天然气地球化学

注蒸汽开采稠油过程中H2S的形成

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  • (1.长江大学地球化学系,湖北 荆州 434023;2.中国石油勘探开发研究院,北京 100083;
    3.中国石化国际石油勘探开发有限公司,北京 100083)
张静岩(1981-),男,河北邯郸人,硕士,主要从事地球化学研究.

收稿日期: 2007-07-27

  修回日期: 2007-09-29

  网络出版日期: 2008-06-20

基金资助

国家自然科学基金项目(编号:40602016);中国石油科技风险创新研究项目联合资助.

FORMATION OF H2S DURING THERMAL RECOVERY FOR VISCOUS OIL BY STEAM 

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  • 1. Department of Geochemistry, Yangtze University, Jingzhou 434023, China;  2. Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China; 3.International Petroleum Exploration and Development Co Ltd. SINOPEC,Beijing 100083,China)

Received date: 2007-07-27

  Revised date: 2007-09-29

  Online published: 2008-06-20

摘要

蒸汽吞吐和蒸汽驱是目前广泛使用的稠油热开采技术,但当该技术用于生产时,由于高温蒸汽对油层的加热,可产生大量的次生型H2S。指出了次生型H2S产生的原因主要为含硫化合物的热裂解(TDS)和硫酸盐热化学还原(TSR)反应等,当储层为浅层砂岩时,硫化氢的产生量与原油的硫含量成正比,如果地层中含有硫酸根离子,地层的高温高压条件有利于TSR反应的进行;生产实践证明热采过程中H2S的形成确实与上述2种原因有关,并且这2种原因又是一个相互联系的统一体。

关键词: 稠油; 蒸汽驱; 蒸汽吞吐

本文引用格式

张静岩;朱光有;田建波;文志刚 张水昌 . 注蒸汽开采稠油过程中H2S的形成[J]. 天然气地球科学, 2007 , 18(6) : 798 -802 . DOI: 10.11764/j.issn.1672-1926.2007.06.798

Abstract

Steam soak and steam flood are popular thermal recovery techniques for viscous oil. But when they are used for production, some H2S will form for heating oil sand by steam. The formation of H2S is complex when geologic conditions and recovery methods are varied. The H2S formed during thermal recovery are secondary. Through research we think that the reasons for the formation of secondary H2S are thermal decomposition of sulfides (TDS) and thermo\|chemical sulphate reduction (TSR). Examples of thermal recovery for viscous oil abroad have proved that the quantity of H2S formed is in direct proportion to sulfur content of crude oil. Moreover, if there are sulfate ions in the layer, the high temperature will favor the TSR. In fact, the formation of H2S has something to do with both reasons above, and the reasons are connected to each other. Since H2S is harmful, something must be done to prevent H2S from forming.

参考文献

1 C & C Reservoirs. Reservoir Evaluation ReportM.Cold Lake Area,1999;Tia Juana Field,1999;Schoonebeek Field,1998;Emeraude Field,2004.

2Wilhelm H E Lillie.Status of the Steam Drive Pilot in the Georgsdorf Field,Federal Republic of GermanyR.SPE 8385,173-180.

3]朱光有,戴金星,张水昌,. 含硫化氢天然气的形成机制及其分布规律研究[J.天然气地球科学,2004,152):166-170.

4]朱光有,张水昌,梁英波,. 天然气中高含H2S的成因及其预测[J.地质科学, 2006,41(1): 152-157.

5]朱光有,张水昌,梁英波,. 高含H2S天然气形成的主控因素研究[J.天然气工业, 2006,26(增刊):8-1.

6]朱光有,张水昌,梁英波,. 四川盆地深部海相优质储集层的形成机理及其分布预测[J.石油勘探与开发, 2006,33(2):161-166.

7]胡常忠.稠油开采技术[M.北京:石油工业出版社,1998,6:34-45.

8]刘喜林.难动用储量开发/稠油开采技术[M.北京:石油工业出版社,2005,11:151-162.9]双喜岭油田齐40块蒸汽驱先导试验及扩大试验跟踪研究[R].辽河油田分公司勘探开发研究院,2005:3-6.

10Askinat M H.Gas evolution and change of oil composition during steam flooding of oil reservoirs[J].Pet Geology,1983,5(4):363-388.

11Monin J C,Audbert A.Thermal Craching of Heavy-oil/Mineral Matrix Systems[R].SPE 16269,1243-1250.

12Kowalewski I,Lamoureux-Var V,Lorant F. Geochemical factors controlling H2S production in petroleum reservoirs during steam injection process: TSR experimental simulation[J]. Organic Geochemistry Challenges for the 21th Century,20051:368-369.

13[KG*7/8]Hoffmann G G,Adelgunde Strohschein. Thermal recovery pr-ocesses and hydrogen sulfide formation[R].SPE 29016.

14]朱光有,张水昌,梁英波,.四川盆地H2S的硫同位素组成及其成因探讨[J].地球化学,200635(3):432-442.

15[JP2]Hyne J B,Greidanus J W. Aquathermolysis of heavy oilC//Proc 2nd Int Conf on heavy crude and rar sands.Caracas,Venezuela,1982.

16Lamoureux-Var V,Lorant F. H2SArtificial Formation as a Result of Steam Injection for EOR:a Compositional Kinetic Approach[R]. SPE/PS-CIM/CHOA97810.

17Belgrave J D M,Moore R G,Ursenbach R G. Comprehensive kinetic models for the aquathermolysis of heavy oils[J]. Journal of Canadian Petroleum Technology, 1997,364:38-44.18]朱光有,张水昌,梁英波,.川东北地区飞仙关组高含H2S天然气TSR成因的同位素证据[J].中国科学:D,35(11):1037-1046.

19]朱光有,张水昌,梁英波,等.TSR对深部碳酸盐岩储层的溶蚀改造——四川盆地深部碳酸盐岩优质储层形成的重要方式[J].岩石学报,2006,228,2182-2194.

20]朱光有,张水昌,梁英波,.四川盆地威远气田硫化氢的成因及其证据[J].科学通报,2006,51(23):2780-2788.

21]朱光有,张水昌,梁英波,,四川盆地高含H2S天然气的分布与TSR成因证据[J].地质学报,2006,808:1208-1217.

22]范洪富,刘永建,钟立国. 油层矿物对蒸汽作用下稠油组成与粘度变化的影响[J]. 油田化学,2001,184,299-310.

 

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