天然气地球科学 ›› 2019, Vol. 30 ›› Issue (12): 1771–1781.doi: 10.11764/j.issn.1672-1926.2019.10.014

• 非常规天然气 • 上一篇    

通化盆地下白垩统亨通山组泥页岩储层特征

王丹丹1,2(),周新桂1,刘丽红1(),李世臻1,张交东1,张文浩1,刘卫彬1,刘旭锋1,曾秋楠1   

  1. 1. 中国地质调查局油气资源调查中心,北京 100083
    2. 中国地质调查局非常规油气地质重点实验室,北京100083
  • 收稿日期:2019-09-11 修回日期:2019-10-08 出版日期:2019-12-10 发布日期:2020-03-25
  • 通讯作者: 刘丽红 E-mail:ddwangcn@163.com;liulihong713@163.com
  • 作者简介:王丹丹(1982-),女,山东菏泽人,高级工程师,博士,主要从事油气地质调查综合研究.E-mail:ddwangcn@163.com.
  • 基金资助:
    中国地质调查局项目“吉林东部地区油气基础地质调查”(12120115001701);“松辽东部外围断陷盆地群油气基础地质调查”(DD20160165);国家自然科学基金项目“埋藏条件下碳酸盐岩储层孔隙充填与保存机理研究”(41802173)

Study on the shale reservoirs characteristics in the Lower Cretaceous Hengtongshan Formation, Tonghua Basin

Dan-dan Wang1,2(),Xin-gui Zhou1,Li-hong Liu1(),Shi-zhen Li1,Jiao-dong Zhang1,Wen-hao Zhang1,Wei-bin Liu1,Xu-feng Liu1,Qiu-nan Zeng1   

  1. 1. Oil & Gas Survey, China Geological Survey, Beijing 100083, China
    2. Key Laboratory of Unconventional Oil & Gas Geology, Beijing 100083,China
  • Received:2019-09-11 Revised:2019-10-08 Online:2019-12-10 Published:2020-03-25
  • Contact: Li-hong Liu E-mail:ddwangcn@163.com;liulihong713@163.com

摘要:

通化盆地下白垩统亨通山组油气显示好,具有良好的常规和非常规油气勘探前景,但目前缺乏系统总结,特别是对亨通山组泥页岩储层特征的认识尚未开展。以通化盆地首次钻遇油气显示的通地1井岩心为研究对象 ,系统开展了X?射线衍射、扫描电镜、液氮吸附等分析测试。研究结果表明:通化盆地亨通山组泥页岩脆性矿物含量为58.2%,石英脆度为35.4%,有利于压裂改造;孔隙类型主要为有机质孔、微裂缝、粒内孔和粒间孔,其中粒内溶蚀孔最为发育,粒间孔次之;泥页岩孔径分布较复杂,主要分布在2~60nm之间,以中孔为主,其次为微孔和大孔;中孔提供了90.87%的孔隙体积和85.74%的比表面积,是页岩气赋存的主要载体。对影响亨通山组泥页岩孔隙结构的因素进行了探讨,认为有机质丰度和显微组分对该地区孔隙的影响较为明显。

关键词: 泥页岩, 储层特征, 液氮吸附, 扫描电镜, 通化盆地

Abstract:

Good hydrocarbon shows have been found in the Lower Cretaceous Hengtongshan Formation of the Tonghua Basin, and it has good prospects for conventional and unconventional oil and gas exploration. However, currently no systematic summary, especially the study on the characteristics of shale reservoirs in Low Cretaceous Hengtongshan Formation in the Tonghua Basin has been carried out. In this study, we took the core of Tongdi No.1 drilling well with oil and gas shows as the study object, and used the methods of organic geochemistry, X-ray diffraction, scanning electron microscopy, liquid nitrogen adsorption and other analytical methods to study the mineral composition and pore types of shale. The results show that: the brittle mineral content of shale from Hengtongshan Formation in the Tonghua Basin is 58.2%, and the quartz brittleness is 35.4%, which is conducive to fracturing; the main pore types include organic pores, microcracks, intragranular pores and intergranular pores. Among them, intragranular dissolution pores are most developed, while intergranular pores are second; the pore size distribution of shale is complex, mainly distributed between 2nm and 60nm, mainly in mesopores, followed by micropores and macropores; the mesopores provide a volume of 90.87% and a specific surface area of 85.74%, and this is the main carrier of the shale gas. In addition, this paper also discusses the factors affecting the pore structure of Hengtongshan Formation shale, It is found that the abundance of organic matter and the microscopic composition have obvious influence on the pores in the study area.

Key words: Shale, Reservoir characteristics, Liquid nitrogen adsorption, Scanning electron microscope, Tonghua Basin

中图分类号: 

  • TE122.2+3

图1

通化盆地构造特征及采样位置(据文献[9]修改)"

图2

通化盆地下白垩统亨通山组泥页岩矿物成分组成(偶数号样品引自文献[9])"

表1

通化盆地亨通山组泥页岩微观孔隙结构参数及有机地球化学参数"

样品号 TD1 TD5 TD7 TD11 TD15 TD19
深度/m 216 293.3 326.6 425.7 584.1 587.8
岩性 泥岩 泥岩 泥岩 泥岩 泥岩 泥岩
TOC/% 0.70 1.49 1.77 1.21 1.26 1.66
T max/℃ 441 459 455 462 466 458
R O/% 1.54 1.08 1.06 1.09 1.16 1.31
BJH总孔容/(cm3/g) 0.019 0.008 0.003 0.017 0.008 0.010
BET比表面积/(m2/g) 17.523 5.741 2.677 17.374 7.447 11.029
平均孔径/(nm) 5.435 7.868 5.877 4.881 5.771 5.385
微孔/(<2nm) 孔容/(cm3/g) 0.019 0.008 0.003 0.016 0.008 0.010
比表面积/(m2/g) 13.709 4.282 1.999 13.497 5.700 7.304
中孔/(2~50nm) 孔容/(cm3/g) 0.210 0.107 0.033 0.172 0.089 0.101
比表面积/(m2/g) 81.711 30.561 12.117 76.627 35.113 41.466
大孔/(>50nm) 孔容/(cm3/g) 0.002 0.002 0.000 0.001 0.001 0.001
比表面积/(m2/g) 0.121 0.100 0.026 0.080 0.055 0.060
各孔段体积比/% <2nm 8.07 7.20 8.11 8.68 8.40 8.77
2~50nm 91.12 91.47 90.81 90.67 90.74 90.42
>50nm 0.81 1.33 1.08 0.65 0.86 0.81
各孔段比表面积比/% <2nm 14.35 12.26 14.14 14.96 13.95 14.96
2~50nm 85.52 87.46 85.68 84.95 85.92 84.92
>50nm 0.13 0.29 0.18 0.09 0.13 0.12

图3

通化盆地亨通山组泥页岩石英脆度、碳酸盐脆度与总脆度关系"

图4

通化盆地亨通山组泥页岩与北美页岩矿物含量对比图(底图据文献[17]修改)"

图5

通化盆地亨通山组泥页岩主要孔隙类型及分布 (a)有机质孔,425.7m,0.055~0.354μm;(b)有机质孔,216m,0.052~0.225μm;(c)有机质孔,587.8m,0.090~0.980μm;(d)有机质与矿物颗粒间微裂缝,326.6m,0.160~0.706μm;(e)有机质内微裂隙,425.7m,0.027~0.169μm;(f)矿物溶蚀孔隙、粒间孔,216m,0.335~5.364μm;(g)矿物溶蚀孔隙,584.1m, 0.107~0.509μm;(h)黄铁矿晶间孔、铸模孔,293.3m ,0.081~1.530μm;(i)矿物粒间孔隙、溶蚀孔隙,293.3m ,0.122~1.213μm"

图6

通化盆地亨通山组泥页岩氮气吸附曲线 (a)TD1,黑色泥岩,216.0m;(b)TD5,黑色泥岩,293.3m;(c)TD7,黑色泥岩,326.7m;(d)TD11,黑色泥岩,425.7m;(e)TD51,灰黑色粉砂质泥岩,558.4m;(f)TD19,黑色粉砂质泥岩,587.8m"

图7

通化盆地亨通山组泥页岩孔径分布曲线"

图8

亨通山组泥页岩矿物成分含量与孔隙度、比表面和孔容的关系"

图9

通化盆地亨通山组TOC、R O与比表面积和总孔容的关系"

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