油气中汞及其化合物样品采集与实验分析方法研究进展

刘全有;李剑;侯路;

doi:10.11764/j.issn.1672-1926.2006.04.559

天然气地球科学 >

2006 , Vol. 17 >Issue 4: 559 - 565

DOI: https://doi.org/10.11764/j.issn.1672-1926.2006.04.559

天然气地球化学

油气中汞及其化合物样品采集与实验分析方法研究进展

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[1]中国石油勘探开发研究院; [2]中国石油勘探开发研究院廊坊分院; [3]中国石油大学（北京）; 河北廊坊;

网络出版日期: 2006-08-20

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ADVANCE OF RESEARCH ON MERCURY AND ITS COMPOUNDS COLLECTING AND MEASURING METHODS

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1.Research Institute of Petroleum Exploration and Development,PetroChina,Beijing 100083,China;2.Lanfang Branch,Research Institute of Petroleum Exploration and Development,PetroChina,Langfang 065007,China; 3.Chinese University of Petroleum(Beijing),Beijing 102200,China

Online published: 2006-08-20

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摘要

汞是油气中最重要的毒性物质之一,油气燃烧后,汞会进入大气造成环境污染。随着分析技术的不断发展,对汞在油气中的存在形式有了进一步的认识。准确地确定油气中总汞和汞化合物物种需要熟练的采样方法和严格的分析技术,因为利用常规的分析技术很难检测到油气中的某些汞化合物。目前,已有关于石油中不同汞化合物的报道,但数值变化范围很大,对于二甲基汞作为人类潜在的危害有了一些认识,其在油气中准确的含量仍有待深入研究,油气中汞及其化合物的含量和相对分布主要与源岩类型和地质背景有关。

关键词： 油气; 汞; 汞化合物; 分析技术

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刘全有;李剑;侯路; . 油气中汞及其化合物样品采集与实验分析方法研究进展[J]. 天然气地球科学, 2006 , 17(4) : 559 -565 . DOI: 10.11764/j.issn.1672-1926.2006.04.559

Abstract

Mercury is one of the most important toxic elements in oil and gases.Owing to the high volatize feature Hg tend to dispose into the air during combustion and therefore it results in the environmental pollution. The understanding of various chemical forms of mercury in hydrocarbon matrices has evolved due to technical advances.Accurate determinations of total mercury and speciation of mercury compounds in oil and gases depend on sophisticated sampling techniques and rigorous analytical procedures.

Key words： Oil and gas; Mercury; Mercury compound; Analytical technology.

参考文献

[1]WILHELM S M,BLOOM N.Mercury in petroleum[J].Fuel Processing Technology, 2000,63:1-27.

[2] FRECH W,BAXTER D C,DYVIK G,et al.On the determination of total mercury in natural gases using the amalgamation technique and cold vapor atomic absorption spectrometry[J].Journal of Analytical Atomic Spectrometry,1995,10:769-775.

[3] 戴金星,戚厚发, 王少昌,等.我国煤系的气油地球化学特征、煤成气藏形成条件及资源评价[M].北京:石油工业出版社,2001:159.

[4] SHAFAWI A,EBDON L,OULKES M,et al.Determination of total mercury in hydrocarbons and natural gas condensate by atomic fluorescence spectrometry[J].Analyst,1999,124:185-189.

[5]EVANS R D,HINTELMANN H,DILLON P J.Measurement of high precision isotope ratios for mercury from coals using transient signals[J]. Journal of Analytical Atomic Spectrometry,2001,16:1064-1069. [6] MAGALHāES C E C,KRUG F J,FOSTIER A H,et al.Direct determination of mercury in sediments by atomic absorption spectrometry[J]. Journal of Analytical Atomic Spectrometry, 1997, 12:1231-1234.

[7] RYZHOV V V,MASHYANOV N R,OZEROVA N A.et al.Regular variations of the mercury concentration in natural gas[J].The Science of The Total Environment, 2003, 304:145-152.

[8] FRECH W,SNELL J,STURGEON R.Performance comparison between furnace atomization plasma emission spectrometry and microwave induced plasma-atomic emission spectrometry for the detection of mercury species in gas chromatography effluents[J].Journal of Analytical Atomic Spectrometry,1998, 13:1347.

[9]BOUYSSIERE B,BACO F,SAVARY L,et al.Speciation analysis of mercury in gas condensates by capillary gas chromatography with inductively coupled plasma mass spectrometric detection［J］．Journal of Chromatography A, 2002, 976:431-439.

[10] HINTELMANN H,LU S.High precision isotope ratio measurements of mercury isotopes in cinnabar ores using multi-collector inductively coupled plasma mass spectrometry[J].Analyst,2003,128:635-639.

[11] XIE Q,LU S,EVANS D,et al.High precision Hg isotope analysis of environmental samples using gold trap-MC-ICP-MS［Ｊ］．Journal of Analytical Atomic Spectrometry, 2005,20:515-522.

[12] KRUPP E M.DONARD O F X.Isotope ratios on transient signals with GC-MC-ICP-MS［Ｊ］．International Journal of Mass Spectrometry,2005,242:233-242.

[13] DIETZ C,MADRID Y,CAMARA C.Mercury speciation using the capillary cold trap coupled with microwave-induced plasma atomic emission spectroscopy[J].Journal of Analytical Atomic Spectrometry,2001,16:1397-1402.

[14] MUSA M,MARKUS W,ELGHONDI A,et al.Neutron activation analysis of major and trace elements in crude petroleum[J].J Radioanal Nucl Chem,1995,198:17.

[15] EMTEBORG H,SNELL J,QIAN J,et al.Source of systematic errors in mercury speciation using Grignard Reagents and capillary gas chromatography coupled to atomic spectrometry[J].Chemosphere,1999,39:1137-1152.

[16]BOUYSSIERE B,BACO F,SAVARY L,et al.Analytical methods forspeciation of mercury in gas condensates: critical assessment and recommendations[J].Oil & Gas Science and Technology-Rev.IFP,2000,55:639-648.

[17] LOBINAKI R,ADAMS F C.Speciation analysis by gas chromatography with plasma source spectrometry detection[J].Spectrochimica Acta, Part B, 1997,52(B):1865-1903.

[18] SNELL J P,FRECH W,THOMASSEN Y.Performance improvements in the determination of mercury species in natural gas condensate usingan on-line amalgamation trap or solid-phase micro-extraction with capillary gas chromatography Microwave-induced plasma atomic emission spectrometry[J]. Analyst,1996,121:1055-1060.

[19]AO H,MURAKAMI T,TOMINAGA M,et al.Mercury speciation in natural gas condensate by gas chromatography-inductively coupled plasma mass spectrometry[J].Journal of Analytical Atomic Spectrometry,1998,13:1085-1093.

[20] 张鸿，孙慧斌，柴之芳. AAS，ICP-MS 与NAA的特点及其应用比较[J]. 现代科学仪器, 2003,4:34-38.

[21] SCHICKLING C,BROEKAERT J.Determination of mercury species in gas condensates by on line coupled high. Performance liquid chromatography and cold vapor atomic.absorption spectrometry［J］．Appl Organomet Chem.1995,9:29-36.

[22] 陈践发,妥进才,李春园, 等.辽河坳陷天然气中汞的成因及地球化学意义[J].石油探勘与开发,2000,27:23-24.

[23] 涂修元.河南泌阳坳陷天然气中汞的分布[J].石油与天然气地质,1980,（6）:241-247.

[24] 陈践发,王万春,朱岳年.含油气盆地中天然气汞含量的主要影响因素[J].石油与天然气地质,2001,22:352-354.

[25] 侯路,戴金星,胡军,等.天然气中汞含量的变化规律及应用——兼述岩石和土壤中汞的含量［Ｊ］．天然气地球科学,2005,16(4):514-521.

[26] 徐永昌.天然气成因理论及应用[C].北京:科学出版社,1994:413.

[27] 戴金星,戚厚发,宋岩.鉴别煤成气和油型气若干指标的初步探讨[J].石油学报,1985,(6):31-38.

[28] 涂修元,吴学明,陶庆才.论我国天然气中汞分布的几个特征[C]//中国石油学会石油地质委员会，有机地化和陆相生油.北京:石油工业出版社,1986:305-314.

[29] WILHELM S M.Estimate of mercury emissions to the atmosphere from petroleum[J].Environ Sci Technol,2001,35:4704-4710.

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