天然气地质学

#br# 裂解气成因特征及成藏模式探讨

展开
  • 1.中国石油大学(北京)石油工程学院,北京 102249; 2.中国石油勘探开发研究院廊坊分院,河北 廊坊065007; 3.渤海钻探第二录井分公司, 河北 廊坊 065007
李君(1974-),男,吉林农安人,高级工程师,博士,主要从事石油地质研究.E-mail:jlbjlijun@163.com.

收稿日期: 2013-01-09

  修回日期: 2013-03-26

  网络出版日期: 2013-06-10

基金资助

国家科技重大专项“中国大型气田形成条件、富集规律及目标评价(二期)”(编号:2011ZX05007)资助.

The Genetic Feature and Reservoir Forming Mode of Cracked Gas in China

Expand
  • 1.College of Petroleum Engineering,China University of Petroleum(Beijing),Beijing 102249,China;
    2.Langfang Branch,Research Institute of Petroleum Exploration and Development,CNPC,Langfang 065007,China;
    3.Second Logging Branch of Bohai Drilling company,CNPC,Langfang 065007,China

Received date: 2013-01-09

  Revised date: 2013-03-26

  Online published: 2013-06-10

摘要

中国现阶段干酪根高演化阶段裂解气和原油裂解气探明储量占总储量26%以上,有必要系统研究该类天然气的形成、分布特征及下一步勘探方向。在大量源岩高演化生烃模拟和原油裂解模拟实验基础上,结合国内外裂解气研究成果,进一步分析了原油、海相—湖相泥岩及湖相煤系源岩裂解气的成因特征,并提出了5种成藏模式。原油裂解一般认为地温大于150℃以上时发生,实验证实一些地区在高于190℃才开始形成裂解气;烃源岩裂解气主要是干酪根芳甲基和终端甲基断裂,海相泥岩在RO值接近3%时裂解生气潜力接近枯竭,湖相煤系源岩在RO值为2.5%~5%时仍有较大的生成甲烷潜力,该阶段生气量占总生气量20%以上,而湖相泥岩裂解潜力介于二者之间,相对而言煤系源岩裂解气最具有潜力。裂解气主要具有古隆起原油裂解气、古风化—岩溶斜坡源岩裂解气、致密砂岩煤系源岩裂解气、特殊储集体裂解气、煤层—页岩源内裂解气5种成藏模式,古老海盆古隆起和斜坡、海陆过渡相盆地致密砂岩、中新生代湖相盆地特殊储集体是重要的勘探方向。

本文引用格式

李君,吴晓东,王东良,姜燕华,高阳,杨慎,莫午零 . #br# 裂解气成因特征及成藏模式探讨[J]. 天然气地球科学, 2013 , 24(3) : 520 -528 . DOI: 10.11764/j.issn.1672-1926.2013.03.520

Abstract

At present,the proven reserves of kerogen cracked and oil cracked gases at high thermal evolution stage have accounted for about 26% of the total reserves in China,so it is important to carry out systematic analysis of the formation and distribution characteristics of natural gas.Based on a number of pyrolytic experiments on kerogen and oil at high thermal stage,,combined with the researches on cracked gas,this paper further analyzed the genetic characteristics of cracked gases from oil,marine-lacustrine mudstone and lacustrine coal measures,and proposed five gas accumulation modes.Crude oil cracking was generally thought to occur at temperature more than 150℃.Our experiment proves that it begins to form cracking gas at temperature more than 190℃ in some areas.Gas generation potential of marine mudstone would exhaust when RO approaches 3%.However,lacustrine coal measures still have great methane generation potential when RO is near 2.5%-5%,and the gas amount generated at this stage accounts for more than 20% of the total generated gas.The cracking potential of lacustrine mudstone lies between the two formers,and the coal source rock has the greatest gas cracking potential.Cracking gas mainly has five accumulation modes,including ancient uplift crude oil cracked gas,ancient slope weathering karst cracking gas,dense sandstone coal source rock cracking gas,special reservoir cracking gas,and coal seam-shale source cracking gas.The ancient uplift and slope reservoir,the marine-terrestrial transitional basin dense sandstone reservoir and Meso-Cenozoic special reservoir are important potential exploration direction.

参考文献

[1]Zhao Mengjun,Zhang Shuichang,Liao Zhiqin.The cracking gas from crude oil and its significance in gas exploration[J].Petroleum Exploration and Development,2001,28(4):47-56.[赵孟军,张水昌,廖志勤.原油裂解气在天然气勘探中的意义[J].石油勘探与开发,2001,28(4):47-56.]

[2]Zhao Mengjun,Zeng Fangang,Qin Shengfei,et al.Two pyrolytic gases found and proved in Talimu Basin[J].Natural Gas Industry,2001,21(1):35-38.[赵孟军,曾凡刚,秦胜飞,等.塔里木发现和证实两种裂解气[J].天然气工业,2001,21(1):35-38.]

[3]Zhao Mengjun,Zhang Shuichang,Liu Fengzhong.Two possible fates for paleo-reservoir oils[J].Petroleum Exploration and Development,2003,30(5):21-230.[赵孟军,张水昌,刘丰忠.油藏演化的两个极端过程[J].石油勘探与开发,2003,30(5):21-230.]

[4]Dai Jinxing,Pei Xigu,Qi Houfa.Natural Gas Geology in China:Volume 1 [M].Beijing:Petroleum Industry Press,1992.[戴金星,裴锡古,戚厚发.中国天然气地质学:卷一 [M].北京:石油工业出版社,1992.]

[5]Xu Yongchang.Natural Gas Origin Theory and Application [M].Beijing:Science Press,1994.[徐永昌.天然气成因理论及应用[M].北京:科学出版社,1994.]

[6]Li Jian,Xie Zengye,Luo Xia,et al.Gas source identification of the major gas reservoirs in Talimu Basin[J].Natural Gas Industry,1999,19(2):38-43.[李剑,谢增业,罗霞,等.塔里木盆地主要天然气藏的气源判识[J].天然气工业,1999,19(2):38-43.]

[7]Guo Jianying,Zhong Ningning,Li Jian.Characteristics of carbon and hydrogen isotopes and genetic type of hydrocarbon gases in Qikou Sag[J].Natural Gas Geoscience,2011,22(6):1054-1061.[国建英,钟宁宁,李剑.歧口凹陷烷烃气碳、氢同位素特征及成因类型[J].天然气地球科学,2011,22(6):1054-1061.]

[8]Chen Shijia,Fu Xiaowen,Lin Feng,et al.Genetic discrimination of marine sapropelic type gas in Tarim Basin[J].Oil & Gas Geology,2001,22(2):100-101,118.[陈世加,付晓文,林峰,等.塔里木盆地海相腐泥型天然气的成因判识[J].石油与天然气地质,2001,22(2):100-101,118.]

[9]Chen Shijia,Fu Xiaowen,Ma Lining,et al.Genetic identification method of kerogen-cracked gases and oil-cracken gases[J].Experimental Petroleum Geology,2002,24(4):364-366,371.[陈世加,付晓文,马力宁,等.干酪根裂解气和原油裂解气的成因判识[J].石油实验地质,2002,24(4):364-366,371.]

[10]Wang Yunpeng,Tian Jing.Review of oil cracked gas formation,identification and migration[J].Natural Gas Geoscience,2007,18(2):235-244.[王云鹏,田静.原油裂解气的形成、鉴别与运移研究综述[J].天然气地球科学,2007,18(2):235-244.]

[11]Hu Guoyi,Xiao Zhongyao,Luo Xia,et al.Light hydrocarbon composition difference between two kinds of cracken gases and its application[J].Natural Gas Industry,2005,25(9):23-25.[胡国艺,肖中尧,罗霞,等.两种裂解气中轻烃组成差异性及其应用[J].天然气工业,2005,25(9):23-25.]

[12]Tian Hui,Xiao Xianming,Li Xianqing,et al.Comparison of gas generation and carbon isotope fractionation of methane from marine kerogen-and crude oil-cracking gases[J].Geochimica,2007,36(1):71-77.[田辉,肖贤明,李贤庆,等.海相干酪根与原油裂解气甲烷生成及碳同位素分馏的差异研究[J].地球化学,2007,36(1):71-77.]

[13]Li Xianqing,Xiao Xianming,Tang Y.Kinetic study of carbon isotope in humic gas methane in Kuqa Depression[J].Oil & Gas Geology,2004,25(1):21-25.[李贤庆,肖贤明,Tang Y.库车坳陷煤成甲烷碳同位素动力学研究[J].石油与天然气地质,2004,25(1):21-25.]

[14]Geng Xinhua,Geng Ansong.Kinetic simulating experiment on secondary thermal cracking of the bitumen generated from marine carbonate rock[J].Natural Gas Geoscience,2008,19(5):695-700.[耿新华,耿安松.源自海相碳酸盐岩烃源岩原油裂解成气的动力学研究[J].天然气地球科学,2008,19(5):695-700.]

[15]Yin Changhe,Wang Tingdong,Wang Shunyu.Differences between kerogen and oil cracked gases in sinian reservoirs of Weiyuan and Ziyang area[J].Acta Sedimentologica Sinica,2001,19(1):156-160.[尹长河,王廷栋,王顺玉.威远、资阳震旦系干酪根与油裂解气的鉴别[J].沉积学报,2001,19(1):156-160.]

[16]Xie Zengye,Li Jian,Shan Xiuqin,et al.Reservoiring process and accumulation efficiency of Feixianguan Formation gas pool in Luojiazhai,northeastern Sichuan Basin[J].Oil & Gas Geology,2005,26(6):765-769.[谢増业,李剑,单秀琴,等.川东北罗家寨飞仙关组气藏成藏过程及聚集效率[J].石油与天然气地质,2005,26(6):765-769.]

[17]Hou Dujie,Zhao Zengying,Tang Youjun,et al.The gelogical and geochemical characteristics of oil crackedgas in Kekeya region,Tarim  Basin[J].Natural Gas Geoscience,2004,15(2):137-141,200.[侯读杰,赵增迎,唐友军,等.柯克亚地区原油裂解气的地质—地球化学特征[J].天然气地球科学,2004,15(2):137-141,200.]

[18]Wang Hongjun,Zhou Xingxi.Formation modes of typical marine origin gas pools in Tarim Basin[J].Acta Petrolei Sinica,2001,22(1):14-19.[王红军,周兴熙.塔里木盆地典型海相成因天然气藏成藏模式[J].石油学报,2001,22(1):14-19.]

[19]Fabuss B M,Smith J O,Satterfield C N.Thermal cracking of pure saturated hydrocarbons[J].Advances in Petroleum Chemistry and Refining,1964,9:157-201.

[20]Siskin M,Katritzky A R.Reactivity of organic compounds in hot water:Geochemical and technological implications[J].Science,1991,254:231-237.

[21]Shuai Y H,Zhang S C,Luo P,et al.Experimental evidence for formation water promoting crude oil cracking to gas[J].Chinese Science Bulletin,2012,57(30):2857- 2863.[帅燕华,张水昌,罗攀,等.地层水促进原油裂解成气的模拟实验证据.科学通报,2012,57(30):2857-2863.]

[22]Wei Guoqi,Li Jian,Zhang Shuichang .New progress in the studies on basic geological theories of natural gas in China[J].Natural Gas Industry,2012,32(3):6-14.[魏国齐,李剑,张水昌.中国天然气基础地质理论问题研究新进展[J],天然气工业,2012,32(3):6-14.]

[23]Greensfelder B S,Voge H H,Good G M.Catalytic and thermal cracking of pure hydrocarbons[J].Industrial and Engineering  Chemistry,1949,41:2573-2584.

[24]Johns W D,Shimoyama A.Clay minerals and petroleum- forming reactions during burial and diagenesis[J].AAPG Bulletin,1972,56:2160-2167.

[25]Goldstein T P.Geocatalytic reactions in formation and maturation of petroleum[J].AAPG Bulletin,1983,67:152-159.

[26]Espitalié J,Senga Makadi K,Trichet J.Role of the mineral matrix during kerogen pyrolysis[J].Organic Geochemistry,1984,6:365-382.

[27]Kiyosu Y,Krouse H R.Carbon isotope effect during abiogenic oxidation of methane[J].Earth and Planetary Science Letters,1989,95:302-306.

[28]Machel H G.Gas souring by thermochemical sulfate reduction at 140℃:Discussion[J].AAPG Bulletin,1998,82:1870-1873.

[29]Zhang Shuichang,Shuai Yanhua,He Kun,et al.Research on the initiation mechanism of thermochemical sulfate reduction(TSR) [J].Acta Petrologica Sinica,2012,28(3):739-746.[张水昌,帅燕华,何坤,等.硫酸盐热化学还原作用的启动机制研究[J].岩石学报,2012,28(3):739-746.]

[30]Tissot B P,Welte D H.Petroleum Formation and Occurrence[M].New York:Springer-Verlang,1978.

[31]Waples D W.The kinetics of inreservoir oil destruction and gas formation:Constraints from experimental and empirical data,and from the rmodynamics[J].Organic Geochemistry,2000,31(6):553-575.

[32]Cai C F,Worden R H,Bottrell S H,et al.Thermochemical sulphate reduction and the generation of hydrogen sulphide andthiols(mercaptans)in Triassic carbonate reservoirs from the Sichuan Basin,China[J].Chemical  Geollogy,2003,202:39-57.

[33]Ma Xibin,Zhang Jianyong,Zhang Yan,et al.Generation mechanism of acid gas in northeast Sichuan[J].Fault-Block Oil & Gas Field,2008,15(6):13-17.[马喜斌,张建勇,张燕,等.川东北高含硫天然气形成机理[J].断块油气田,2008,15(6):13-17.]

[34]Zhang Jianyong,Liu Wenhui,Tenger,et al.Material selection of tsr simulation experiment instruments[J].Petroleum Geology & Experiment,2010,32(4):400-404.[张建勇,刘文汇,腾格尔,等.硫酸盐热还原作用模拟实验装置的材料选择[J].石油实验地质,2010,32(4):400-404.]

[35]Zhang Jianyong,Liu Wenhui,Fan Ming,et al.Whether TSR products can meliorate reservoir property of carbonate rock or not:an evidence from experimental geology[J].Marine Origin Petroleum Geology,2008,13(2):57-61.[张建勇,刘文汇,范明,等.TSR产物对碳酸盐岩储层是否具有改良作用:实验地质学的依据[J].海相油气地质,2008,13(2):57-61.]

[36]Fan Ming,Hu Kai,Jiang Xiaoqiong,et al.Effect of acid fluid on carbonate reservoir reconstruction[J].Geochimica,2009,38(1):20-26.[范明,胡凯,蒋小琼,等.酸性流体对碳酸盐岩储层的改造作用[J].地球化学,2009,38(1):20-26.]

[37]Voge H H,Good G M.Thermal cracking of higher paraffins[J].Journal of the American Chemical Society,1949,69:593-597.

[38]Dieckmann V,Keym M.A newapproach to bridge theeffect of organofacies variations on kinetic modelling andgeological extrapolations[J].Organic Geochemistry,2006.

[39]Mahlstedt N,Horsfield B,Dieckmann V.Second Order Reactions as Aprelude to Gas Generation at High Maturity[M].Organic Geochemistry,2008.

[40]Yang Xiancheng,Sui Fenggui,Li wentao,et al.The main controlling factors of deep cracked gas accumulation in Dongying Sag[J].Xinjiang Petroleum Geology,2001,28(5):563-565.[杨显成,隋风贵,李文涛,等.东营凹陷深层裂解气成藏主控因素[J].新疆石油地质,2001,28(5):563-565.]

[41]Li linlin,Zha Ming Chen Zhongong.Cracked gas accumulation condistins in deep Bonan Sag[J].Special Oil and Gas Reservoirs,2009,16(3):38-43.[李琳琳,查明,陈中红.渤南洼陷深层裂解气成藏条件分析[J].特种油气藏,2009,16(3):38-43.]

 

 
文章导航

/