陈双，黄海平,张博原，谢增业 . 原油及源内残余沥青裂解成气差异及地质意义[J]. 天然气地球科学, 2017 , 28(9) : 1375 -1384 . DOI: 10.11764/j.issn.1672-1926.2017.07.005

［1］Tissot B P，Welte D H.Petroleum Formation and Occurrence[M].Springer Verlag，1984:330-381.
[2]Hill R J，Tang Y，Kaplan I R.Insights into oil cracking based on laboratory experiments[J].Organic Geochemistry，2003，34(12)：1651-1672.
[3]Horsfield B，Schenk H J，Mills N，et al.Closed-system programmed-temperature pyrolysis for simulating the conversion of oil to gas in a deep petroleum reservoir[J].Organic Geochemistry，1992，19(1-3)191-204.
[4]Wang Xiaotao，Wang Tongshan，Li Yongxin，et al.Experimental study on the effects of reservoir medium on oil cracking to gas[J].Geochimica，2015，44(2)：178-188.[王晓涛，王铜山，李永新，等.储层介质环境对原油裂解生气影响的实验研究[J].地球化学，2015，44(2):178-188.]
[5]He Kun，Zhang Shuichang，Mi Jingkui.Research on the kinetics and controlling factors for oil cracking[J].Natural Gas Geoscience，2011，22(2)：211-218.[何坤，张水昌，米敬奎.原油裂解的动力学及控制因素研究[J].天然气地球科学，2011，22(2)：211-218.]
[6]He Kun，Zhang Shuichang，Wang Xiaomei，et al.Effect of gas generation from in-situ cracking of residual bitumen in source on hydrocarbon generation from organic matter[J].Acta Petrolei Sinica，2013，34(supplement 1)：57-64.[何坤，张水昌，王晓梅，等.源内残留沥青原位裂解生气对有机质生烃的影响[J].石油学报，2013，34(增刊1)：57-64.]
[7]Tian Hui，Xiao Xianming，Li Xianqing，et al.comparison of gas generation and carbon isotope fractionation of methane from marine kerogen- and crude oil-cracking gases[J].Geochimica，2007，36(1)：71-77.[田辉，肖贤明，李贤庆，等.海相干酪根与原油裂解气甲烷生成及碳同位素分馏的差异研究[J].地球化学，2007，36(1)：71-77.]
[8]Liu Wenhui，Wang Jie，Tenger，et al.Stable carbon isotopes of gaseous alkanes as genetic indicators in ferred from laboratory pyrolysis experiments of various marine hydrocarbon source materials from southern China[J].Science China:Earth Science，2012，55：966-974.[刘文汇，王杰，腾格尔，等.南方海相不同类型烃源生烃模拟气态烃碳同位素变化规律及成因判识指标[J].中国科学：地球科学，2012，42(7)：973-982.]
[9]Tian H，Xiao X，Wilkins R W T，et al.An experimental comparison of gas generation from three oil fractions：Implications for the chemical and stable carbon isotopic signatures of oil cracking gas[J].Organic Geochemistry，2012，46(191)：96-112.
[10]Sun Mengmeng，Mi Jingkui，Feng Zihui，et al.Comparison of the characteristics of hydrocarbons generated by typeⅠof organic matter using two different experiment methods in gold tube system[J].Natural Gas Geoscience，2015，26(6)：1156-1164.[孙萌萌，米敬奎，冯子辉，等.黄金管体系中Ⅰ型有机质2种模拟方法生烃特征对比[J].天然气地球科学，2015，26(6)：1156-1164.]
[11]Lin Huixi，Wang Shengzhu，Li Yanli，Zhang Kuihua，Jin Qiang.Hydrocarbon generation simulation ofdifferent Carboniferous source rocks in the Junggar Basin[J].Natural Gas Industry，2014，34(10)：27-32.[林会喜，王圣柱，李艳丽，等.准噶尔盆地石炭系不同类型烃源岩生烃模拟[J].天然气工业，2014，34(10)：27-32.]
[12]Fu Deliang，Zhou Shixin，Li Jing，et al.Kinetics of oil cracking and the meaning of its phase transition characteristics：Taking Well YS1 in northern Qaidam Basin as an example[J].Natural Gas Geoscience，2016，27(8)：1500-1508.[付德亮，周世新，李靖，等.原油裂解动力学及其相变特征和意义——以柴达木盆地北缘伊深1井为例[J].天然气地球科学，2016，27(8):1500-1508.]
[13]Wang Zhichao，Mi Jingkui，Li Xianqiang，et al.Current situation and problems of simulation experiment approach of hydrocarbon generation[J].Natural Gas Geoscience，2009，20(4)：592-597.[王治朝，米敬奎，李贤庆，等.生烃模拟实验方法现状与存在问题[J].天然气地球科学，2009，20(4)：592-597.]
[14]Gai Haifeng，Xiao Xianming，Cheng Peng，et al.Gas generation of shale organic matter with different contents of residual oil based on a pyrolysis experiment[J].Organic Geochemistry，2015，78(57)：69-78.
[15]Ma Anlai.Kinetics of oil-cracking of different types of marine oils from Tahe Oilfield，Tarim Basin，NW China[J].Natural Gas Geoscience，2015，26(6)：1120-1128.[马安来.塔河油田不同类型海相原油裂解动力学分析[J].天然气地球科学，2015，26(6)：1120-1128.]
[16]Li Xianqing，Yang Yunfeng，Feng Songbao，et al.Characteristics of hydrocarbon and gas generation process from pyrolyzed crude oils in Tarim Basin[J].Journal of China University of Mining & Technology，2012，41(3)：397-405.[李贤庆，仰云峰，冯松宝，等.塔里木盆地原油裂解生烃特征与生气过程研究[J].中国矿业大学学报，2012，41(3)：397-405.]
[17]Tian Hui，Xiao Xianming，Yang Liguo，et al.Pyrolysis of oil at high temperatures：Gas potentials，chemical and carbon isotopic signatures[J].Chinese Science Bulletin，2009，54(7)：1217-1224.[田辉，肖贤明，杨立国，等.原油高温裂解生气潜力与气体特征[J].科学通报，2009,54(7)：1217-1224.]
[18]Guo Liguo，Xiao Xianming，Tian Hui.Laboratory study of differences between oil-derived and kerogenmaturation gases[J].Petroleum Geology & Experiment，2011，33(4)：428-436.[郭利果，肖贤明，田辉.原油裂解气与干酪根裂解气差异实验研究[J].石油实验地质，2011，33(4)：428-436.]
[19]Wang Tongshan，Geng Ansong，Li Xia，et al.Gas-generation mechanism of the pyrolysis of asphaltenes in marine crude oil and its geological application[J].Acta Sedimentologica Sinica，2010，28(4):808-814.[王铜山，耿安松，李霞，等.海相原油沥青质作为特殊气源的生气特征及其地质应用[J].沉积学报，2010，28(4):808-814.]
[20]Wang Zixiang，Wang Yongli，Wu Baoxiang，et al.Characteristics of gas generation and the application of hydrocarbon generation kinetics from low-maturity asphalt in Northwestern Sichuan Basin[J].Acta Petrolei Sinica，2016，37(3):339-347.[王自翔，王永莉，吴保祥，等.川西北低成熟沥青产气特征及生烃动力学应用[J].石油学报，2016，37(3):339-347.]
[21]Wang Qingtao，Lu Hong，Gao Lihui，et al.Geochemical characterization of thermogenic gas during the simulation experiments of the mature Salgan shale[J].Journal of China Coal Society，2013，38(5)：754-759.[王庆涛，卢鸿，高黎惠，等.高成熟萨尔干页岩热模拟产气的地球化学特征[J].煤炭学报，2013，38(5)：754-759.]
[22]Chen Yuan.Mechanisms and Evaluation of Shale Gas Generation from Organic-Rich Marine Shales[D].Chinese Academy of Sciences:Guangzhou Institute of Geochemistry，2015.[陈媛.海相富有机质页岩的生气机理和生气能力评价[D].中国科学院:广州地球化学研究所，2015.]
[23]Dong Zeliang，Li Xianqing，Yang Jie，et al.An experimental study on coal measures source rock gas generation thermal simulation[J].Coal Geology of China，2015，27(6):12-17，34.[董泽亮，李贤庆，杨杰，等.煤系烃源岩生气热模拟实验研究[J].中国煤炭地质，2015 ，27(6)：12-17，34.]
[24]Tang Qingyan，Zhang Mingjie，Yu Ming，et al.Pyrolysis constraints on the generation mechanism of shale gas[J].journal of china coal society，2013，38(05):742-747.[汤庆艳，张铭杰，余明，等.页岩气形成机制的生烃热模拟研究[J].煤炭学报，2013，38(05):742-747.]
[25]Sweeney J J，Burnham A K.Evaluation of a simple model of vitrinite reflectance based on chemical kinetics (1)[J].AAPG Bulletin，1990，74(10):1559-1570.
[26]Zhang Shuichang，Hu Guoyi，Mi Jingkui，et al.Time-limit and yield of natural gas generation from different origins and their effects on forecast of deep oil and gas resources[J].Acta Petrolei Sinica，2013，34(supplement 1)：41-50.[张水昌，胡国艺，米敬奎，等.三种成因天然气生成时限与生成量及其对深部油气资源预测，影响[J].石油学报，2013,34(增刊1):41-50.]
[27]Zhang Min，Huang Guanghui，Hu Guoyi，et al.Geochemical study of oil-cracking gas and Kerogen-cracking gas(Ⅰ):Analysis of Simulation experiments and products[J].Science China：Series D，2008,(supplement 2):1-8.[张敏，黄光辉，胡国艺，等.原油裂解气和干酪根裂解气的地球化学研究 (Ⅰ)——模拟实验和产物分析[J].中国科学：D辑，2008，(增刊2):1-8.]
[28]Tang Xiaoqiang，Huang Guanghui，Zhang Min，et al.Composition characteristics of products in the process of cracking of crude oil and oil fractions[J].Journal of Chengdu University of Technology:Science & Technology Edition，2011，38(1)：21-28.[唐小强，黄光辉，张敏，等.原油及其族组分裂解过程中产物组成变化特征[J].成都理工大学学报：自然科学版，2011，38(1)：21-28.]
[29]Zhao Wenzhi，Wang Zhaoyun，Zhang Shuichang，et al.Successive generation of natural gas from organic materials and its significance in future exploration[J].Petroleum Exploration and Development，2005，32(2)：1-7.[赵文智，王兆云，张水昌，等.有机质 “接力成气” 模式的提出及其在勘探中的意义[J].石油勘探与开发，2005，32(2)：1-7.]
[30]Wei Guoqi，Du Jinhu，Xu Chunchun，et al.Characteristics and accumulation modes of large gas reservoirs in Sinian-Cambrian of Gaoshiti-Moxi region，Sichuan Basin[J].Acta Petrolei Sinica，2015，36(1)：1-12.[魏国齐，杜金虎，徐春春，等.四川盆地高石梯—磨溪地区震旦系—寒武系大型气藏特征与聚集模式[J].石油学报，2015 ，36(1)：1-12.]
[31]Xu Guosheng，Xu Yanli，Yuan Haifeng，et al.Geochemical characteristics of source rocks and reservoir bitumen of sinian-lower palaeozoic in the middle-southwest of Sichuan Basin[J].Journal of oil and Gas Technology，2007，29(4)：45-51.[徐国盛，徐燕丽，袁海锋，等.川中—川东南震旦系—下古生界烃源岩及储层沥青的地球化学特征[J].石油天然气学报，2007，29(4)：45-51.]
[32]Luo Bing，Luo Wenjun，Wang Wenzhi，et al.Formation mechanism of the Sinian natural gas reservoir in the Leshan-Longnvsi paleo-uplift，Sichuan Basin[J].Natural Gas Geoscience，2015，26(3)：444-455.[罗冰，罗文军，王文之，等.四川盆地乐山—龙女寺古隆起震旦系气藏形成机制[J].天然气地球科学，2015，26(3)：444-455.]
[33]Wei Guoqi，Xie Zengye，Song Jiarong，et al.Features and origin of natural gas in the Sinian-Cambrian of central Sichuan paleo-uplift，Sichuan Basin，SW China[J].Petroleum Exploration and Development，2015，42(6):702-711.[魏国齐，谢增业，宋家荣，等.四川盆地川中古隆起震旦系—寒武系天然气特征及成因[J].石油勘探与开发，2015，42(6):702-711.]
[34]Zou Caineng，Du Jinhu，Xu Chunchun，et al.Formation，distribution，resource potential and discovery of the Sinian-Cambrian giant gasfield，Sichuan Basin，SW China[J].Petroleum Exploration and Development，2014，41(3)：278-293.[邹才能，杜金虎，徐春春，等.四川盆地震旦系—寒武系特大型气田形成分布，资源潜力及勘探发现[J].石油勘探与开发，2014，41(3)：278-293.]
[35]Zhou Q，Xiao X，Pan L，et al.The relationship between micro-Raman spectral parameters and reflectance of solid bitumen[J].International Journal of Coal Geology，2014，121(1)：19-25.
[36]Ma Wei，Li Jian，Wang Dongliang，et al.Hydrocarbon expulsion efficiency of source rocks and its influencing factors[J].Natural Gas Geoscience，2016，27(9)：1742-1751.[马卫，李剑，王东良，等.烃源岩排烃效率及其影响因素[J].天然气地球科学，2016，27(9)：1742-1751.]
[37]Li Jian，Wang Yifeng，Ma Wei，et al.Evaluation on occluded hydrocarbon in deep-ultra deep ancient source rocks and its cracked gas resources[J].Natural Gas Geoscience，2015，35(11):9-15.[李剑，王义凤，马卫，等.深层—超深层古老烃源岩滞留烃及其裂解气资源评价[J].天然气工业，2015，35(11):9-15.]
[38]Hao Bin，Hu Suyun，Huang Shipeng，et al.Geochemical characteristics and its significance of reservoir bitumen of Longwangmiao Formation in Moxi area，Sichuan Basin[J].Geoscience，2016,30(3)：614-626.[郝彬，胡素云，黄士鹏，等.四川盆地磨溪地区龙王庙组储层沥青的地球化学特征及其意义[J].现代地质，2016,30(3)：614-626.]
[39]Wei Guoqi，Yang Wei，Du Jinhu，et al.Tectonic features of Gaoshiti-Moxi paleo-uplift and its controls on the formation of a giant gasfield，Sichuan Basin，SW China[J].Petroleum Exploration and Development，2015，42(3):257-265.[魏国齐，杨威，杜金虎，等.四川盆地高石梯—磨溪古隆起构造特征及对特大型气田形成的控制作用[J].石油勘探与开发，2015，42(3):257-265.]
[40]Tian Hui，Wang Zhaoming，Xiao Zhongyao，et al.The kinetics simulation of oil cracking and its significance[J].Chinese Science Bulletin，2006，51(15):1821-1827.[田辉，王招明，肖中尧，等.原油裂解成气动力学模拟及其意义[J].科学通报，2006，51(15):1821-1827.]
[41]Li Wei，Hu Guoyi，Zhou Jingao.Asphalt features and gas accumulation mechanism of Sinian reservoirs in the Tongwan Palaeo-uplift，Sichuan Basin[J].Natural Gas Industry，2015，35(6)：14-23.[李伟，胡国艺，周进高.四川盆地桐湾期古隆起震旦系储层沥青特征与天然气聚集机制[J].天然气工业，2015，35(6)：14-23.]