天然气地球科学 ›› 2020, Vol. 31 ›› Issue (3): 436446.doi: 10.11764/j.issn.1672-1926.2019.10.007
Ji-fa YAN1,2(),An-lai MA3(),Jie-hao LI4,Xian-qing LI1,2
摘要:
目前石油和烃源岩中金刚烷类化合物的检测主要采用气相色谱—质谱(GC?MS)仪和气相色谱—质谱—质谱(GC?MS?MS)仪。在GC?MS分析中,金刚烷类化合物普遍存在明显的共溢出现象,而GC?MS?MS分析通过多反应监测(MRM)方式有效解决了GC?MS分析中共溢出问题。通过对塔里木盆地4种不同类型原油样品中金刚烷类化合物的GC?MS、GC?MS?MS定量结果对比,发现MRM GC?MS?MS具有更低的检出下限和定量下限、更高的灵敏度和准确度,能够检测出更多的金刚烷类化合物,是一种较好的检测原油和烃源岩中金刚烷类化合物的分析方法。对三金刚烷、四金刚烷系列化合物含量低的原油样品, GC?MS?MS方法可以获得清晰谱图,但GC?MS?MS对金刚烷系列的准确定量仍需建立原油样品中金刚烷系列全部化合物的响应因子。
中图分类号:
1 | LANDA S, MACHACEK V. Adamantane, a new hydrocarbon extracted from petroleum[J]. Collection of Czechoslovak Chemical Communications, 1933, 5(1): 1-5. |
2 | 米镇涛, 郭建维, 邱立勤. 笼状烃金刚烷的新合成方法[J]. 燃料化学学报, 1998, 26(1): 89-92. |
Mi Z T, Guo J W, Qiu L Q. Study on the new synthesis method of adamantane[J]. Journal of Fuel Chemistry and Technology, 1998, 26(1): 89-92. | |
3 | CHEN J H, FU J M, SHENG G Y, et al. Diamondoid hydrocarbon ratios: Novel maturity indices for highly mature crude oils[J]. Organic Geochemistry, 1996, 25(3/4): 179-190. |
4 | GRICE K, ALEXANDER R, KAGI R I. Diamondoid hydrocarbon ratios as indicators of biodegradation in Australian crude oils[J]. Organic Geochemistry, 2000, 31(1): 67-73. |
5 | WILLIAMS J A, BJORÙY M, DOLCATER D L, et al. Biodegradation in south Texas Eocene Oils:Effects on aromatics and biomarkers[J]. Organic Geochemistry, 1986, 10(3/4): 451-461. |
6 | WINGERT W S. GC-MS analysis of diamondoid hydrocarbons in Smackover petroleums[J]. Fuel, 1992, 71(1): 37-43. |
7 | WEI Z B, MOLDOWAN J M, ZHANG S C, et al. Diamondoid hydrocarbons as a molecular proxy for thermal maturity and oil cracking: Geochemical models from hydrous pyrolysis[J]. Organic Geochemistry, 2007, 38: 227-249. |
8 | 马安来, 金之钧, 朱翠山, 等. 塔河油田原油中金刚烷化合物绝对定量分析[J]. 石油学报, 2009, 30(2): 214-218. |
MA A L, JIN Z J, ZHU C S, et al. Quantitative analysis on absolute concentration of diamondoids in oils from Tahe Oilfield[J]. Acta Petrolei Sinica, 2009, 30(2): 214-218. | |
9 | 陈军红, 傅家谟, 盛国英, 等. 金刚烷化合物在石油中的分布特征研究[J]. 自然科学进展, 1997, 7(3): 363-367. |
CHEN J H, FU J M, SHENG G Y, et al. The research in the distribution characteristic of diamondoid hydrocarbons in crude oils[J]. Advancement Nature Science, 1997, 7(3): 363-367. | |
10 | SCHULZ L K, WILHELMS A, REIN E, et al. Application of diamondoids to distinguish source rock facies[J]. Organic Geochemistry, 2001, 32(3): 365-375. |
11 | WEI Z B, MOLDOWAN J M, JARVIE D M, et al. The fate of diamondoids in coals and sedimentary rocks[J]. Geology, 2006, 34(12): 1013-1016. |
12 | 房忱琛, 吴伟, 刘丹, 等. 煤系中金刚烷化合物演化特征及应用[J]. 天然气地球科学, 2015, 26(1): 110-117. |
FANG C C, WU W, LIU D, et al. Evolution characteristics and application of diamondoids in coal measures[J]. Natural Gas Geoscience, 2015, 26(1): 110-117. | |
13 | 郑伦举, 曹建平, 薛建华, 等. 原油及烃源岩成熟度的新指标—甲基双金刚烷指数[J]. 石油实验地质, 1998, 20(4): 411-416. |
ZHENG L J, CAO J P, XUE J H, et al. A new index for the maturity of crude oil and hydrocarbon source rock: Methyl-diamantane index[J]. Experimental Petroleum Geology, 1998, 20(4): 411-416. | |
14 | LIN R, WILK Z A. Natural occurrence of tetramantane (C22H28), pentamantane (C26H32) and hexamantane (C30H36) in a deep petroleum reservoir[J].Fuel,1995,74(10):1512-1521. |
15 | SASSEN R, POST P. Enrichment of diamondoids and 13C in condensate from Hudson Canyon, US Atlantic[J]. Organic Geochemistry, 2008, 39: 147-151. |
16 | 张水昌, 赵文智, 王飞宇, 等. 塔里木盆地东部地区古生界原油裂解气成藏历史分析——以英南2气藏为例[J]. 天然气地球科学, 2004, 15(5): 441-451. |
ZHANG S C, ZHAO W Z, WANG F Y, et al. Paleozoic oil cracking gas accumulation history from eastern part of the Tarim Basin: A case study of the YN2 gas reservoir[J]. Natural Gas Geoscience, 2004, 15(5): 441-451. | |
17 | 侯读杰, 赵增迎, 唐友军, 等. 柯克亚地区原油裂解气的地质—地球化学特征[J]. 天然气地球科学, 2004, 15(2): 137-142. |
HOU D J, ZHAO Z Y, TANG Y J, et al. The geological and geochemical characteristics of oil cracked gas in Kekeya region, Tarim Basin[J]. Natural Gas Geoscience, 2004, 15(2): 137-142. | |
18 | FANG C C, XIONG Y Q, LIANG Q Y, et al. Variation in abundance and distribution of diamondoids during oil cracking[J]. Organic Geochemistry, 2012, 47: 1-8. |
19 | FANG C C, XIONG Y Q, LI Y, et al. The origin and evolution of adamantanes and diamantanes in petroleum[J]. Geochimica et Cosmochimica Acta, 2013, 120(11): 109-120. |
20 | DAHL J E, MOLDOWAN J M, PETERS K E, et al. Diamondoid hydrocarbons as indicators of natural oil cracking[J]. Nature, 1999, 399(5): 54-57. |
21 | 马安来, 金之钧, 朱翠山. 塔里木盆地塔河油田奥陶系原油成熟度及裂解程度研究[J]. 天然气地球科学, 2017, 28(2): 313-323. |
MA A L, JIN Z J, ZHU C S. Maturity and oil-cracking of the Ordovician oils from Tahe Oilfield, Tarim Basin, NW China[J]. Natural Gas Geoscience, 2017, 28(2): 313-323. | |
22 | WEI Z B, MOLDOWAN J M, PETERS K E, et al. The abundance and distribution of diamondoids in biodegraded oils from the San Joaquin Valley: Implications for biodegradation of diamondoids in petroleum reservoirs[J]. Organic Geochemistry, 2007, 38: 1910-1926. |
23 | CHENG X, HOU D J, XU C G. The effect of biodegradation on adamantanes in reservoired crude oils from the Bohai Bay Basin, China[J]. Organic Geochemistry, 2018, 123: 38-43. |
24 | HANIN S, ADAM P, KOWALEWSKI I, et al. Bridgehead alkylated 2-thiaadamantanes: Novel markers for sulfurisation occurring under high thermal stress in deep petroleum reservoirs[J]. Chemical Communications, 2002, 16: 1750-1751. |
25 | 姜乃煌,朱光有,张水昌,等. 塔里木盆地塔中83井原油中检测出2-硫代金刚烷及其地质意义[J]. 科学通报, 2007,52(24):2871-2875. |
JIANG N H, ZHU G Y, ZHANG S C, et al. Detection of 2-thiaadamantanes in the oils from Well TZ 83 in Tarim Basin and its geological implication[J]. Chinese Science Bulletin, 2007,52(24):2871-2875. | |
26 | WEI Z B, WALTERS C C, MOLDOWAN J M, et al. Thiadiamondoids as proxies for the extent of thermochemical sulfate reduction[J]. Organic Geochemistry, 2012,44: 53-70. |
27 | 马安来, 金之钧, 朱翠山. 塔里木盆地顺南1井原油硫代金刚烷系列的检出及意义[J]. 石油学报, 2018, 39(1): 313-323. |
MA A L, JIN Z J, ZHU C S. Detection and research significance of Thiadiamondoids from crude oil in Well Shunnan 1,Tarim Basin[J].Acta Petrolei Sinica, 2018, 39(1): 313-323. | |
28 | JIANG W M, LI Y, XIONG Y Q. The effect of organic matter type on formation and evolution of diamondoids[J]. Marine and Petroleum Geology, 2018, 89: 714-720. |
29 | LI Y, CHEN Y, XIONG Y Q, et al. Origin of adamantanes and diamantanes in marine source rock[J]. Energy Fuels, 2015, 29: 8188-8194. |
30 | ZHU G Y, WANG H T, WENG N, et al. Use of comprehensive two-dimensional gas chromatography for the characterization of ultra-deep condensate from the Bohai Bay Basin, China[J]. Organic Geochemistry, 2013, 63: 8-17. |
31 | ZHU G Y, WENG N, WANG H T, et al. Origin of diamondoid and sulphur compounds in the Tazhong Ordovician condensate,Tarim Basin, China: Implications for hydrocarbon exploration in deep-buried strata[J]. Marine and Petroleum Geology, 2015, 62: 14-27. |
32 | 王汇彤, 翁娜, 张水昌, 等. 全二维气相色谱/飞行时间质谱对饱和烃分析的图谱识别及特征[J]. 质谱学报, 2010, 31(1): 18-27. |
WANG H T, WENG N, ZHANG S C, et al. Characteristics and identification of saturated hydrocarbons by comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry[J]. Journal of Chinese Mass Spectrometry Society, 2010, 31(1): 18-27. | |
33 | 王汇彤, 翁娜, 张水昌, 等. 石油样品中金刚烷类化合物的定量分析新方法[J]. 石油实验地质, 2019, 41(3): 443-450. |
WANG H T, WENG N, ZHANG S C, et al. A novel for quantitative analysis of diamodoids in petroleum samples[J]. Petroleum Geology & Experiment, 2019, 41(3): 443-450. | |
34 | LIANG Q Y, XIONG Y Q, FANG C C, et al. Quantitative analysis of diamondoids in crude oils using gas chromatography-triple quadrupole mass spectrometry[J]. Organic Geochemistry, 2012, 43: 83-91. |
35 | 梁前勇, 熊永强, 房忱琛, 等. 两种测定原油中金刚烷化合物方法的对比研究[J]. 地球化学, 2012, 41(5): 433-441. |
LIANG Q Y, XIONG Y Q, FANG C C, et al. Comparison of two methods for the determination of diamondoids in crude oils[J]. Geochimica, 2012, 41(5): 433-441. | |
36 | 马安来, 金之钧, 朱翠山, 等. 塔里木盆地中深1C井原油高聚硫代金刚烷及金刚烷硫醇的检出及意义[J]. 中国科学: 地球科学, 2018b, 48(10): 1-12. |
MA A L, JIN Z J, ZHU C S, et al. Detection and significance of higher thiadiamondoids and diamondoidthiols in oil from the Zhongshen 1C well of the Tarim Basin, NW China[J]. Science China Earth Sciences, 2018, 48(10): 1-12. | |
37 | ZHU G Y, WANG H T, WENG N. TSR-altered oil with high-abundance thiaadamantanes of a deep-buried Cambrian gas condensate reservoir in Tarim Basin[J]. Marine and Petroleum Geology, 2016, 69: 1-12. |
38 | CAI C F, XIAO Q L, FANG C C, et al. The effect of thermochemical sulfate reduction on formation and isomerization of thiadiamondoids and diamondoids in the Lower Paleozoic petroleum pools of the Tarim Basin, NW China[J]. Organic Geochemistry, 2016, 101: 49-62. |
39 | MEI M, BISSADA K K, THOMAS B, et al. Improved method for simultaneous determination of saturated and aromatic biomarkers, organosulfur compounds and diamondoids in crude oils by GC-MS/MS[J]. Organic Geochemistry, 2018, 116: 35-50. |
40 | QIAN Y, WANG Z D, TUO J C, et al. Multiple reaction monitoring of GC/MS/MS analysis of terpanes and its application to petroleum exploration[J]. Petroleum Science and Technology, 2016, 35(2):134-140. |
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