气田开发

源自海相碳酸盐岩烃源岩原油裂解成气的动力学研究

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  • (1.广州大学化学化工学院,广东 广州 510006;
    2.中国科学院广州地球化学研究所有机地球化学国家重点实验室,广东 广州 510640;)

收稿日期: 2008-01-02

  修回日期: 2008-06-07

  网络出版日期: 2008-10-10

Kinetic Simulating Experiment on Secondary Thermal Cracking of theBitumen Generated from Marine Carbonate Rock

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  • (1.College of Chemistry and Chemical Engineering Guangzhou University,Guangzhou 510006,China;  2. State Key Laboratory of Organic Geochemistry,Guangzhou Institute of eochemistry Chinese Academy of Sciences,Guangzhou 510640,China)

Received date: 2008-01-02

  Revised date: 2008-06-07

  Online published: 2008-10-10

摘要

对源自海相碳酸盐岩的原油进行了动力学模拟实验,阐述了该原油再次热解过程中气态烃组分的演化特征和生成动力学参数。运用动力学参数将模拟实验结果外推到地质条件下,结果表明:在150℃时,海相碳酸盐岩烃源岩生成的原油将开始热裂解并生成大量天然气,温度达到220℃时,裂解生气基本结束,天然气就全部取代石油;甲烷的生成Easy%RO主要介于1.2%~2.9%之间,C 2-5烃类气体的生成Easy%RO主要介于1.5%~2.5%之间。这一研究结果可为我国的碳酸盐岩烃源岩再次热解产气的定量模拟提供重要依据,有助于海相碳酸盐岩油气的资源评估。

本文引用格式

耿新华,;耿安松 . 源自海相碳酸盐岩烃源岩原油裂解成气的动力学研究[J]. 天然气地球科学, 2008 , 19(05) : 695 -700 . DOI: 10.11764/j.issn.1672-1926.2008.05.695

Abstract

This study reveal composition and the kinetic parameters of gaseous hydrocarbon by kinetic simulating experiment on secondary thermal cracking of the bitumen generated from marine carbonate rocks. The results can be used in nature extrapolation of laboratory kinetic data to very low, geological heating rates. The extrapolation indicates that methane generated under the secondary thermal stress 150℃O<1.9%). The heavy gaseous hydrocarbons (C2,C3,C 4-5) generated under 170℃O< 2.5%). The results can be used in quantitatively modeling the yield of gas generated from the oil that cracked from marine carbonate rocks and provides a new method for evaluating quantitatively the effective source rock.

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