,northern Sichuan,China and its geological implications[J].Geological Bulletin of China,2008,27(3):380- 387.
甘媛，于林松，何明友，等.川北江油—广元一带二叠系—三叠系界线粘土岩稀土元素地球化学特征及其地质意义[J].地质通报，2008，27(3)：380-387.
[7]Wu Mengshuang,Shao Lei,Pang Xiong,et al.REE geochemical characteristics of sediments and its inplications in the deepwater area of the northern South China Sea[J].Acta Sedimentologica Sinica,2012，30(4):672-678.
吴梦霜，邵磊，庞雄，等.南海北部深水区沉积物稀土元素特征及其物源指示意义[J].沉积学报,2012，30(4)：672-678.
[8]Li Juan,Yu Bingsong,Guo Feng.Depositional setting and tectonic background analysis on Lower Cambrian black shales in the north of Guizhou Province[J].Acta Sedimentologica Sinica,2013,31(1):20-31.
李娟,于炳松,郭峰.黔北地区下寒武统底部黑色页岩沉积环境条件与源区构造背景分析[J].沉积学报,2013,31(1):20-31.
[9]Mou Baolei.Elemental Geochemistry[M].Beijing:Science Press,1999.
牟宝磊.元素地球化学[M].北京：科学出版社，1999.
[10]Murray R W,Buchholtz ten Brink M R,Jones D L,et al.Rare earth,major,and trace elements in chert from the Franciscan Complex and Monterey Group,California:Assessing REE sources to fine-grained marine sediments[J].Geochimica et Cosmochimica Acta,1991,55(7):1875-1895.
[11]Hein J R,Kuijpers E P,Denyer P,et al.Petrology and geochemistry of Cretaceous and Paleogene cherts from western Costa Rica[J].Developments in Sedimentology,1983,36(8):143-174.
[12]Klinkhammer G,Elderfield H,Hudson A.Rare earth elements in seawater near hydrothermal vents[J].Nature,1983,305(5931):185-188.
[13]Adachi M,Yamamoto K,Sugisaki R.Hydrothermal chert and associated siliceous rocks from the northern Pacific their geological significance as indication od ocean ridge activity[J].Sedimentary Geology,1986,47(1):125-148.
[14]Michard A,Albarède F.The REE content of some hydrothermal fluids[J].Chemical Geology,1986,55(1):51-60.
[15]Yamamoto K.Geochemical characteristics and depositional environments of cherts and associated rocks in the Franciscan and Shimanto Terranes[J].Sedimentary Geology,1987,52(1):65-108.
[16]Crocket J H.Noble metals in seafloor hydrothermal mineralization from the Juan de Fuca and mid-Atlantic ridges:A fractionation of gold from platinum metals in hydrothermal fluids[J].Can Mineral,1990,28:639-648.
[17]Barrett T J.Mass changes in the Galapagos hydrothermal mounds:Near-axis sediment transformation and mineralization[J].Geology,1992,20(12):1075-1078.
[18]Larson P B,Cunningham C G,Naeser C W.Large-scale alteration effects in the Rico paleothermal anomaly,southwest Colorado[J].Economic Geology,1994,89(8):1769-1779.
[19]Fouquet Y.Where are the large hydrothermal sulphide deposits in the oceans?[J].Philosophical Transactions of the Royal Society of London A:Mathematical,Physical and Engineering Sciences,1997,355(1723):427-441.
[20]Zhou Yongzhang,Liu Jianming,Chen Duofu.Thread and knowledge to fossil sea-floor hydrothermal sedimentation of South China[J].Bulletin of Mineralogy Petrology and Geochemistry,2000,19(2):114-118.
周永章,刘建明,陈多福.华南古海洋热水沉积作用研究概述及若干认识[J].矿物岩石地球化学通报,2000,19(2):114-118.
[21]Xue Chunji,Qi Sijing,Zheng Minghua,et al.Hydrothermal sediment research and associated scientific problems [J].Bulletin of Mineralogy Petrology and Geochemisty,2000,19(3):155-163.
薛春纪,祁思敬,郑明华,等.热水沉积研究及相关科学问题[J].矿物岩石地球化学通报,2000,19(3):155-163.
[22]Konn C,Charlou J L,Donval J P,et al.Hydrocarbons and oxidized organic compounds in hydrothermal fluids from Rainbow and Lost City ultramafic-hosted vents[J].Chemical Geology,2009,258(3):299-314.
[23]Zhang Wenzheng,Yang Hua,Xie Liqin,et al.Lake-bottom hydrothermal activities and their influence on high-quality source rock development:A case from Chang 7 source rocks in Ordos Basin[J].Petroleum Exploration and Development,2010,37(4):424-429.
[24]Peng Xiaotong,Li Jiwei,Zhou Huaiyang,et al.Characteristics and source of inorganic and organic compounds in the sediments from two hydrothermal fields of the central Indian and mid-atlantic Ridges[J].Journal of Asian Earth Sciences,2011,41(3):355-368.
[25]Rushdi A I,Simoneit B R T.Hydrothermal alteration of sedimentary organic matter in the presence and absence of hydrogen to tar then oil[J].Fuel,2011,90(5):1703-1716.
[26]Chen Hui,Xie Xinong,Hu Chaoyong,et al.Geochemical characteristics of Late Permian sediments in the Dalong Formation of the Shangsi section,northwest Sichuan Basin in South China:Implications for organic carbon-rich siliceous rocks formation[J].Journal of Geochemical Exploration,2012,112(1):35-53.
[27]Ventura G T,Simoneit B R T,Nelson R K,et al.The composition,origin and fate of complex mixtures in the maltene fractions of hydrothermal petroleum assessed by comprehensive two-dimensional gas chromatography[J].Organic Geochemistry,2012,45(45):48-65.
[28]Kawagucci S,Ueno Y,Takai K,et al.Geochemical origin of hydrothermal fluid methane in sediment-associated fields and its relevance to the geographical distribution of whole hydrothermal circulation[J].Chemical Geology,2013,339(2):213-225.
[29]Pasini V,Brunelli D,Dumas P,et al.Low temperature hydrothermal oil and associated biological precursors in serpentinites from Mid-Ocean Ridge[J].Lithos,2013,178(9):84-95.
[30]Nomura S F,Sawakuchi A O,Bello R M S,et al.Paleotemperatures and paleofluids recorded in fluid inclusions from calcite veins from the northern flank of the Ponta Grossa dyke swarm:Implications for hydrocarbon generation and migration in the Paraná Basin[J].Marine and Petroleum Geology,2014,52(2):107-124.
[31]Zhang Aiyun,Wu Damao,Guo Lina,et al.The Geochemistry of Marine Black Shale Formation and its Metallogenic Significance[M].Beijing:Science Press,1987.
张爱云,伍大茂,郭丽娜,等.海相黑色页岩建造地球化学与成矿意义[M].北京:科学出版社,1987.
[32]Steiner M,Wallis E,Erdtmann B D,et al.Submarine-hydrothermal exhalative ore layers in black shales from South China and associated fossils-insights into a Lower Cambrian facies and bio-evolution[J].Palaeogeography,Palaeoclimatology,Palaeoecology,2001,169(3):165-191.
[33]Feng Hongzhen,Ling Hongfei,Jiang Shaoyong,et al.δ13C carb and Ceanom excursions in the post-glacial Neoproterozoic and Early Cambrian interval in Guizhou,South China[J].Progress in Natural Science,2004,14(2):188-192.
[34]Pan Jiayong,Ma Dongsheng,Cao Shuanglin.Trace element geochemistry of the Lower Cambrian black rock series from northwestern Hunan,South China[J].Progress in Natural Science,2004,14(1):64-70.
[35]Jiang Shaoyong,Yang Jinghong,Ling Hongfei,et al.Re-Os isotopes and PGE geochemistry of black shales and intercalated Ni-Mo polymetallic sulfide bed from the Lower Cambrian Niutitang Formation,South China[J].Progress in Natural Science,2003,13(10):788-794.
[36]Jiang Shaoyong,Chen Yongquan,Ling Hongfei,et al.Trace-and rare-earth element geochemistry and Pb-Pb dating of black shales and intercalated Ni-Mo-PGE-Au sulfide ores in Lower Cambrian strata,Yangtze Platform,South China[J].Mineralium Deposita,2006,41(5):453-467.
[37]Guo Q J,Shields G A,Liu C Q,et al.Trace element chemostratigraphy of two Ediacaran-Cambrian successions in South China:Implications for organosedimentary metal enrichment and silicification in the Early Cambrian[J].Palaeogeography,Palaeoclimatology,Palaeoecology,2007,254(1-2):194-216.
[38]Fan H F,Wen H J,Zhu X K,et al.Hydrothermal activity during Ediacaran-Cambrian transition:Silicon isotopic evidence[J].Precambrian Research,2013,224(224):23-35.
[39]Wang S F,Zou C N,Dong D H,et al.Multiple controls on the paleoenvironment of the Early Cambrian marine black shales in the Sichuan Basin,SW China:Geochemical and organic carbon isotopic evidence[J].Marine and Petroleum Geology,2015,66(3):660-672.
[40]Guo Q J,Deng Y A,Hippler D,et al.REE and trace element patterns from organic-rich rocks of the Ediacaran-Cambrian transitional interval[J].Gondwana Research,2016,36(36):94-106.
[41]Yin L M,Borjigin T,Knoll A H,et al.Sheet-like microfossils from hydrothermally influenced basinal cherts of the lower Cambrian (Terreneuvian) Niutitang Formation,Guizhou,South China[J].Palaeoworld,2016,26(1):45-54.
[42]Zhang J P,Fan T L,Algeo T J,et al.Paleo-marine environments of the early Cambrian Yangtze platform[J].Palaeogeography,Palaeoclimatology,Palaeoecology,2016,443:66-79.
[43]Fu Y,Wu C D,Guan P,et al.Geochemistry of platinum group and rare earth elements of the Polymetallic Layer in the Lower Cambrian,Weng’an,Guizhou province[J].Acta Geologica Sinica:English Edition,2009,83(3):618-627.
[44]Pi D H,Liu C Q,Shields-Zhou G A,et al.Trace and rare earth element geochemistry of black shale and kerogen in the Early Cambrian Niutitang Formation in Guizhou Province,South China:Constraints for redox environments and origin of metal enrichments[J].Precambrian Research,2013,225(1):218-229.
[45]Han S C,Hu K,Cao J,et al.Origin of early Cambrian black-shale-hosted barite deposits in South China:Mineralogical and geochemical studies[J].Journal of Asian Earth Sciences,2015,106:79-94.
[46]Fan H F,Wen H J,Zhu X K.Marine redox conditions in the Early Cambrian ocean:Insights from the Lower Cambrian phosphorite deposits,South China[J].Journal of Earth Science,2016,27(2):282-296.
[47]Han T,Fan H F,Zhu X Q,et al.Submarine hydrothermal contribution for the extreme element accumulation during the Early Cambrian,South China[J].Ore Geology Reviews,2017,86:297-308.
[48]Yang R D,Wei H R,Bao M,et al.Discovery of hydrothermal venting community at the base of Cambrian barite in Guizhou Province,Western China:Implication for the Cambrian biological explosion[J].Progress in Natural Science,2008,18(1):65-70.
[49]Zhu B,Jiang S Y,Yang J H,et al.Rare earth element and Sr Nd isotope geochemistry of phosphate nodules from the Lower Cambrian Niutitang Formation,NW Hunan Province,South China[J].Palaeogeography,Palaeoclimatology,Palaeoecology,2014,398(3):132-143.
[50]Li Y F,Fan T L,Zhang J C,et al.Geochemical changes in the Early Cambrian interval of the Yangtze platform,South China:Implications for hydrothermal influences and paleocean redox conditions[J].Journal of Asian Earth Sciences,2015,109:100-123.
[51]Och L M,Cremonese L,Shields-Zhou G A,et al.Palaeoceanographic controls on spatial redox distribution over the Yangtzeplatform during the Ediacaran-Cambrian transition[J].Sedimentology,2015,63(2):378-410.
[52]Luo Chao.Geological Characteristics of Gas Shale in the Lower Cambrian Niutitang Formation of the Upper Yangtze Platform[D].Chengdu:Chengdu University of Technology,2014:65-91.
罗超.上扬子地区下寒武统牛蹄塘组页岩特征研究[D].成都:成都理工大学,2014:65-91.
[53]Wu Chengquan,Zhang Zhengwei,Li Yujiao,et al.Geochemistry and genesis of the Shuidong Mo-Ni polymetallic deposit,Nayong,Guizhou[J].Bulletin of Mineralogy,Petrology and Geochemistry,2013,32(6):759-768.
吴承泉,张正伟,李玉娇,等.贵州省纳雍县水东钼镍多金属矿床地球化学及成因研究[J].矿物岩石地球化学通报,2013,32(6):759-768.
[54]Li Shengrong,Gao Zhenmin.REE characteristics of black rock series of the Lower Cambrian Niutitang Formation in Hunan-Guizhou Provinces,China,with a discussion on the REE patterns in marine hydrothermal sediments[J].Acta Mineralogica Sinica,1995,15(2):225-229.
李胜荣,高振敏.湘黔地区牛蹄塘组黑色岩系稀土特征——兼论海相热水沉积岩稀土模式[J].矿物学报,1995,15(2):225-229.
[55]Coryell C D,Chase J W,Winchester J W.A procedure for geochemical interpretation of terrestrial rare-earth abundance patterns[J].Journal of Geophysical Research,1963,68(2):559-566.
[56]Wilde P,Quinby-Hunt M S,Erdtmann B D.The whole-rock cerium anomaly:A potential indicator of eustatic sea-level changes in shales of the anoxic facies[J].Sedimentary Geology,1996,101(1/2):43-53.
[57]Steiner M,Wallis E,Erdtmann B D,et al.Submarine-hydrothermal exhalative ore layers in black shales from South China and associated fossils-insights into a Lower Cambrian facies and bio-evolution[J].Palaeogeography,palaeoclimatology,palaeoecology,2001,169(3):165-191.
[58]Shimizu H,Masuda A.Cerium in chert as an indication of marine environment of its formation[J].Nature,1977,266(5600):346-348.
[59]Rona P A.Criteria for recognition of hydrothermal mineral deposits in oceanic crust[J].Economic Geology,1978,73(2):135-160.
[60]Marchig V,Gundlach H,Mller P,et al.Some geochemical indicators for discrimination between diagenetic and hydrothermal metalliferous sediments[J].Marine Geology,1982,50(3):241-256.
[61]Murray R W,Buchholtz Ten Brink M R,Jones D L,et al.Rare earth elements as indicators of different marine depositional environments in chert and shale[J].Geology,1990,18(3):268-271.
[62]Liu Jiajun,Zheng Minghua.Geochemistry of hydrothermal sedimentary silicalite[J].Acta Geologica Sichuan,1993,13(2):110-118.
刘家军,郑明华.热水沉积硅岩的地球化学[J].四川地质学报,1993,13(2):110-118.
[63]Mills R A,Elderfield H.Rare earth element geochemistry of hydrothermal deposits from the active TAG Mound,26N Mid-Atlantic Ridge[J].Geochimica et Cosmochimica Acta,1995,59(17):3511-3524.
[64]Grenne T,Slack J F.Paleozoic and Mesozoic silica-rich seawater:Evidence from hematitic chert (jasper) deposits[J].Geology,2003,31(4):319-322.
[65]Sugisaki R,Yamamoto K,Adachi M.Triassic bedded cherts in central Japan are not pelagic[J].Nature,1982,298(5875):644-647.
[66]Tang Haoshu,Chen Yanjing,Wu Guang,et al.Rare earth element geochemistry of carbonates of Dashiqiao Formation,Liaohe Group,eastern Liaoning province:Implications for Lomagundi Event[J].Acta Petrologica Sinica,2006,25(11):3075-3093.
汤好书,陈衍景,武广,等.辽东辽河群大石桥组碳酸盐岩稀土元素地球化学及其对Lomagundi事件的指示[J].岩石学报,2009,25(11):3075-3093.
[67]Webb G E,Kamber B S.Rare earth elements in Holocene reefal microbialites:Anew shallow seawater proxy[J].Geochim Cosmochim Acta,2000,64(9):1557-1565.
[68]German C R,Elderfield H.Rare earth elements in the NW Indian Ocean[J].Geochimica et Cosmochimica Acta,1990,54(7):1929-1940.
[69]Schijf J,De Baar H J,Wijbrans J R,et al.Dissolved rare earth elements in the Black Sea[J].Deep Sea Research Part A Oceanographic Research Papers,1991,38(1):S805-S823.
[70]Sverjensky D A.Europium redox equilibria in aqueous solution[J].Earth and Planetary Science Letters,1984,67(1):70-78.
[71]Calvert S E,Pedersen T F.Geochemistry of recent oxic and anoxic marine sediments:implications for the geological record[J].Marine geology,1993,113(1/2):67-88.