收稿日期: 2008-01-02
修回日期: 2008-06-07
网络出版日期: 2008-10-10
Kinetic Simulating Experiment on Secondary Thermal Cracking of theBitumen Generated from Marine Carbonate Rock
Received date: 2008-01-02
Revised date: 2008-06-07
Online published: 2008-10-10
耿新华,;耿安松 . 源自海相碳酸盐岩烃源岩原油裂解成气的动力学研究[J]. 天然气地球科学, 2008 , 19(05) : 695 -700 . DOI: 10.11764/j.issn.1672-1926.2008.05.695
This study reveal composition and the kinetic parameters of gaseous hydrocarbon by kinetic simulating experiment on secondary thermal cracking of the bitumen generated from marine carbonate rocks. The results can be used in nature extrapolation of laboratory kinetic data to very low, geological heating rates. The extrapolation indicates that methane generated under the secondary thermal stress 150℃O<1.9%). The heavy gaseous hydrocarbons (C2,C3,C 4-5) generated under 170℃O< 2.5%). The results can be used in quantitatively modeling the yield of gas generated from the oil that cracked from marine carbonate rocks and provides a new method for evaluating quantitatively the effective source rock.
[1]赵孟军,张水昌,廖志勤.原油裂解气在天然气勘探中的意义[J].石油勘探与开发,2001,28(4):47-52.
[2]胡宗全.准噶尔盆地西北缘车排子地区油气成藏模式[J].断块油气田,2004,14(1):12-15.
[3]张水昌,赵文智,王飞宇,等.塔里木盆地东部地区古生界原油裂解气成藏历史分析:以英南2气藏为例[J].天然气地球科学,2004,15(5):441-451.
[4]侯读杰,赵增迎,唐友军.柯克亚地区原油裂解气的地质-地球化学特征[J].天然气地球科学,2004,15(2):137-142.
[5]尹长河,王廷栋,王顺玉,等.威远、资阳震旦系干酪根与油裂解气鉴别[J].沉积学报,2001,19(1):156-160.
[6]赵孟军,卢双舫.原油二次裂解气——天然气重要的生成途径[J].地质论评,2000,46(6):645-650.
[7]赵孟军,张水昌,刘丰忠.油藏演化的两个极端过程[J].石油勘探与开发,2003,30(5):21-23.
[8]赵文智,王兆云,张水昌,等.有机质“接力成气”模式的提出及其在勘探中的意义[J].石油勘探与开发,2005,32(2):1-7.
[9]卢双舫,薛海涛,钟宁宁.石油保存下限的化学动力学研究[J].石油勘探与开发,2002,29(6):1-3.
[10]曲佳燕,王振平,付晓泰,等.油藏热破坏的化学动力学定量研究[J].河北工业大学学报,2003,32(4):35-40.
[11]Schenk H J,Di Primio R,Horsfield B.The conversion of oil into gas in petroleum reservoirs.PartⅠ:Comparative kinetic investigation of gas generation from crude oils of lacustrine,marine and fluviodeltaic origin by programmed-temperature closed-system pyrolysis[J].Org Geochem,1997,26(7-8):467-481.
[12]Dieckmann V,Schenk B,Horsfield B.Kinetics of petroleum generation and cracking by programmed-temperature closed-system pyrolysis of Toarcian Shales[J].Fuel,1998,77(1-2):23-31.
[13]Wang Tongshan,Geng Ansong,Xiong Yongqiang,et al.Mass balance calculation of the pyrolysates generated from marine crude oil:A prediction model of oil cracking gas resources based on solid bitumen in reservoir[J].Chinese Science Bulletin,2006,52(1):1532-1539.
[14]田辉,王招明,肖中尧,等.原油裂解成气动力学模拟及其意义[J].科学通报,51(15):1821-1827.
[15]王铜山,耿安松,熊永强,等.海相原油裂解生气实验产物的物质平衡计算:一个基于储层固体沥青分析的原油裂解气资源量预测模型[J].科学通报,2007,52(7):836-842.
[16]卢双舫,付晓泰,刘晓艳,等.油成气的动力学模型及其标定[J].天然气工业,1996,16(6):6-9.
[17]赵文智,王兆云,张水昌,等.油裂解生气是海相气源灶高效成气的重要途径[J].科学通报,2006,51(5):589-595.
[18]王云鹏,田静.原油裂解气的形成,鉴别与运移研究综述[J].天然气地球科学,2007,18(2):235-244.
[19]高岗,姜振学,赵喆,等.加水模拟条件下升温速率对烃源岩成烃特征的影响 [J].天然气地球科学,2004,15(5):461-464.
[20]高岗.两种灰岩的生气特征比较研究[J].天然气地球科学,2004,15(3):302-305.
[21]刘金钟,唐永春.用干酪根生烃动力学方法预测甲烷生成量之一例[J].科学通报,1998,43(11):1187-1191.
[22]Behar F,Tang Y,Liu J.Comparison of rate constant for some molecular tracers generated during artificial maturation of kerogens:influence of kerogen types[J].Organic Geochemistry,1997,26:281-287.
[23]Ungerer P,Pelet R.Extrapolation of oil and gas formation kinetics from laboratory experiments to sedimentary basins[J].Natrue,1987,327:52-54.
[24]耿新华,耿安松,熊永强,等.海相碳酸盐岩烃源岩热解动力学研究——全岩和干酪根的对比[J].地球化学,2005,34(6):612-618.
[25]耿新华,耿安松,熊永强,等.海相碳酸盐岩烃源岩热解动力学研究——气液态产物演化特征[J].科学通报,2006,51(5):582-588.
[26]赵文智,王兆云,何海清,等.中国海相碳酸盐岩烃源岩成气机理[J].中国科学:D辑,2005,35 (7):638-648.
[27]Mango F D,Hightower J W.The catalytic decomposition of petroleum into natural gas[J].Geochim Cosmochim Acta,1997,61:5347-5350.
[28]Domine F,Dessort D,Brevart O.Towards a new method of geochemical kinetic modeling:implications for the stability of crude oils[J].Org Geochem,1998,28:576-612.
[29]Jerry J S,Alan K B.Evaluation of a Simple Model of Vitrinite Reflectance Based on Chemical Kinetics[J].AAPG Bulletin,1990,74(10):1559-1570.
[30]张抗,王大锐.中国海相油气勘探的启迪[J].石油勘探与开发,2003,30(2):9-16.
[31]赵文智,窦立荣.中国陆上剩余油气资源潜力及其分布和勘探对策[J].石油勘探与开发,2001,28(1):1-5.
/
〈 |
|
〉 |