天然气地球化学

过渡金属对有机质热解生烃过程的影响

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  • [1]北京科技大学, 北京100083; [2]石油勘探研究院廊坊分院, 河北廊坊065007;

网络出版日期: 2004-06-20

CATALYTIC EFFECTS OF TRANSITIONAL METALS ON THE GENERATION OF HYDROCARBON IN ORGANIC MATTER

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  • 1.Beijing University of Science and Technology, Beijing 100083, China;2. Langfang Branch Research Institute of Petroleum Exploration and Development, Langfang 065007,China

Online published: 2004-06-20

摘要

利用热模拟实验, 探讨了过渡金属对有机质(胆甾醇和正十六烷) 热解生烃过程的影响。实验结果表明: 过渡金属的存在降低了有机质热解成烃的表观活化能, 使得生烃温度提前; 过渡金属的存在改变了热解产物的组成, 使饱和烃含量相对增加。认为过渡金属对低温下有机质成烃起着至关重要的作用。

本文引用格式

宁占武;王卫华;温美娟;李 剑; . 过渡金属对有机质热解生烃过程的影响[J]. 天然气地球科学, 2004 , 15(3) : 317 -319 . DOI: 10.11764/j.issn.1672-1926.2004.03.317

Abstract

The effect s of t ran sit ional m etals on the generat ion of hydrocarbon pyro lysised f rom o rgan ic\r\nm at ter are invest igated w ith sim u lat ion experim en t. The resu lt s show ed that the apparen t act ivat ion\r\nenergy as w ell as the temperatu re of the generat ion of hydrocarbon decrease in p resence of the t ran sit ional\r\nm etals. A t the sam e t im e, the p roduct compo sit ion changed and the con ten t of satu rat ion hydrocarbon\r\nincreased.

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