南方海相页岩物质组成与孔隙微观结构耦合关系

doi:10.11764/j.issn.1672-1926.2018.10.001

天然气地球科学

南方海相页岩物质组成与孔隙微观结构耦合关系

李文镖，卢双舫，李俊乾，张鹏飞，陈晨，王思远

1.中国石油大学（华东）非常规油气与新能源研究院，山东青岛 266580；
2.中国石油大学（华东）地球科学与技术学院，山东青岛 266580

收稿日期:2018-07-08 修回日期:2018-09-27 出版日期:2019-01-10
通讯作者: 李俊乾（1987-），男，河南商丘人，副教授，博士，主要从事非常规油气地质学研究. E-mail:llijunqian1987@126.com.
作者简介:李文镖（1996-），男，江西上饶人，博士研究生，主要从事页岩油气储层表征及同位素分馏效应研究.E-mail：liwenbiao1996upc@163.com.
基金资助:
国家自然科学基金（编号：41672130;41602131）；国家科技重大专项（编号：2016ZX05061-003-001）；中国石化科技项目（编号：P17027-3）联合资助.

The coupling relationship between material composition and pore microstructure of southern China marine shale

Li Wen-biao，Lu Shuang-fang，Li Jun-qian，Zhang Peng-fei，Chen Chen，Wang Si-yuan

1.Research Institute of Unconventional Oil & Gas and Renewable Energy，China University of Petroleum，Qingdao 266580，China；
2.School of Geosciences，China University of Petroleum，Qingdao 266580，China

Received:2018-07-08 Revised:2018-09-27 Online:2019-01-10

摘要/Abstract

摘要： 为研究页岩物质组成与孔隙微观结构耦合关系，对南方海相五峰组—龙马溪组30个高—过成熟页岩样品开展低温氮气吸附实验，并根据迟滞回线形态划分3类页岩。结果表明：①黏土矿物主要发育板状孔，孔径较大，从微孔（<2nm）到宏孔（>50nm）均较为发育；有机质主要发育墨水瓶状孔，主要为微孔和介孔（2~50nm）级别。②页岩比表面积主要由微孔、介孔贡献，其中微孔比表面积主要由有机质提供，黏土矿物主要提供介孔、宏孔比表面积；总孔体积主要由介孔、宏孔贡献，其中有机质主要贡献微孔、介孔体积，黏土矿物主要贡献宏孔体积。③样品普遍具有三段分形特征，且在不同孔径范围，墨水瓶状孔均要较板状孔复杂。研究成果有助于认识页岩气的储集、运移规律。

关键词: 页岩, 物质组成, 孔隙形态, 孔隙结构, 分形特征, 耦合关系

Abstract: To explore the coupling relationship between material composition and pore microstructure，30 marine shale samples with high-over maturity from the Wufeng and Longmaxi Formations，Southern China were analyzed by using nitrogen adsorption method.According to the shape of hysteresis，3 types of shales are identified.The results show that clay mineral mainly develops slit pores ranging from micropore (<2nm) to macropore (>50nm)，while organic matter mainly develops inkbottle pores with the size of mesopore (2-50nm).Whether in BET specific surface area (SSA) or total pore volume (PV)，mesopores always makes the largest contribution.Micropores make the second largest contribution to the SSA，while macropores offer moderate PV.The SSA of microporeis mainly provided by organic matter，and clay minerals mainly contribute to the SSA of mesopores and macropores.Clay minerals mainly provide macropore volume，while organic matter mainly contributes to micropore and mesopore volume.The shale samples generally show three stages of fractal characteristics，and in the range of different pore size，the inkbottle pores are more complex than slit pores.The results are helpful to understand the law of gas accumulation and migration.

Key words: Shale, Material composition, Pore shape, Pore structure, Fractal characteristics, Coupling relationship

中图分类号:

TE311

李文镖, 卢双舫, 李俊乾, 张鹏飞, 陈晨, 王思远. 南方海相页岩物质组成与孔隙微观结构耦合关系[J]. 天然气地球科学, 2019, 30(1): 27–38.

Li Wen-biao, Lu Shuang-fang, Li Jun-qian, Zhang Peng-fei, Chen Chen, Wang Si-yuan. The coupling relationship between material composition and pore microstructure of southern China marine shale[J]. Natural Gas Geoscience, 2019, 30(1): 27–38.

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