凌源—宁城盆地牛营子坳陷侏罗系海房沟组烃源岩芳烃地球化学特征及其地质意义

doi:10.11764/j.issn.1672-1926.2019.10.024

天然气地球科学

凌源—宁城盆地牛营子坳陷侏罗系海房沟组烃源岩芳烃地球化学特征及其地质意义

唐友军¹，郑磊¹，李永飞²，郜晓勇²，宗文明²，孙求实²，何大祥¹

1.长江大学资源与环境学院，油气资源与勘探技术教育部重点实验室，湖北武汉 430100;
2.沈阳地质矿产研究所，中国地质调查局沈阳地质调查中心，辽宁沈阳 110034

收稿日期:2018-08-15 修回日期:2018-10-25 出版日期:2019-03-10
通讯作者: 郑磊(1993-)，男，湖北武汉人，硕士研究生，主要从事油气地球化学研究 E-mail:522958677@qq.com.
作者简介:唐友军(1975-)，男，湖北荆州人，副教授，博士，主要从事油气地球化学研究.E-mail：309378729@qq.com.
基金资助:
国地质调查局项目“松辽外围南部盆地群油气基础地质调查”(编号:DD20160167)；中国石油科技创新基金项目（编号：2017D-5007-0105）;国家自然科学重点基金项目（编号：41730424）联合资助.

The aromatic fraction of source rocks from the Jurassic Haifanggou Formation in Niuyingzi Depression of Lingyuan-Ningcheng Basin

Tang You-jun¹，Zheng Lei¹，Li Yong-fei²，Gao Xiao-yong²，Zong Wen-ming²，Sun Qiu-shi²，He Da-xiang¹

1.College of Resources and Environment,Key Laboratory of Exploration Technologies for Oil and Gas Resources,Ministry of Education,Yangtze University,Wuhan 430100,China; 2.Shenyang Institute of Geology and Mineral Resources /Shenyang Center of Geological Survey,China Geological Survey( CGS),Shenyang 110034,China

Received:2018-08-15 Revised:2018-10-25 Online:2019-03-10

摘要/Abstract

摘要： 基于凌源—宁城盆地牛营子坳陷侏罗系海房沟组13个烃源岩抽提物中芳烃馏分的GC—MS分析，结果表明：侏罗系海房沟组烃源岩中均检测到1,2,5-三甲基萘、卡达烯、联苯、蒽、苝等陆源高等植物来源的化合物以及部分低等生物来源的[XC草字屈.tif]和苯并藿烷等化合物，反映出海房沟组烃源岩有机质主要来源于陆源高等植物，少量低等生物贡献，并且在302.0m以浅的烃源岩中卡达烯/菲、联苯/菲、蒽/菲等值相对较高，反映出浅部烃源岩中陆源高等植物贡献更为充足。此外，三芳甾烷系列、三芴系列、苯并藿烷系列和脱羟基维生素E系列分布特征表明302.0m以浅的烃源岩形成于偏氧化的淡水沼泽相环境，302.0m以深的烃源岩则形成于弱氧化—弱还原的淡水—微咸水环境；芳烃中烷基萘参数(DNR、TNR、TMNr、TeMNr)、烷基菲参数(MPI1)、三芳甾烷参数[C₂₈TAS-20S/(20R+20S)]、二苯并噻吩参数(MDR)、苯并藿烷分布特征以及脱羟基维生素E系列参数(β-MTTC/γ-MTTC)均反映海房沟组烃源岩处于低成熟阶段且深部与浅部成熟度相近，深部略高于浅部。

关键词: 凌源—宁城盆地, 侏罗系, 海房沟组, 烃源岩, 芳烃地球化学特征

Abstract: The aromatic fraction of thirteen source rock samples from the Jurassic Haifanggou Formation in Niuyingzi Depression of Lingyuan-Ningcheng Basin were analyzed by gas chromatography-mass spectrometer(GC-MS).The aromatic hydrocarbon molecular compounds in the source rocks shallower than 302.0m are distinctly different from that in the source rocks deeper than 302.0m in the Haifanggou Formation of the Well Niu D1.The 1,2,5-trimethylnaphthalene,cadalene,biphenyl,anthrance,perylene,chrysene and dibenzoforan have an obvious distribution in all source rocks of the Jurassic Haifanggou Formation,which indicate a significant terrigenous high plant input and a small amount of lower biological contributions.However,the shallow source rocks contain relatively higher values of cadalene/phenanthrene,biphenyl/phenanthrene and anthrance/phenanthrene ratios than those of the deep source rocks,reflecting that the shallow source rocks have more abundant terrestrial higher plants than the deep source rocks.The distributions of triaromatic steranes,fulorenes,dibenzothiophenes and dibenzoforans,benzohopanes and dehydroxyl-vitamin E indicate that the shallow source rocks were deposited in the swamp environment with relatively oxic condition and freshwater water,whereas the deep source rocks are formed in lacustrine environment with suboxic condition and freshwater to brackish water.In addition,various measured maturity-related indicators in aromatic fraction,including DNR,TNR,TMNr,TeMNr,MPI1,C₂₈TAS-20S/(20R+20S),MDR and β-MTTC/γ-MTTC,as well as the distribution of benzohopanes,show that the Haifanggou Formation just have entered early oil generation stage,and the maturity level of deep source rocks is slightly higher than shallow source rocks.

Key words: Lingyuan-Ningcheng Basin, Jurassic, Haifanggou Formation, Source rock, Aromatic hydrocarbon geochemical characteristics

中图分类号:

TE122.1+13

唐友军, 郑磊, 李永飞, 郜晓勇, 宗文明, 孙求实, 何大祥. 凌源—宁城盆地牛营子坳陷侏罗系海房沟组烃源岩芳烃地球化学特征及其地质意义[J]. 天然气地球科学, 2019, 30(3): 433–446.

Tang You-jun, Zheng Lei, Li Yong-fei, Gao Xiao-yong, Zong Wen-ming, Sun Qiu-shi, He Da-xiang. The aromatic fraction of source rocks from the Jurassic Haifanggou Formation in Niuyingzi Depression of Lingyuan-Ningcheng Basin[J]. Natural Gas Geoscience, 2019, 30(3): 433–446.

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[2]	张帆, 冉清昌, 吴玉明, 任志高. 松辽盆地北部古中央隆起带天然气地球化学特征及成藏条件[J]. 天然气地球科学, 2019, 30(1): 126-132.
[3]	于聪, 胡国艺, 陈瑞银. 不同煤系烃源岩热解气地球化学差异及其在苏里格气田的应用[J]. 天然气地球科学, 2019, 30(1): 133-142.
[4]	傅宁,刘建升. 北部湾盆地流二段3类烃源岩的生烃成藏特征[J]. 天然气地球科学, 2018, 29(7): 932-941.
[5]	贾智彬,侯读杰,孙德强,姜玉涵,张自鸣,洪梅. 贵州地区牛蹄塘组底部烃源岩地球化学特征[J]. 天然气地球科学, 2018, 29(7): 1031-1041.
[6]	程志强，王飞宇，师玉雷，冯伟平，谢佩宇，任利兵，吴子强,江涛，赵志刚. 二连盆地乌里雅斯太凹陷南洼烃源岩有机相与生烃特征[J]. 天然气地球科学, 2018, 29(5): 696-707.
[7]	申宝剑，秦建中，腾格尔，潘安阳，仰云峰，边立曾. 中国南方海相烃源岩中细菌状化石识别[J]. 天然气地球科学, 2018, 29(4): 510-517.
[8]	贺领兄，宋维刚，安生婷，徐永锋，沈娟，路超，王军. 青海东昆仑地区八宝山盆地烃源岩有机地球化学特征与页岩气勘探前景[J]. 天然气地球科学, 2018, 29(4): 538-549.
[9]	邢舟,曹高社，毕景豪，周新桂,张交东. 南华北盆地禹州地区ZK0606钻孔上古生界煤系烃源岩评价[J]. 天然气地球科学, 2018, 29(4): 518-528.
[10]	杨飞，蒲秀刚，姜文亚，韩文中，张伟，时战楠，林常梅. 渤海湾盆地沧东凹陷孔二段细粒相区有机地球化学特征[J]. 天然气地球科学, 2018, 29(4): 550-558.
[11]	李国欣, 易士威, 林世国, 高阳, 李明鹏, 李德江, 王昌勇. 塔里木盆地库车坳陷东部地区下侏罗统储层特征及其主控因素[J]. 天然气地球科学, 2018, 29(10): 1506-1517.
[12]	白雪峰, 梁江平, 张文婧, 付丽, 彭建亮, 薛涛, 杨立伟, 刘继莹. 松辽盆地北部深层天然气地质条件、资源潜力及勘探方向[J]. 天然气地球科学, 2018, 29(10): 1443-1454.
[13]	秦胜飞，罗平，王铜山，王蓝军，马奎. 华北南缘东部新元古界冰碛砾岩层系中优质烃源岩的发现及地质意义[J]. 天然气地球科学, 2018, 29(1): 55-61.
[14]	李玉婷，黄志龙，安成龙，马强，王瑞，辛铭. 三塘湖盆地石炭系哈尔加乌组上、下段烃源岩特征及差异[J]. 天然气地球科学, 2018, 29(1): 73-86.
[15]	陈晓艳，田福清,邹华耀，郭柳汐,芦晓伟，殷杰，王道军. 湖相烃源岩热演化生烃研究——基于冀中坳陷烃源岩加水热模拟实验[J]. 天然气地球科学, 2018, 29(1): 103-113.