天然气水合物

天然气水合物动态成藏理论

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  • (1. 华南理工大学传热强化与过程节能教育部重点实验室,广东 广州,510640;
    2. 中国科学院广州能源研究所,广东 广州 510640;
    3. 中国科学院广州天然气水合物研究中心,广东 广州 510640;
    4. 中国科学院研究生院,北京100039;5. 中国地质大学工程学院,湖北 武汉 430074)
樊栓狮(1965-),男,陕西蒲城人,教授,博士生导师,主要从事天然气水合物、化工分离等研究.

收稿日期: 2007-07-23

  修回日期: 2007-09-28

  网络出版日期: 2008-06-20

基金资助

中国科学院创新项目(编号:KGCX2-SW-224);国家自然科学基金(编号:90410003);广东省自然科学基金重点(编号:052001130)联合资助.

A DYNAMIC THEORY ON NATURAL GAS HYDRATE RESERVOIR FORMATION

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  • (1.South China University of Technology,Key Laboratory of Enhanced Heat Transfer and Energy Conservation, MOE,Guangzhou 510640,China; 2.Guangzhou Institute of Energy Conversion,CAS,Guangzhou 511640,China; 3.Guangzhou Center for Gas Hydrate Research, Guangzhou 541640,China;4.Graduate School of the Chinese Academy of Sciences, Beijing 100039,China;5.Faculty of Engineering, China University of Geosciences, Wuhan 430074,China)

Received date: 2007-07-23

  Revised date: 2007-09-28

  Online published: 2008-06-20

摘要

总结了天然气水合物的赋存状态及其分类,从生成和分解速度角度提出了天然气水合物的动态成藏理论, 并依据冻土层钻井气体喷溢、海底水合物露头和海底羽状气泡流等实例论证了这种动态成藏理论。指出天然气水合物赋存状态主要有3种类型,即成长型(渗透型、扩散型)、成熟型和消退型,认为我国南海北部陆坡区的西沙海槽、东沙群岛东南坡、台西南盆地、笔架南盆地等区域有可能存在着仍处于发育阶段的渗透型或扩散型水合物层,而青藏高原羌塘盆地则是属于消退型水合物,祁连山地区、准噶尔盆地等的烃类气体泄漏表明在我国西北和东北的冻土带也可能存在着含气水合物层。

本文引用格式

樊栓狮,关进安,梁德青,宁伏龙 . 天然气水合物动态成藏理论[J]. 天然气地球科学, 2007 , 18(6) : 819 -826 . DOI: 10.11764/j.issn.1672-1926.2007.06.819

Abstract

Classification on natural gas hydrate deposits occurrence is summarized, and a dynamic theory of gas hydrate reservoir formation is put forward. According to this theory, there are three types of reservoirs: growing type (including seeping type and diffusing type), mature type and regressive type. This theory is demonstrated by three examples: the natural gas blowout when drilling in the permafrost, the hydrate cropouts in the seafloor and the gas bubbles in abyssal plumes. Then, several conclusions are drawn: there maybe exist the seeping and diffusing types of gas hydrate reservoirs which may still be growing in the Xisha trough, Dongsha continental slope of the South China Sea, west and south of Taiwan basin, and Bijianan basin; whereas in the Qiangtang basin of the Qinghai Tibet plateau may exist the regressive type gas hydrate deposit. Furthermore, the phenomenon of hydrocarbon gas leaking in the Qilian mountain areas and Junger basin indicates that these areas may ensconce gas hydrate reservoirs.

参考文献

 [1] Sloan E D.Clathrate Hydrates of Natural Gases[M].2nd ed.New York : Marcel Dekker, 1998.
[2]Tréhu A M, Ruppel C, Holland M,et al.Gas Hydrates in Marine Sediments: Lessons from Scientific Ocean Drilling[J].Oceanography, 2006, 19(4): 124-142.
[3]Klauda J B, Sandler S I.Global distribution of methane hydrate in ocean sediment[J].Energy & Fuels, 2005, 19(2): 459-470.
[4]Malone R D.Overview Gas Hydrate Geology and Geography[C]//Annals of the New York Academy of Sciences.New York:[s.n.]1994, 225-231.
[5]Uchida T, Dallimore S, Mikami J.Occurrences of natural gas hydrates beneath the permafrost zone in machenzie delta visual and X-ray CT imagery[C]//Holder G D,Bishnoi P R.Gas Hydrates Challenges for the Future.New York:The New York Academy of Sciences: 2000:1020-1033.
[6]樊栓狮, 刘峰, 陈多福.海洋天然气水合物的形成机理探讨[J].天然气地球科学, 2004, 15(5): 524-530.
[7]Perlova E V, Yakushev V S, Makhonina N A,et al.Submarine Gas Hydrate Deposits: from Genesis, Geology to Peculiarities of Gas Production and Treatment[C]//Proceedings of the Fifth International Conference on Gas Hydrates(ICGH5).Trondheim, Norway,2005, 3(3009).
[8]Yakushev V S, Perlova E V, Makhonina N A,et al.Classification of gas hydrate deposits as important step to natural gas production from hydrates[C]//Proceedings of the fifth international conference on gas hydrates(ICGH5).Trondheim, Norway,2005, 3(3015).
[9]Bernard B, Brooks J M, Sackett W M.A geochemical model for characterization of hydrocarbon gas source in marine sediments[C]//Proceding 9th Annual Offshore Technology Conference.Houston: Offshore Technology Conference, 1977, 435-438.
[10]Hesse R, Harrison W E.Gas hydrates(clathrates) causing pore water freshening and oxygen-isotope fractionation in deep-water sedimentary sections of terrigenous continental margins[J].Earth and Planetary Science Letters, 1981, 55: 453-462.
[11]Sassen R, Sweet S T, Milkov A V,et al.Geology and geochemistry of gas hydrates, central Gulf of Mexico continental slope[J].Gulf Coast Associ Geol Societies Trans, 1999,49: 462-468.
[12]蒋少勇,杨竞红,凌洪飞,等.用地球化学方法勘查中国南海的天然气水合物[J].海洋地质与第四纪地质,2004,24(3):103-109.
[13]Yakushev V S, Chuvilin E M.Natural gas and gas hydrate accumulations within permafrost in Russia[J].Cold Regions Science and Technology, 2000 31(3): 189-197.
[14]Dai J C, Xu H B, Snyder F,et al.Detection and estimation of gas hydrates using rock physics and seismic inversion: Examples from the northern deepwater Gulf of Mexico[J].The Leading Edge, 2004, 23(1):60-66.
[15]Moridis G J.Numerical simulation of gas production from methane hydrates[R].SPE 75691,2002.
[16]Archer D.Methane hydrate stability and anthropogenic climate change[J].Biogeosciences Discuss, 2007, 4: 993-1057.
[17]Kastner M, Bartlett D, MacDonald I,et al.CH4 fluxes across the seafloor at the three distinct gas hydrate fields: Impacts on ocean and atmosphere chemistry[C]//Proceedings of the fifth international conference on gas hydrates(ICGH5).Trondheim, Norway,2005, 3(3002).
[18]Solomon E A, Kastner M, Robertson G,et al.Insights into the dynamics of in situ gas hydrate formation and dissociation at the Bush Hill gas hydrate field, Gull of Mexico[C]//Proceedings of the fifth international conference on gas hydrates(ICGH5).Trondheim, Norway,2005,3(3035).
[19]Liu Xiao-li, Flemings P B.Passing gas through the hydrate stability zone at southern Hydrate Ridge, offshore Oregon[J].Earth and Planetary Science Letters, 2006, 241: 211-226.
[20]Sauter E J, Muyakshin S I, Charlou J-L,et al.Methane discharge from a deep-sea submarine mud volcano into the upper water column by gas hydrate-coated methane bubbles[J].Earth and Planetary Science Letters, 2006, 243: 354-365
[21]Yakushev V.Relic gas hydrates in northwestern Siberia[J].The national energy technology methane hydrate newsletter: Fire in the ice, Fall,2004: 8-10.
[22]Pohlman J W, Canuel E A, Chapman N R,et al.The origin of thermogenic gas hydrates on the northern Cascadia Margin as inferred from isotopic (13C/12C and D/H) and molecular composition of hydrate and vent gas[J].Organic Geochemistry, 2005, 36: 703-716.
[23]Xu W Y, Ruppel C.Prediction the occurrence, distribution, and evolution of methane gas hydrate in porous marine sediments[J].Journal of Geophysical Research, 1999, 104(B3): 5081-5095.
[24]Clennell M B, Judd A, Hovland M.Movement and accumulation of methane in marine sediments: relation to gas hydrate systems[M]//Max M D.Natural Gas Hydrate in Oceanic and Permafrost Environments.Rotterdam, Netherlands: Kluwer Academic Publishers, 2000: 105-122.
[25]Milkov A V, Dickens G R, Claypool G E.Co-existence of gas hydrate, free gas, and brine within the regional gas hydrate stability zone at Hydrate Ridge (Oregon margin): evidence from prolonged degassing of a pressurized core[J].Earth and Planetary Science Letters, 2004, 222: 829-843.
[26]Liu X L.Dynamics of shallow marine gas hydrate and free gas systems[D].Central County, America: Pennsylvania State University, 2006.
[27]MacDonald I R, Guinasso N L Jr., Ackleson S G,et al.Natural oil slicks in the Gulf of Mexico visible from space[J].Journal of Geophysical Research(Oceans), 1993, 98(C9): 16351-16364.
[28]蒋国盛,王达,汤凤林,等.天然气水合勘探与开发[M].武汉:中国地质大学出版社,2002.
[29]Mikami J, Masuda Y, Uchida T,et al.Dissociation of natural gas hydrates observed by X-ray CT scanner[M]//Holder G D,Bishnoi P R.Gas Hydrates Challenges for the Future.New York:The New York academy of sciences.2000:1011-1020.
[30]Macdonld I R, Bend L C, Vardaro M,et al.Thermal and visual time-series at a seafloor gas hydrate deposit on the Gulf of Mexico slope[J].Earth and Planetary Science Letters, 2005,233: 45-59.
[31]Solomon E A, Kastner M, Robertson G,et al.Insights into the dynamics of in situ gas hydrate formation and dissociation at the Bush Hill gas hydrate field, Gull of Mexico[C]//Proceedings of the Fifth International Conference on Gas Hydrates(ICGH5),Trondheim, Norway, 2005, 3(3035).
[32]Milkov A V, Lee Y J, Borowski W S,et al.Co-existence of gas hydrate, free gas, and brine within the regional gas hydrate stability zone at Hydrate Ridge(Oregon margin): Evidence from prolonged degassing of a pressurized core[J].Earth Planet Sci Lett,2004, 222: 829-843.
[33]Obzhirov A, Salyuk A, Vereshchagina O,et al.Methane flux and gas hydrate and seismic activity in the Sea of Okhotsk[C]//Proceedings of the Fifth International Conference on Gas Hydrates(ICGH5),Trondheim, Norway.2005, 3(3038).
[34]Greinert J, Artemov y, Egorov V,et al.1300-m-high rising bubbles from mud volcanoes at 2080 m in the Black Sea-Hydroacoustic characteristics and temporal variability[J].Earth and Planetary Science Letters, 2006, 244: 1-15.
[35]吴时国, 张光学, 郭常升,等.东沙海区天然气水合物形成及分布的地质因素[J].石油学报, 2004, 25(4): 7-12.
[36]姚伯初.南海天然气水合物的形成和分布[J].海洋地质与第四纪地质, 2005, 25(2): 81-90.
[37]陈多福, 王茂春, 夏斌.青藏高原冻土带天然气水合物的形成条件与分布预测[J].地球物理学报, 2005, 48(1): 165-172.
[38]赵洪伟, 龚建明, 陈建文,等.与火山—热液作用有关的海洋天然气水合物[J].石油实验地质, 2005, 27(4): 395-403.
[39]祝有海, 刘亚玲, 张永勤.祈连山多年冻土区天然气水合物的形成条件[J].地质通报, 2006, 25(1-2): 58-64.
[40] [40]  库新勃,吴青柏,蒋观利,等.青藏高原多年冻土区天然气水合物可能分布范围[J].天然气地球科学,2007,18(4):588-592.

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