天然气地球科学 ›› 2021, Vol. 32 ›› Issue (10): 1436–1449.doi: 10.11764/j.issn.1672-1926.2021.08.006

• 综述与评述 • 上一篇    下一篇

天然气中氦资源研究现状及我国氦资源前景

陈践发1,2(),刘凯旋1,2(),董勍伟1,2,汪华3,罗冰3,戴鑫3   

  1. 1.中国石油大学(北京)油气资源与探测国家重点实验室,北京 102249
    2.中国石油大学(北京)地球科学学院,北京 102249
    3.中国石油西南油气田分公司勘探开发研究院,四川 成都 610041
  • 收稿日期:2021-07-02 修回日期:2021-07-29 出版日期:2021-10-10 发布日期:2021-10-21
  • 通讯作者: 刘凯旋 E-mail:jfchen@cup.edu.cn;1158763393@qq.com
  • 作者简介:陈践发(1961-),男,湖南耒阳人,教授,博士生导师,主要从事油气地球化学研究. E-mail: jfchen@cup.edu.cn.
  • 基金资助:
    国家科技重大专项(2016ZX05027-001-004);中国石油西南油气田分公司项目(JS2020-044)

Research status of helium resources in natural gas and prospects of helium resources in China

Jianfa CHEN1,2(),Kaixuan LIU1,2(),Qingwei DONG1,2,Hua WANG3,Bing LUO3,Xin DAI3   

  1. 1.State Key Laboratory of Petroleum Resources and Prospecting,China University of Petroleum,Beijing 102249,China
    2.College of Geosciences,China University of Petroleum,Beijing 102249,China
    3.Research Institute of Petroleum Exploration and Development,Southwest Oil and Gasfield Company,PetroChina,Chengdu 610041,China
  • Received:2021-07-02 Revised:2021-07-29 Online:2021-10-10 Published:2021-10-21
  • Contact: Kaixuan LIU E-mail:jfchen@cup.edu.cn;1158763393@qq.com
  • Supported by:
    The National Science and Technology Major Project of China(2016ZX05027-001-004);the PetroChina Southwest Oil and Gas Field Company Project(JS2020-044)

摘要:

氦气具有强化学惰性和低沸点等独有特征,在高新技术产业和科研实验中具有不可替代的作用。氦在地球上以微量组分广泛分布,但从含氦、富氦天然气藏中提取氦气仍是工业制氦的唯一途径。目前全球已发现的氦储量主要分布在美国、卡塔尔、阿尔及利亚、俄罗斯和加拿大等国,上述五国氦储量占全球总储量的92%。天然气藏中的氦气有3个主要来源:大气源、壳源和幔源。目前主要根据3He/4He值来确定氦的来源,通常大气源的3He/4He值为1.4×10-6、壳源的3He/4He值为2×10-8和幔源的3He/4He值为1.1×10-5。富氦天然气的成藏条件和成藏特征与常规天然气藏既有共性又有明显的差异,一些有利于形成大型油气藏的高生烃强度地区,反而不利于富氦、高氦气藏的形成。而生烃强度相对低的隆起区则有利于富氦、高氦气藏的形成。全球已发现的氦气资源主要分布于晚元古代—古生代地台背景下的沉积盆地,此外在中—新生代构造—岩浆活动强烈且具有古老花岗岩的基底区也是富氦气藏发育的有利区带。现有资料表明,中国四川盆地、塔里木盆地、柴达木盆地、鄂尔多斯盆地和东部中新生界含油气盆地中已发现一些富氦气藏。同时非常规天然气领域亦展现出良好的氦资源勘探前景,如渭河盆地水溶气和四川盆地页岩气。中国富氦天然气具有点多、类型多、资源前景较好的特征,但氦气资源整体研究程度很低。

关键词: 稀有气体, 氦气资源, 成因, 成藏, 资源前景

Abstract:

Helium has unique characteristics such as strong chemical inertness and low boiling point, and plays an irreplaceable role in high-tech industries and scientific research experiments. Helium is widely distributed as trace components on the earth, but the extraction of helium from helium-containing, helium-rich natural gas reservoirs is still the only way to industrially produce helium. At present, the world's discovered helium reserves are mainly distributed in the United States, Qatar, Algeria, Russia, Canada and other countries. The helium reserves of the above five countries account for 92% of the world's total reserves. There are three main sources of helium in natural gas reservoirs: atmospheric, crustal and mantle-derived. At present, the source of helium is mainly determined based on the value of 3He/4He. Generally, the 3He/4He value of atmospheric, crustal and mantle-derived helium are 1.4×10-6, 2×10-8 and 1.1×10-5, respectively. The accumulation conditions and characteristics of helium-rich natural gas have both common features and obvious differences with conventional natural gas reservoirs. Some areas with high hydrocarbon generation intensity that are conducive to the formation of large-scale oil and gas reservoirs are not conducive to the formation of helium-rich and high-helium gas reservoirs. Uplift areas with relatively low hydrocarbon generation intensity are conducive to the formation of helium-rich and high-helium gas reservoirs. The helium resources discovered in the world are mainly distributed in sedimentary basins under the platform background of the Late Proterozoic and Paleozoic. In addition, the Mesozoic-Cenozoic structure-magmatic activity is strong and the area with ancient granite basement is also a favorable area for the development of helium-rich gas reservoirs. Existing data indicate that China has discovered some helium-rich gas reservoirs in the Sichuan Basin, Tarim Basin, Qaidam Basin, Ordos Basin and Mesozoic and Cenozoic petroliferous basins in the eastern China. At the same time, unconventional natural gas fields also show good prospects for helium resource exploration, such as soluble gas in the Weihe Basin and shale gas in the Sichuan Basin. China's helium-rich natural gas has many points, types and good resource prospects, but the overall research level of helium resources is very low.

Key words: Noble gas, Helium resources, Genetic, Accumulation, Prospects of resources

中图分类号: 

  • TE151

图1

全球氦气产量分布(修改自文献[8])"

图2

美国主要富氦天然气藏(修改自文献[5])"

图3

俄罗斯主要富氦天然气藏(修改自文献[6])"

图4

富氦天然气藏中氦与其主要伴生组分关系"

图5

全球富氦天然气田与基底特征分布(修改自文献[46])"

图6

美国潘汉德富氦天然气田剖面(修改自文献[52])"

图7

低压条件下不同气体亨利系数随温度的变化(修改自文献[16])"

1 NUTTALL W, CLARKE R, GLOWACKI B. The Future of Helium as a Natural Resource[M]. London:Taylor & Francis Group,2012.
2 CAI Z, CLARKE R H, GLOWACKI B A, et al. Ongoing ascent to the helium production plateau:Insights from system dynamics[J]. Resources Policy,2010,35(2):77-89.
3 ANDERSON S T. Economics, helium, and the U.S. federal helium reserve: Summary and outlook[J]. Natural Resources Research,2018,27(4):455-477.
4 HAMAK J E. 2015 Minerals Yearbook-Helium[R].Virginia: United States Geological Survey,2017.
5 DANABALAN D. Helium: Exploration Methodology for a Strategic Resource[D]. Durham: Durham University, 2017.
6 YAKUTSENI V P. World helium resources and the perspectives of helium industry development[J]. Petroleum Geology, 2014:1-22.
7 DANABALAN D, GLUYAS J G, BALLENTINE C J. Encyclopedia of Petroleum Geoscience[M]. Berlin: Springer, 2018.
8 PETERSON J B. Mineral Commodity Summaries-Helium[R]. Virginia: United States Geological Survey, 2020.
9 赵荟鑫,张雁,李超良.全球氦气供应和价格体系分析[J].化学推进剂与高分子材料, 2012,10(6):91-96.
ZHAO Y X, ZHANG Y, LI C L. Analysis of supply and price system for global helium gas[J]. Chemical Propellants & Polymeric Materials, 2012,10(6):91-96.
10 BROADHEAD R F. Helium in New Mexico: Geologic distribution, resource demand, and exploration possibilities[J]. New Mexico Geology, 2005,27(4):93-101.
11 BROADHEAD R F. Oil, natural gas and helium potential of the Chupadera Mesa area, Lincoln and Socorro Counties, New Mexico[C]//LUETH V, LUCAS S G. CHAMBERLIN R M. Geology of Geology of the Chupadera Mesa, The 60th Annual Fall Field Conference Guidebook, New Mexico Geological Society,2009:359-374.
12 FLAWN P T. Basement Rocks of Texas and Southeast New Mexico[R].Texas: University of Texas, 1956.
13 BARNES M A, ANTHONY E Y, WILLIAMS I, et al. Architecture of a 1.38-1.34 Ga granite-rhyolite complex as revealed by geochronology and isotopic and elemental geochemistry of subsurface samples from west Texas, USA[J]. Precambrian Research, 2002,119:9-43.
14 BALL M M, HENRY M E, FREZON S E. Petroleum Geology of the Anadarko Basin Region, Province (115), Kansas, Oklahoma, and Texas[R]. Virginia: United States Geological Survey,1991.
15 NELSON P H, GIANOUTSOS N J. Evolution of Overpressured and Underpressured Oil and Gas Reservoirs, Anadarko Basin of Oklahoma, Texas, and Kansas[R]. Virginia: United States Geological Survey, 2011.
16 BROWN A A. Formation of high helium gases: A guide for explorationists[C]. AAPG Convention, New Orleans, Louisiana, 2010.
17 NAKASHIMA K. Petroleum potential in the east Siberian Region[J]. Sekiyu Gijutsu Kyokaishi, 2005,70(2):132-141.
18 王四海,费琪,高金川.俄罗斯西伯利亚地台油气资源地质特征探析[J].地质科技情报, 2013,32(6):86-94.
WANG S H, FEI Q, GAO J C. Geological features of petroleum resources in Siberian platform of Russia[J]. Geological Science and Technology Information,2013,32(6):86-94.
19 陶高强,董清水,聂辉,等.俄罗斯西伯利亚地台油气成藏条件与分布规律[J].世界地质, 2012,31(1):139-147.
TAO G Q, DONG Q S, NIE H, et al. Research on hydrocarbon accumulation condition and distributive regulation of Siberian platform,Russia[J].Global Geology,2012,31(1):139-147.
20 王先彬.稀有气体地球化学与宇宙化学及其应用前景[J].地质地球化学,1988(8):41-49.
WANG X B. Noble gas geochemistry and cosmochemistry and their application prospects[J].Geology and Geochemistry, 1988(8):41-49.
21 徐永昌,沈平.幔源氦的工业储聚和郯序大断裂带[J].科学通报,1990,35(12):932-935.
XU Y C, SHEN P. Industrial storage and accumulation of mantle-derived helium and the Tancheng-Lujiang fault zone[J]. Chinese Science Bulletin,1990,35(12):932-935.
22 BALLENTINE C J, BURNARD P G. Production, release and transport of noble gases in the continental crust[J]. Reviews in Mineralogy and Geochemistry,2002,47(1):481-538.
23 MAMYRIN B A, TOLSTIKHIN I. Helium Isotopes in Nature[M]. Amsterdam: Elsevier Science Publish, 1984.
24 OXBURGH E R,O'NIONS R K, HILL R I. Helium isotopes in sedimentary basins[J].Nature,1986,324(18):632-635.
25 GOLD T, HELD M. Helium-nitrogen-methane systematics in natural gases of Texas and Kansas[J]. Journal of Petroleum Geology,1987,10(4):415-424.
26 CRAIG H, LUPTON J E. Primordial neon, helium, and hydrogen in oceanic basalts[J]. Earth and Planetary Science Letters,1976,31(3):369-385.
27 GAUTHERON C, MOREIRA M. Helium signature of the subcontinental lithospheric mantle[J]. Earth and Planetary Science Letters,2002,199(1):39-47.
28 杜建国.轻稀有气体同位素地球化学[J].地质地球化学,1989(4):57-59.
DU J G. Light noble gas isotope geochemistry[J]. Geology and Geochemistry, 1989(4):57-59.
29 徐永昌,沈平,陶明信,等.东部油气区天然气中幔源挥发份的地球化学-Ⅰ.氦资源的新类型:沉积壳层幔源氦的工业储集[J].中国科学:D辑:地球科学,1996,26(1):1-8.
XU Y C, SHEN P, TAO M X, et al. Geochemistry of mantle-derived volatiles in natural gas in the eastern oil and gas regions-Ⅰ. A new type of helium resource: Industrial accumulation of mantle-derived helium in sedimentary crust[J]. Science in China:Series D,1996, 26(1):1-8.
30 王先彬,徐胜,陈践发,等.腾冲火山区温泉气体组分和氦同位素组成特征[J].科学通报, 1993,38(9):48-51.
WANG X B, XU S, CHEN J F, et al. Gas composition and helium isotopic composition characteristics of hot springs in Tengchong volcanic area[J]. Chinese Science Bulletin, 1993, 38(9):48-51.
31 高博,陈践发,王先彬.陆地水热系统气体地球化学研究进展[J].地球科学进展, 2004,19(2):211-217.
GAO B, CHEN J F, WANG X B. A review of gas geochemistry of continental geothermal system[J]. Advances in Earth Science, 2004,19(2):211-217.
32 冯子辉,霍秋立,王雪.松辽盆地北部氦气成藏特征研究[J].天然气工业,2001,21(5):27-30.
FENG Z H, HUO Q L, WANG X. A study of helium reservolr formation characteristic in the north part of Songliao Basin[J]. Natural Gas Industry,2001,21(5):27-30.
33 陶明信,沈平,徐永昌,等.苏北盆地幔源氦气藏的特征与形成条件[J].天然气地球科学, 1997,8(3):1-8.
TAO M X, SHEN P, XU Y C, et al. Characteristics and formation conditions of mantle-derived helium gas reservoirs in Subei Basin[J]. Natural Gas Geoscience, 1997,8(3):1-8.
34 刘全有,戴金星,金之钧,等.塔里木盆地前陆区和台盆区天然气的地球化学特征及成因[J].地质学报, 2009,83(1):107-114.
LIU Q Y, DAI J X, JIN Z J, et al. Geochemistry and genesis of natural gas in the foreland and platform of the Tarim Basin[J]. Acta Geologica Sinica, 2009,83(1):107-114.
35 郑建京,刘文汇,孙国强,等.稳定、次稳定构造盆地天然气氦同位素特征及其构造学内涵[J].自然科学进展, 2005,18(8):951-957.
ZHENG J J, LIU W H, SUN G Q, et al. Helium isotope characteristics of natural gas in stable and sub-stable structural basins and their tectonic connotations[J]. Progress in Natural Science, 2005,18(8):951-957.
36 HE D X, CHEN J F, ZHANG C, et al. Compositions of non-hydrocarbon and noble gases in natural gas samples from Tarim Basin, China[J]. Geological Journal,2015,49(3):271-282.
37 徐永昌,沈平,陶明信,等.中国含油气盆地天然气中氦同位素分布[J].科学通报, 1994,39(16):67-70.
XU Y C, SHEN P, TAO M X, et al. Distribution of helium isotopes in natural gas in China's petroliferous basins[J]. Chinese Science Bulletin, 1994,39(16):67-70.
38 PRINZHOFER A. Noble Gases in Oil and Gas Accumulations[M]. Berlin: Springer,2013:225-247.
39 BARNARD P C, COOPER B S. A review of geochemical data related to the northwest European Gas Province[J]. Geological Society of London, 1983,12:19-33.
40 GERLING P, GELUK M C, KOCKEL F, et al. 'NW European Gas Atlas' - New Implications for the Carboniferous Gas Plays in the Western Part of the Southern Permian Basin[C]. Geological Society, London: Petroleum Geology Conference series,1999, 5: 799-808
41 BALLENTINE C J, BURGESS R, MARTY B. Tracing fluid origin, transport and interaction in the crust[J]. Reviews in Mineralogy and Geochemistry,2002,47(1):539-614.
42 GILFILLAN S M V, BALLENTINE C J, HOLLAND G, et al. The noble gas geochemistry of natural CO2 gas reservoirs from the Colorado Plateau and Rocky Mountain Provinces, USA[J]. Geochimica et Cosmochimica Acta, 2008,72(4):1174-1198.
43 ZHOU Z, BALLENTINE C J, SCHOELL M, et al. Identifying and quantifying natural CO2 sequestration processes over geological timescales: The Jackson Dome CO2 Deposit, USA[J]. Geochimica et Cosmochimica Acta, 2012,86:257-275.
44 戴金星,王廷斌,宋岩,等.中国大中型天然气田形成条件与分布规律[M].北京:地质出版社, 1997.
DAI J X, WANG T B, SONG Y, et al. Formation Conditions and Distribution Patterns of Large and Medium-sized Natural Gas Fields in China[M]. Beijing: Geological Publishing House, 1997.
45 金之钧,张一伟,王捷.油气成藏机理与分布规律[M].北京:石油工业出版社, 2003.
JIN Z J, ZHANG Y W, WANG J. Hydrocarbon Accumulation Mechanism and Distribution Patterns[M]. Beijing: Petroleum Industry Press, 2003.
46 李江海,韩喜球,毛翔.全球构造图集[M].北京:地质出版社, 2014.
LI J H, HAN X Q, MAO X. Atlas of Global Tectonics[M]. Beijing: Geological Publishing House, 2014.
47 BALLENTINE C J, BARRY P H, HILLEGONDS D, et al. Commercial Helium Reserves, Continental Rifting and Volcanism[C]. AGU Fall Meeting, 2017.
48 HAND E. Massive helium fields found in rift zone of Tanzania[J]. Science, 2016,353(6295):109-110.
49 BALLENTINE C J, SHERWOOD L B. Regional groundwater focusing of nitrogen and noble gases into the Hugoton-Panhandle giant gas field, USA[J]. Geochimica et Cosmochimica Acta, 2002,66(14):2483-2497.
50 徐永昌,沈平,刘文汇,等.东部油气区天然气中幔源挥发份的地球化学-Ⅱ.幔源挥发份中的氦、氩及碳化合物[J].中国科学:D辑, 1996,26(2):187-192.
XU Y C,SHEN P,LIU W H,et al.Geochemistry of mantlede-rived volatiles in natural gas in eastern oil and gas regions-Ⅱ. Helium, argon and carbon compounds in mantle-derived volatiles[J]. Science in China:Series D,1996,26(2):187-192.
51 BROWN A. Origin of helium and nitrogen in the Panhandle-Hugoton field of Texas, Oklahoma, and Kansas, United States[J]. AAPG Bulletin,2019,103(2):369-403.
52 SORENSON R P. A dynamic model for the Permian Panhandle and Hugoton fields, western Anadarko Basin[J]. AAPG Bulletin, 2005,89(7):921-938.
53 ROQUES C,WEBER U W,BRIXEL B,et al.In-situ observation of helium and argon release during fluid-pressure-triggered rock deformation[J]. Scientific Reports, 2020,10(1):1-9.
54 TORGERSEN T, CLARKE W B. Helium accumulation in groundwater, I: An evaluation of sources and the continental flux of crustal 4He in the Great Artesian Basin, Australia[J]. Geochimica et Cosmochimica Acta, 1985,49(5):1211-1218.
55 LOWENSTERN J B, BERGFELD D, EVANS W C, et al. Origins of geothermal gases at Yellowstone[J]. Journal of Volcanology and Geothermal Research, 2015,302:87-101.
56 KENNEDY B M, VAN SOEST M C. A helium isotope perspective on the Dixie Valley, Nevada, hydrothermal system[J]. Geothermics, 2006,35(1):26-43.
57 WEISS R F. Solubility of helium and neon in water and seawater[J]. Journal of Chemical & Engineering Data, 1971,16(2):235-241.
58 SOLEN K A, CHUEH P L, PRAUSNITZ J M. Thermodynamics of helium solubility in cryogenic solvents at high pressures[J]. Industrial & Engineering Chemistry Research, 1970,9(2):310-317.
59 DUAN Z H, MØLLER N, WEARE J H. An equation of state for the CH4-CO2-H2O system: I. Pure systems from 0 to 1000°C and 0 to 8000 bar[J]. Geochimica et Cosmochimica Acta, 1992,56(7):2605-2617.
60 PIERCE A P, GOTT G B, MYTTON J W. Uranium and helium in the Panhandle Gas Field Texas, and adjacent areas[R]. Virginia: United States Geological Survey,1964.
61 杜建国,刘文汇.三水盆地天然气中的氦和氩同位素地球化学研究[J].天然气地球科学, 1991,2(6):283-285.
DU J G, LIU W H. Geochemical study of helium and argon isotopes in natural gas in Sanshui Basin[J]. Natural Gas Geoscience, 1991,2(6):283-285.
62 戴金星.威远气田成藏期及气源[J].石油实验地质, 2003,25(5):473-480.
DAI J X. Pool-forming periods and gas sources of Weiyuan Gas Field[J]. Petroleum Geology & Experiment, 2003,25(5):473-480.
63 曹忠祥,车燕,李军亮,等.济阳坳陷花沟地区高含He气藏成藏分析[J].石油实验地质, 2001,23(4):395-399.
CAO Z X, CHE Y, LI J L, et al. Accumulation analysis on a helium-enriched gas reservoir in Huagou area, the Jiyang Depression[J]. Petroleum Geology & Experiment, 2001,23(4):395-399.
64 王江,张宏,林东成.海拉尔盆地乌尔逊含氦CO2气藏勘探前景[J].天然气工业,2002, 22(4):109-111.
WANG J, ZHANG H, LIN D C. Exploration prospects of Urxun helium-bearing CO2 gas reservoir in Hailar Basin[J]. Natural Gas Industry,2002,22(4):109-111.
65 常兴浩,宋凯.巴什托构造石炭系小海子组高氦气藏成藏机理浅析[J].天然气工业,1997, 17(2):18-20.
CHANG X H, SONG K. Analysis of reservoir-forming mechanism of high-He pool in the Carboniferous of Xiaohaizi Formation of Bashitou Structure[J]. Natural Gas Industry, 1997, 17(2):18-20.
66 余琪祥,史政,王登高,等.塔里木盆地西北部氦气富集特征与成藏条件分析[J].西北地质, 2013,46(4):215-222.
YU Q X, SHI Z, WANG D G, et al. Analysis on helium enrichment characteristics and reservoir forming condition in nor-thwest Tarim Basin[J].Northwestern Geology,2013,46(4):215-222.
67 韩伟,刘文进,李玉宏.柴达木盆地北缘地区氦气资源调查实现突破,有望改变我国贫氦面貌[J]. 天然气地球科学, 2019,30(2):273.
HAN W, LIU W J, LI Y H. A breakthrough has been achieved in the investigation of helium resources in the northern margin of the Qaidam Basin, which is expected to change the face of helium-poor in China[J]. Natural Gas Geoscience, 2019,30(2):273.
68 ZHANG T W, ZHANG M J, BAI B J, et al. Origin and accumulation of carbon dioxide in the Huanghua depression, Bohai Bay Basin, China[J]. AAPG Bulletin, 2008,92(3):341-358.
69 DAI J X, NI Y Y, QIN S F, et al. Geochemical characteristics of He and CO2 from the Ordos(cratonic) and Bohaibay (rift) Basins in China[J].Chemical Geology,2017,469:192-213.
70 陶小晚,李建忠,赵力彬,等.我国氦气资源现状及首个特大型富氦储量的发现:和田河气田[J]. 地球科学, 2019,44(3):1024-1041.
TAO X W, LI J Z, ZHAO L B, et al. Helium resources and discovery of first supergiant helium reserve in China:Hetianhe Gas Field[J]. Earth Science, 2019,44(3):1024-1041.
71 NI Y Y, DAI J X, TAO S Z, et al. Helium signatures of gases from the Sichuan Basin, China[J]. Organic Geochemistry, 2014,74:33-43.
72 WANG X F, LIU W H, LI X B, et al. Radiogenic helium concentration and isotope variations in crustal gas pools from Sichuan Basin, China[J]. Applied Geochemistry, 2020,117:104586.
73 LIU Q Y, JIN Z J, CHEN J F, et al. Origin of nitrogen molecules in natural gas and implications for the high risk of N2 exploration in Tarim Basin, NW China[J]. Journal of Petroleum Science and Engineering, 2012,81:112-121.
74 徐胜.中国天然气中稀有气体丰度和同位素组成[J].矿物岩石地球化学通报,1997,16(2):71-74.
XU S. Noble gas abundances and isotopes in natural gases in China[J]. Bulletin of Mineralogy,Petrology and Geochemistry,1997,16(2):71-74.
[1] 韩双彪, 唐致远, 杨春龙, 谢林丰, 向朝涵, HORSFIELD Brian, 王成善. 天然气中氢气成因及能源意义[J]. 天然气地球科学, 2021, 32(9): 1270-1284.
[2] 李让彬, 段金宝, 潘磊, 李红. 川东地区中二叠统茅口组白云岩储层成因机理及主控因素[J]. 天然气地球科学, 2021, 32(9): 1347-1357.
[3] 李二庭, 米巨磊, 周波, 马聪, 陈世加, 张晓刚, 刘翠敏. 准噶尔盆地莫索湾地区白垩系生物降解与成藏地球化学特征[J]. 天然气地球科学, 2021, 32(9): 1384-1392.
[4] 李剑, 王晓波, 侯连华, 陈昌, 国建英, 杨春龙, 王义凤, 李志生, 崔会英, 郝爱胜, 张璐. 四川盆地页岩气地球化学特征及资源潜力[J]. 天然气地球科学, 2021, 32(8): 1093-1106.
[5] 杨春龙, 谢增业, 李剑, 国建英, 张璐, 金惠, 郝翠果, 王晓波, 李志生, 李谨, 齐雪宁. 四川盆地中侏罗统沙溪庙组天然气地球化学特征及成因[J]. 天然气地球科学, 2021, 32(8): 1117-1126.
[6] 刘海亮, 刘四兵, 周栋, 刘文, 金思丁. 四川盆地西部致密砂岩气来源及运移地球化学示踪[J]. 天然气地球科学, 2021, 32(8): 1127-1141.
[7] 刘金水, 张书平. 东海盆地西湖凹陷中北部天然气运移特征与成藏模式[J]. 天然气地球科学, 2021, 32(8): 1163-1176.
[8] 刘刚, 李建忠, 齐雪峰, 朱明, 袁波, 庞志超. 准噶尔盆地南缘西段下部成藏组合油气藏形成过程[J]. 天然气地球科学, 2021, 32(7): 1009-1021.
[9] 卢晓林, 李美俊, 王小娟, 唐友军, 韦腾强, 何大祥, 洪海涛, 吴长江, 冉子超. 川中地区侏罗系天然气与原油轻烃地球化学特征对比[J]. 天然气地球科学, 2021, 32(7): 1073-1083.
[10] 李蓉, 苏成鹏, 石国山, 贾霍甫, 李素华, 余洋. 川南地区二叠系茅口组一段瘤状灰岩储层成因[J]. 天然气地球科学, 2021, 32(6): 806-815.
[11] 张光荣, 聂海宽, 唐玄, 李东晖, 孙川翔, 张培先. 基于有机孔和生物成因硅优选页岩气富集高产层段的方法及应用[J]. 天然气地球科学, 2021, 32(6): 888-898.
[12] 张藜, 张新涛, 刘艺萌, 韩芮, 魏国财. 渤海海域深部热流体存在的证据及其对油气成藏意义——以秦皇岛29⁃2/2E油气田为例[J]. 天然气地球科学, 2021, 32(5): 633-644.
[13] 张亚震, 裴健翔, 李俊良, 杜艺可, 史德锋, 向远高. 南海南部海域构造—沉积演化及其对区域成藏组合的控制[J]. 天然气地球科学, 2021, 32(5): 657-674.
[14] 邹妞妞, 张大权, 史基安, 鲁新川, 张顺存. 准噶尔盆地中拐凸起二叠系上乌尔禾组油气成藏及其主控因素[J]. 天然气地球科学, 2021, 32(4): 540-550.
[15] 钱海涛, 苏东旭, 阿布力米提·依明null, 王学勇, 李宗浩, 王国栋. 准噶尔盆地盆1井西凹陷斜坡区油气地质特征及勘探潜力[J]. 天然气地球科学, 2021, 32(4): 551-561.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
[1] 赵应成,周晓峰,王崇孝,王满福,郭娟娟 . 酒西盆地青西油田白垩系泥云岩裂缝油藏特征和裂缝形成的控制因素[J]. 天然气地球科学, 2005, 16(1): 12 -15 .
[2] 任以发. 微量烃分析在井中化探录井中的应用[J]. 天然气地球科学, 2005, 16(1): 88 -92 .
[3] 旷理雄,郭建华,王英明,冯永宏,李广才 . 柴窝堡凹陷达坂城次凹油气成藏条件及勘探方向[J]. 天然气地球科学, 2005, 16(1): 20 -24 .
[4] 何家雄;李明兴;陈伟煌;. 莺歌海盆地热流体上侵活动与天然气运聚富集关系探讨[J]. 天然气地球科学, 2000, 11(6): 29 -43 .
[5] 郑建京;吉利明;孟仟祥;. 准噶尔盆地天然气地球化学特征及聚气条件的讨论[J]. 天然气地球科学, 2000, 11(4-5): 17 -21 .
[6] Seewald J S;Benitez-Netson B C;Whelan J K(美国);刘全有(译). 天然气形成与组成的实验和理论因素[J]. 天然气地球科学, 2000, 11(4-5): 30 -44 .
[7] Al-Arouri K;Mckirdy D;Boreham C(澳大利亚);孙庆峰(译). 用油源对比方法识别澳大利亚南塔鲁姆凹陷的石油系统[J]. 天然气地球科学, 2000, 11(4-5): 57 -67 .
[8] 张延敏, . 1996~1999年世界天然气产量[J]. 天然气地球科学, 2000, 11(3): 44 -45 .
[9] 付广;王剑秦. 地壳抬升对油气藏保存条件的影响[J]. 天然气地球科学, 2000, 11(2): 18 -23 .
[10] 廖成君. VSP技术在锦612复杂断块油藏开发部署研究中的应用[J]. 天然气地球科学, 2005, 16(1): 117 -122 .