网络出版日期: 2008-04-20
基金资助
中国科学院知识创新工程重要方向项目(编号:KZCX2\|YW\|114\|1);国家自然科学基金(编号:40572083)联合资助.
An Analysis of Characteristics of Hydrocarbon Generation from Pyrolysis Experiment of Source Rock
Online published: 2008-04-20
采用开放体系下进行的全岩热模拟实验,对塔里木盆地哈2井三叠系的黑色泥岩开展了产气率变化特征的研究,并结合成熟度及其显微组分的变化,探讨了烃源岩的生排烃过程。模拟实验结果表明:加温在400℃以前,R O值低于0.8%,累积产气率仅1.04 mL/g,所产烃气仅占总产气率的8.2%;加温到600℃时,累积产气率达9.23 mL/g,占总产气率的72.7%;生烃高峰在500~600℃之间,此时阶段产气率为6.23 mL/g,占总产气率的49.1%,大致相当于R O值为1.24%~1.78%,此阶段所生烃气约占总产气率的一半;700℃以后镜质组等腐殖组分仍可生成相当数量烃气,但已进入干气阶段,大量生烃阶段基本结束。
肖芝华, 胡国艺, 李志生 . 从烃源岩热模拟实验讨论其生烃特征[J]. 天然气地球科学, 2008 , 19(4) : 544 -547 . DOI: 10.11764/j.issn.1672-1926.2008.04.544
By means of thermal simulating experiment in the open system, this article focused on the hydrocarbon\|generating characteristics of Trias source rock from well Ha 2 in Tarim basin, it also combined with the alteration of maceral and maturation to discuss the characteristics of generating hydrocarbon. The result of experiment indicate that the accumulative yield is only 1.04 mL/g when the heating temperature is under 400℃( value of R O is below 0.8%), it only reach to 8.2% of the total gas yield. When the heating temperature reaches 600℃, the accumulative yield is 9.23 mL/g (about 72.7%of the total gas yield). The peak yield of hydrocarbon is between the heating temperature 500℃ and 600℃ (the value of R O is from 1.24% to 1.78%), the periodical yield in this evolution period is 6.23 mL/g (about 50% of the total gas yield). Although the humin component still could generate hydrocarbon when the heating temperature reaches 700℃, it has already been entered into the period of dry gas. The period of large quantity of generation has finished.
Key words: Open system; Thermal simulation; Hydrocarbon generation; Maceral.
[1]关德师,戚厚发.煤和煤系泥岩产气率实验结果讨论[M].北京:石油工业出版社,1987:182-193.
[2]关德师,程克明,张文正,等.依模拟实验论不同母质产油气特征及潜力[J].天然气地球科学,1991,2(1):16-22.
[3]卢双舫,赵锡嘏,黄第藩,等.煤成烃的生成和运移的模拟实验研究--Ⅰ.气态和液态产物特征及其演化[J].石油实验地质,1994,16(3):290-301.
[4] 金奎励,李荣西. 烃源岩组分组合规律及其意义[J].天然气地球科学,1998,9(1):23-29.
[5]史基安,王琪,赵欣.不同类型烃源岩气态烃的生成特征研究--来自差热-色谱联机热模拟实验方法的证据[J].沉积学报,1999,17(2):301-305.
[6]段毅,周世新.塔里木盆地石炭系烃源岩热模拟实验地球化学研究[J].沉积学报,1999,17(增):832-835.
[7]高岗.油气生成模拟方法及其石油地质意义[J].天然气地球科学,2000,11(2):25-30.
[8]谢增业,蒋助生,张英,等,全岩热模拟新方法及其在气源岩评价中的应用[J].沉[9]郑建京,温德顺,孟仟祥,等. 煤系烃源岩热模拟演化过程的地球化学参数特征--以准噶尔盆地侏罗系煤系烃源岩为例[J].天然气地球科学, 2003 ,14(2):134-138.
[10] 黄志龙,张四海,钟宁宁.碳酸盐岩生气的热模拟实验[J].地质科学,2003,38(4):455-459.
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