彭威龙,胡国艺,刘全有,贾楠,房忱琛,龚德瑜,于聪,吕玥,王鹏威,冯子齐
Peng Wei-long,Hu Guo-yi,Liu Quan-you,Jia Nan,Fang Chen-chen,Gong De-yu,Yu Cong,Lü Yue,Wang Peng-wei,Feng Zi-qi
摘要: 系统梳理了热模拟实验研究现状,提出了3个值得关注的问题以及5个重要的发展方向。按照体系封闭性分类是目前最为广泛使用的一类热模拟实验分类方案。不同的热模拟实验体系各具特点,可以根据不同的实验目的来选取合适的热模拟实验体系。封闭实验体系更加适合于腐殖型烃源岩的热模拟实验,开放体系的在线分析产物在研究易挥发组分时具有独特的优势,半开放体系是最为接近实际地质体中烃源岩热演化的热模拟体系。热模拟实验中3个值得关注的问题:一是水对热模拟实验的影响;二是热模拟实验中是否可以得出费托合成以外的有说服力的烷烃气碳同位素倒转;三是在进行热模拟实验研究生烃动力学时一定要结合实际地质背景建立模型。热模拟实验5个重要的发展方向:一是有水参与的相对低温长时间的热模拟实验研究;二是与非常规油气形成相关热模拟实验研究;三是热模拟实验中烃源岩孔隙微裂缝发育以及流体排出相互耦合关系相关的研究;四是碳酸盐岩烃源岩相关热模拟实验研究;五是与异常压力相关的热模拟实验研究。
中图分类号:
[1]Tissot B P,Welte D H.Petroleum Formation and Occurrence[M].Second ed.Berlin,Heidelberg,New York:Springer-Verlag,1984:74-266.
[2]Hunt J.Petroleum Geochemistry and Geology[M].New York:W H Freeman and Company,1979:67-178. [3]Xiao Zhihua,Hu Guoyi,Li Zhisheng.An analysis of characteristics of hydrocarbon generation from pyrolysis of source rock[J].Natural Gas Geoscience,2008,19(4):545-547. 肖芝华,胡国艺,李志生.从烃源岩热模拟实验探讨其生烃特征[J].天然气地球科学,2008,19(4):545-547. [4]Lopatian N V.Temperature and geologic time as factors in coalification[J].Izvestiya Akademii Nauk SSSR Seriya Geologicheskaya,1971,3:95-106. [5]Mi Jingkui,Zhang Shuichang,Wang Xiaomei.Comparison of different hydrocarbon generation simulation approaches and key technique[J].Experimental Petroleum & Geology,2009,31(4):409-414. 米敬奎,张水昌,王晓梅.不同类型生烃模拟实验方法对比与关键技术[J].石油实验地质,2009,31(4):409-414. [6]Tang Qingyan,Zhang Mingjie,Zhang Tongwei,et al.A review on pyrolysis experimentation on hydrocarbon generation[J].Journal of Southwest Petroleum University:Science & Technology Edition,2013,35(1):52-62. 汤庆艳,张铭杰,张同伟,等.生烃热模拟实验方法评述[J].西南石油大学学报:自然科学版,2013,35(1):52-62. [7]Jiang Feng,Zhang Youlian,Du Jianguo,et al.Advance of pyrolysis experimentation on hydrocarbon genesis[J].Advance in Earth Sciences,1996,11(5):453-459. 姜峰,张友联,杜建国,等.油气生成热模拟实验研究进展[J].地球科学进展,1996,11(5):453-459. [8]Lu Shuangfang,Wang Min,Wang Yuewen,et al.Comparison of simulation result from the closed and open experimental systems and its significance[J].Acta Sedmentologica Sinica,2006,24(2):282-288. 卢双舫,王民,王跃文,等.密闭体系与开放体系模拟实验结果的比较研究及其意义[J].沉积学报,2006,24(2):282-288. [9]Wang Min,Lu Shuangfang,Wang Dongliang,et al.Characteristics and kinetic of coal pyrolysates with different thermal simulation apparatuses[J].Acta Petrolei Sinica,2011,32(5):806-814. 王民,卢双舫,王东良,等.不同热模拟实验煤热解产物特征及动力学分析[J].石油学报,2011,32(5):806-814. [10]Guo Shaobin,Mao Wenjing,Ma Xiao.Thermal simulation experiment study of the hydrocarbon generation of low maturity shale[J].Earth Science Frontiers,2017,24(6):365-369.郭少斌,毛文静,马啸.低熟页岩生烃特征的热模拟实验研究[J].地学前缘,2017,24(6):365-369. [11]Mao Rong,Mi Jingkui,Zhang Shuichang,et al.Study on the hydrocarbon generation characteristics of different coaly source rocks by gold-tube pyrolysis experiments[J].Natural Gas Geoscience,2012,23(6):1127-1134. 毛榕,米敬奎,张水昌,等.不同煤系源岩生烃特征的黄金管热模拟实验对比研究[J].天然气地球科学,2012,23(6):1127-1134. [12]Chen Jianping,Zhao Changyi,He Zhonghua.Criteria for evaluating the hydrocarbon generating potential of organic matter in coal measures[J].Petroleum Exploration and Development,1997,24(1):1-5. 陈建平,赵长毅,何忠华.煤系有机质生烃潜力评价标准探讨[J].石油勘探与开发,1997,24(1):1-5. [13]Gao Gang,Liu Guangdi.Quantitative modeling of hydrocarbon generation in resource assessment[J].Natural Gas Industry,2006,26(10):6-8. 高岗,柳广弟.资源评价中油气生成定量模型的建立[J].天然气工业,2006,26(10):6-8. [14]Tong Zhigang,Xi Xiaoying,Wang Peng,et al.Reevaluation of hydrocarbon resource potential in Nanwu Sag of the South Yellow Sea basin:Based on the numerical modeling method of hydrocarbon generation kinetics[J].China Offshore Oil and Gas,2017,29(1):23-28. 仝志刚,席小应,王鹏,等.南黄海盆地南五凹油气资源潜力再评价——基于生烃动力学数值模拟方法[J].中国海上油气,2017,29(1):23-28. [15]Zou Yanrong,Shuai Yanhua,Kong Feng,et al.Experiments on petroleum generation-considerations and outlook[J].Experimental Petroleum & Geology,2004,26(4):375-382. 邹艳荣,帅燕华,孔枫,等.油气生成过程实验研究的思考与展望[J].石油实验地质,2004,26(4):375-382. [16]Jia Wanglu,Shuai Yanhua,Peng Ping’an,et al.Kinetic study of hydrocarbon generation of oil asphaltene from Lunnan area,Tabei Uplift[J].Chinese Science Bullentin,2004,49(1):76-80. 贾望鲁,帅燕华,彭平安,等.塔北轮南地区原油沥青质生烃动力学研究[J].科学通报,2004,49(1):76-80. [17]He Kun,Zhang Shuichang,Wang Xiaomei,et al.Hydrocarbon generation kinetics of type I organic matters in the Cretaceous lacustrine sequences,Songliao Basin[J].Oil & Gas Geology,2014,35(1):42-49. 何坤,张水昌,王晓梅,等.松辽盆地白垩系湖相I型有机质生烃动力学[J].石油与天然气地质,2014,35(1):42-49. [18]Xiong Y,Geng A,Wang Y,et al.Kinetic simulating experiment on the secondary hydrocarbon generation of kerogen[J].Science in China:Series D,2002,45(1):13-20. [19]Henderson W,Eglinton G,Simmods P,et al.Thermal alteration as contributory process to genesis of petroleum[J].Nature,1968,209:1012-1016. [20]Brooks J D,Smith J W.The diagenesis of plant liquids during the formation of coal,petroleum and natural gas-Ⅱ .Coalification and the formation of oil and gas in Gippsland Basin[J].Geochimica et Cosmochim Acta,1969,33(10):1183-1194. [21]Mi J,Zhang S,Chen J,et al.Upper thermal maturity limit for gas generation from humic coal[J].International Journal of Coal Geology,2015,152:123-131. [22]Mi J,Zhang S,He K.Experimental investigations about the effect of pressure on gas generation from coal[J].Organic Geochemistry,2014,74:116-122. [23]Liu Q,Liu W,Dai J.Characterization of pyrolysates from maceral components of Tarim coals in closed system experiments and implications to natural gas generation[J].Organic Geochemistry,2007,38(6):921-934. [24]Behar F,Vandenbroucke M,Teermann S C,et al.Experimental simulation of gas generation from coals and a marine kerogen[J].Chemical Geology,1995,126(3/4):247-260. [25]Bertrand P,Behar F,Durand B.Composition of potential oil from humic coals in relation to their petrographic nature[J].Organic Geochemistry,1986,10(1):601-608. [26]Boreham C J,Powell T G.Variation in pyrolysate composition of sediments from the Jurassic Walloon coal measures,eastern Australia as a function of thermal maturation[J].Organic Geochemistry,1991,17(6):723-733. [27]He K,Zhang S,Mi J,et al.The evolution of chemical groups and isotopic fractionation at different maturation stages during lignite pyrolysis[J].Fuel,2018,211:492-506. [28]Wang Yutao.Biomarkers from pindiquan (P2) shale by thermal modelling experiments[J].Xinjiang Petroleum Geology,1992,13(3):240-250. 王屿涛.平地泉组泥岩热模拟实验中的生物标志化合物[J].新疆石油地质,1992,13(3):240-250. [29]Lu Hongxuan,Meng Zifang,Li Bin,et al.Effect of uranium substance on hydrocarbon generation from mudstone by hydrous pyrolysis[J].Acta Sedmentologica Sinica,2008,26(2):324-329. 卢红选,孟自芳,李斌,等.含铀物质对泥岩有机质热模拟生烃产物的影响[J].沉积学报,2008,26(2):324-329. [30]Liang Chunxiu,Wei Zhiping,Mao Chaolin,et al.Comparison of geochemistry character between mudstones from deep lacustrine facies and coal measures by hydrous pyrolysis[J].Acta Sedmentologica Sinica,2002,20(1):165-168. 梁春秀,魏志平,毛超林,等.加水热模拟中深湖与煤系泥岩地化特征比较[J].沉积学报,2002,20(1):165-168. [31]Reynolds J G,Crawford R W,Burnham A L.Analysis of oil shale and petroleum source rock pyrolysis by triple quadrupole mass spectrometry:Comparisons of gas evolution at the heating rate of 10℃/min[J].Energy & Fuels,1991,5(3):507-523. [32]Kong Qingfen,Wang Keren.Thermal simulation of Ordovician source rock of foreland basin in western Ordos Basin[J].Natural Gas Geoscience,2006,17(2):187-191. 孔庆芬,王可仁.鄂尔多斯盆地西缘奥陶系烃源岩热模拟试验研究[J].天然气地球科学,2006,17(2):187-191. [33]Behar F,Kressmann S,Rudkiewicz L,et al.Experimental simulation in a confined system and kinetic modelling of kerogen and oil cracking[J].Organic Geochemistry,1991,19(1-3):173-189. [34]Berner U,Faber E.Expirical carbon isotope/maturity relationships for gases from algal kerogens and terrigenous organic matter,based on dry,open-system pyrolysis[J].Organic Geochemistry,1996,24(10/11):947-955. [35]Behar F,Gillaizeau B,Derenne S,et al,Nitrogen distribution in the pyrolysis products of a type Ⅱ kerogen (Cenomanian,Italy),timing of molecular nitrogen production versus other gases[J].Energy & Fuels,2000,14(2):431-440. [36]Gao Shengjun,Chen Yicai,Li Yanjun,et al.Pyrolysis on crude oil and characteristics of Sha 4 member cracking gas,Dongying Depression[J].Natural Gas Geoscience,2009,20(1):32-35. 高生军,陈义才,李延钧,等.东营凹陷沙四段原油裂解热模拟实验及产物特征[J].天然气地球科学,2009,20(1):32-35. [37]Chen Julin,Zhang Min.Rearranged hopanes compositions in pyrolysis experiment of crude oil and geochemical significance[J].Geoscience,2016,30(4):871-879. 陈菊林,张敏.原油热模拟实验中重排藿烷类变化特征及其意义[J].现代地质,2016,30(4):871-879. [38]Zhang Dianwei,Liu Wenhui,Liu Quanyou,et al.The influence of coal formation maceral to natural gases carbon isotopic composition and its application[J].Natural Gas Geoscience,2005,16(6):792-796. 张殿伟,刘文汇,刘全有,等.煤系源岩显微组分对天然气碳同位素组成影响的应用[J].天然气地球科学,2005,16(6):792-796. [39]Cai Yuwen,Zhang Shuichang,He Kun,et al.Effects of inorganic minerals in source rocks on hydrocarbon generation from organic matter[J].Experimental Petroleum & Geology,2017,39(2):253-260. 蔡郁文,张水昌,何坤,等.烃源岩中无机矿物对有机质生烃的影响[J].石油实验地质,2017,39(2):253-260. [40]Cai Yuwen,Wang Huajian,Wang Xiaomei,et al.Formation conditions and main controlling factors of uranium in marine source rocks[J].Advances in Earth Science,2017,32(2):199-208. 蔡郁文,王华建,王晓梅,等.铀在海相烃源岩中富集的条件及主控因素[J].地球科学进展,2017,32(2):199-208. [41]Cai Yuwen,Zhang Shuichang,He Kun,et al.The effect of magnetite on the products and isotopic fractions of gaseous hydrocarbons[J].Natural Gas Geoscience,2017,28(2):331-340. 蔡郁文,张水昌,何坤,等.磁铁矿对有机质生烃及同位素分馏的影响[J].天然气地球科学,2017,28(2):331-340. [42]He K,Zhang S,Mi J,et al.Pyrolysis involving n-hexadecane,water and minerals:Insight into the mechanisms and isotope fractionation for water-hydrocarbon reaction[J].Journal of Analytical and Applied Pyrolysis,2018,130:198-208. [43]Sun Lina,Zhang Mingfeng,Wu Chenjun,et al.The effect of water medium on the products of different pyrolysis system[J].Natural Gas Geoscience,2015,26(3):524-532. 孙丽娜,张明峰,吴陈君,等.水对不同生烃模拟实验系统产物的影响[J].天然气地球科学,2015,26(3):524-532. [44]Lewan M D,Roy S.Role of water in hydrocarbon generation from type I kerogen in Mahogany oil shale of the Green River Formation[J].Organic Geochemistry,2011,42(1):31-41.[45]Zheng Lunju,He Sheng,Qin Jianzhong,et al.Formation water of near-critical properties and its effects on the processes of hydrocarbon generation and expulsion[J].Earth Science:Journal of China University of Geoscience,2011,36(1):83-92. 郑伦举,何生,秦建中,等.近临界特性的地层水及其对烃源岩生排烃过程的影响[J].地球科学:中国地质大学学报,2011,36(1):83-92. [46]Savage P E.Organic chemical reactions in supercritical water[J].Chemical Reviews,1999,99(2):603-622. [47]Lewan M D.Experiments on the role of water in petroleum formation[J].Geochimica et Cosmochimica Acta,1997,61(17):3691-3723. [48]Yang Tangyu,Wang Hanyun.Simulation experiment of thermo-coalificative natural gas genesis and its significance[J].Petroleum Exploration and Development,1983,10(6):29-36.杨天宇,王涵云.褐煤干酪根煤化作用成气的模拟实验及其地质意义[J].石油勘探与开发,1983,10(6):29-36. [49]Wang Hanyun,Yang Tianyu.Simulation experiment of crude oil pyrolysis gas[J].Natural Gas Industry,1982,2(3):28-33. 王涵云,杨天宇.原油热解成气模拟实验[J].天然气工业,1982,2(3):28-33. [50]Zhang Lijie,Wang Benshan,Shi Jiyang,et al.A discussion on several major problems of petroleum geochemistry from the results of simulating experiment[J].Geochimica,1987,2:113-112. 张丽洁,汪本善,史继扬,等.从模拟实验结果讨论石油地球化学中的几个重要问题[J].地球化学,1987,2:113-112. [51]Mi J,Zhang S,Su J,et al.The upper thermal maturity limit of primary gas generated from marine organic matters[J].Marine and Petroleum Geology,2018,89:120-129. [52]He K,Zhang S,Mi J,et al.The speciation of aqueous sulfate and its implication on the initiation mechanisms of TSR at different temperatures[J].Marine and Petroleum Geology,2014,43(4):121-131. [53]Zhang S,Mi J,He K,et al.Synthesis of hydrocarbon gases from four different carbon sources and hydrogen gas using a gold-tube system by Fischer-Tropsch method[J].Chemical Geology,2013,(349/350):27-35. [54]Takahashi K U,Suzuki N.Semi-open and closed system pyrolysis of Paleogene coal for evaluating the timing of hydrocarbon gas expulsion[J].International Journal of Coal Geology,2017,178:100-109. [55]Fusetti L,Behar F,Bounaceur R,et al.New insights into secondary gas generation from the thermal cracking of oil:Methylated monoaromatics.A kinetic approach using 1,2,4-trimethylbenzene.Part I:A mechanistic kinetic model[J].Organic Geochemistry,2010,41(2):146-167. [56]Fusetti L,Behar F,Lorant F,et al.New insights into secondary gas generation from the thermal cracking of oil:Methylated monoaromatics.A kinetic approach using 1,2,4-trimethylbenzene.Part III:An isotopic fractionation model[J].Organic Geochemistry,2010,41(5):431-436. [57]Cramer B,Faber E,Gerling D,et al.Reaction kinetics of stable carbon isotope in natural gas-insights from dry,open system pyrolysis experiments[J].Energy and Fuels,2001,15(3):517-532. [58]Mi Jingkui,Dai Jinxing,Zhang Shuichang,et al.Study on the gas generating ability of coal in different systems[J].Natural Gas Geoscience,2007,18(2):245-248. 米敬奎,戴金星,张水昌,等.煤在2种不同体系的生气能力研究[J].天然气地球科学,2007,18(2):245-248. [59]Halla P A,Watson A F R,Garner G V,et al.An investigation of micro-scale sealed vessel thermal extraction gas chromatography-mass spectrometry (MSSV-GCMS) and micro-scale sealed vessel pyrolysis-gas chromatography-mass spectrometry applied to a standard reference material of an urban dust rorganics[J].The Science of the Total Environment,1999,1(235):269-276. [60]Chen Ruiyin,Wang Huitong,Chen Jianping,et al.An experimental method to evaluate the hydrocarbon generation and expulsion efficiency in the Songliao Baisn[J].Natural Gas Geoscience,2015,26(5):915-921. 陈瑞银,王汇彤,陈建平,等.实验方法评价松辽盆地烃源岩的生排烃效率[J].天然气地球科学,2015,26(5):915-921. [61]Hill R J,Zhang E,Katz B J,et al.Modeling of gas generation from the Barnett Shale,Fort Worth Basin,Texas[J].American Association of Petroleum Geologists Bulletin,2007,91(4):501-521. [62]Lewan M D,Winters J C,McDonald J H.Generation of oil-like pyrolyzates from organic-rich shales[J].Science,1979,203(4383):897-899. [63]Tian Yiling,Feng Jijun,Qin Ying,et al.The properties and chemical application of supercritical water[J].Chemistry,2002,65(6):396-402. 田宜灵,冯季军,秦颖,等.超临界水的性质及其在化学反应中的应用[J].化学通报,2002,65(6):396-402. [64]Wang Xiaofeng,Liu Wenhui,Xu Yongchang,et al.Thermal simulation experimental study on the effect of water on the formation of gaseous hydrocarbon in organic matter during the thermal evolution[J].Progress in Natural Science,2006,16(10):1275-1281. 王晓锋,刘文汇,徐永昌,等.水在有机质形成气态烃热演化中作用的热模拟实验研究[J].自然科学进展,2006,16(10):1275-1281. [65]Qin Jianzhong,Liu Jingwang,Liu Baoquan,et al.Hydrocarbon yield and geochemical parameters affected by heating time and added water amount in the simulation test[J].Experimental Petroleum & Geology,2002,24(2):152-157. 秦建中,刘井旺,刘宝泉,等.加温时间、加水量对模拟实验油气产率及地化参数的影响[J].石油实验地质,2002,24(2):152-157. [66]Dai J,Xia X,Qin S,et al.Origins of partially reversed alkane δ13C values for biogenic gases in China[J].Organic Geochemistry,2004,35(4):405-411. [67]Dai J,Ni Y,Huang S,et al.Secondary origin of negative carbon isotopic series in natural gas[J].Journal of Natural Gas Geoscience,2016,1:1-7. [68]Tilley B,Muehlenbachs K.Isotope reversals and universal stages and trends of gas maturation in sealed,self-contained petroleum systems[J].Chemical Geology,2013,339:194-204. [69]Xia X,Chen J,Braun R,et al.Isotopic reversals with respect to maturity trends due to mixing of primary and secondary products in source rocks[J].Chemical Geology,2013,339:205-212. [70]Burruss R C,Laughrey C D.Carbon and hydrogen isotopic reversals in deep basin gas:evidence of limits to the stability of hydrocarbons[J].Organic Geochemistry,2009,41(12):1285-1296. [71]Dai J,Ni Y,Gong D,et al.Geochemical characteristics of gases from the largest tight sand gas field (Sulige) and shale gas field (Fuling) in China[J].Marine and Petroleum Geology,2017,79:426-438. [72]Ni Y,Jin Y.Carbon isotopic fractionations during the Fischer-Tropsch synthesis[J].Petroleum Exploration and Development,2011,38(2):249-256. [73]Chen Anding,Zhang Wenzheng,Xu Yongchang.Isotopic characteristics and application of thermal simulation results of hydrocarbon generation in sedimentary rocks[J].Science in China:Series B,1993,23(2):209-217. 陈安定,张文正,徐永昌.沉积岩成烃热模拟实验产物的同位素特征及应用[J].中国科学:B辑,1993,23(2):209-217. [74]Lu S,Zhong N,Xue H,et al.Chemical kinetics study of hydrocarbon regeneration from organic matter in carbonate source rocks and its significance[J].Science in China Series:D-Earth Sciences,2007,50(4):536-543. [75]Wang Yunpeng,Zhao Changyi,Wang Zhaoyun,et al.Kinetic method for determining the main gas generation period of marine organic matters and its application[J].Petroleum Exploration and Development,2005,32(4):153-158. 王云鹏,赵长毅,王兆云,等.利用生烃动力学方法确定海相有机质的主生气期及其初步应用[J].石油勘探与开发,2005,32(4):153-158. [76]Liu Dayong,Peng Ping’an,Lin Huixi,et al.Application of hydrocarbon generation kinetics and isotopic distillation kinetics to the study of hydrocarbon source rocks[J].Geological Bulletin of China,2006,25(9/10):1201-1204. 刘大永,彭平安,林会喜,等.生烃动力学、同位素动力学方法在烃源岩研究中的应用[J].地质通报,2006,25(9/10):1201-1204. [77]Rao Song,Hu Shengbiao,Wang Jiyang.Hydrocarbon generation kinetic parameters of organic matter:review and outlook[J].Progress in Geophys,2010,25(4):1424-1432. 饶松,胡圣标,汪集旸.有机质生烃动力学参数研究进展:回顾和展望[J].地球物理学进展,2010,25(4):1424-1432. [78]Hao Fang,Zou Huayao,Wang Minfang,et al.Research advances and frontier areas of mechanisms of petroleum accumulation[J].Geological Science and Technology Information,2002,21(4):7-14. 郝芳,邹华耀,王敏芳,等.油气成藏机理研究进展和前沿研究领域[J].地质科技情报,2002,21(4):7-14. [79]Hao Fang,Zou Huayao,Ni Jianhua,et al.Evolution of overpressured systems in sedimentary basins and conditions for deep oil/gas accumulation[J].Earth Science:Journal of China University of Geosciences,2002,27(5):610-615. 郝芳,邹华耀,倪建华,等.沉积盆地超压系统演化与深层油气成藏条件[J].地球科学:中国地质大学学报,2002,27(5):610-615. [80]Zou C,Zhai G,Zhang G,et al.Formation,distribution,potential and prediction of global conventional and unconventional hydrocarbon resources[J].Petroleum Exploration and Development,2015,42(1):14-28. [81]Zou C,Yang Z,Zhang G,et al.Conventional and unconventional petroleum “orderly accumulation”:Concept and practical significance[J].Petroleum Exploration and Development,2014,41(1):14-27. [82]Peng Weilong,Hu Guoyi,Huang Shipeng,et al.Natural gas geochemical characteristics and genetic analysis:A case study of the Dongsheng gas field in the Ordos Basin of China[J].Journal of China University of Mining & Technology,2017,46(1):74-84. 彭威龙,胡国艺,黄士鹏,等.天然气地球化学特征及成因分析——以鄂尔多斯盆地东胜气田为例[J].中国矿业大学学报,2017,46(1):74-84. [83]Peng W,Hu G,Feng Z,et al.Origin of Paleogene natural gases and discussion of abnormal carbon isotopic composition of heavy alkanes in the Liaohe Basin,NE China[J].Marine and Petroleum Geology,2018,92:670-684. [84]Liu Guangdi.Petroleum Geology[M].Beijing:Petroleum Industry Press,1999:1-345. 柳广弟.石油地质学[M].北京:石油工业出版社,1999:1-345. [85]He Sheng,Ye Jiaren,Xu Sihuang,et al.Oil and Gas Geology[M].Wuhan:China University of Geosciences Press,2010:1-370. 何生,叶加仁,徐思煌,等.石油及天然气地质学[M].武汉:中国地质大学出版社,2010:1-370. [86]Qin Jianzhong,Liu Baoquan,Guo Jianying,et al.Discussion on the evaluation standards of carbonate source rocks[J].Experimental Petroleum & Geology,2004,26(3):281-286. 秦建中,刘宝泉,国建英,等.关于碳酸盐烃源岩的评价标准[J].石油实验地质,2004,26(3):281-286. [87]Qin Jianzhong,Tenger,Fu Xiaodong.Study of forming condition on marine excellent source rocks and its evaluation[J].Experimental Petroleum & Geology,2009,31(4):366-372. 秦建中,腾格尔,付小东.海海相优质烃源层评价与形成条件研究[J].石油实验地质,2009,31(4):366-372. [88]Qin Jianzhong,Shen Baojian,Fu Xiaodong,et al.Ultramicroscopic organic petrology and potential of hydrocarbon Generation and expulsion of quality marine source rocks in South China[J].Oil & Gas Geology,2010,31(6):826-837. 秦建中,申宝剑,付小东,等.中国南方海相优质烃源岩超显微有机岩石学与生排烃潜力[J].石油与天然气地质,2010,31(6):826-837. [89]Li Jian,Jiang Zhusheng,Luo Xia,et al.Discussion on quantitative evaluation criterion for high-matured carbonate gas source rocks[J].Oil & Gas Geology,1999,20(4):354-356. 李剑,蒋助生,罗霞,等.高成熟碳酸盐气源岩定量评价标准的探讨[J].石油与天然气地质,1999,20(4):354-356. [90]Zhong Ningning,Qin Yong.Organic Petrology of Carbonate Rock[M].Beijing:Science Press,1995:130-155. 钟宁宁,秦勇.碳酸盐岩有机岩石学[M].北京:科学出版社,1995:130-155. [91]Zhao W,Wang Z,He H,et al.Gas formation mechanism of marine carbonate source rocks in China[J].Science in China:Series D,2005,48(4):441-453. [92]Zhao Wenzhi,Wang Zecheng,Hu Suyun,et al.Large-scale hydrocarbon accumulation factors and characteristics of marine carbonate reservoirs in three large onshore cratonic basins in China[J].Acta Petrolei Sinica,2012,33(S2):1-10. 赵文智,王泽成,胡素云,等.中国陆上三大克拉通盆地海相碳酸盐岩油气藏大型化成藏条件与特征[J].石油学报,2012,33(S2):1-10. [93]Hao Fang,Zou Huayao,Fang Yong,et al.Kinetics of organic matter maturation and hydrocarbon generation in overpressure environment[J].Acta Petrolei Sinica,2006,27(5):9-18. 郝芳,邹华耀,方勇,等.超压环境有机质热演化和生烃作用机理[J].石油学报,2006,27(5):9-18. [94]Hao F,Jiang J,Zou H,et al.Differential retardation of organic matter maturation by overpressure[J].Science in China:Series D,2004,47(9):783-793. |
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