天然气地球科学 ›› 2020, Vol. 31 ›› Issue (2): 250–257.doi: 10.11764/j.issn.1672-1926.2019.09.003

• 天然气地球化学 • 上一篇    下一篇

准噶尔盆地吉木萨尔凹陷芦草沟组页岩油偏稠成因分析

李二庭1,2(),向宝力1,2,刘向军1,2,周妮1,2,潘长春3,迪丽达尔·肉孜null1,2,米巨磊1,2   

  1. 1.中国石油新疆油田分公司实验检测研究院,新疆 克拉玛依 834000
    2.新疆砾岩油藏实验室,新疆 克拉玛依 834000
    3.中国科学院广州地球化学研究所,广东 广州 510640
  • 收稿日期:2019-07-26 修回日期:2019-09-03 出版日期:2020-02-10 发布日期:2020-02-28
  • 作者简介:李二庭(1988-),男,安徽宿州人,高级工程师,博士,主要从事油气地球化学研究.E-mail:lierting@petrochina.com.cn.

Study on the genesis of shale oil thickening in Lucaogou Formation in Jimsar Sag,Junggar Basin

Er-ting LI1,2(),Bao-li XIANG1,2,Xiang-jun LIU1,2,Ni ZHOU1,2,Chang-chun PAN3, Dilidaer·Rouzi1,2,Ju-lei MI1,2   

  1. 1.Research Institute of Experiment and Testing, Xinjiang Oilfield Company, PetroChina, Karamay 834000, China
    2.Xinjiang Laboratory of Petroleum Reserve in Conglomerate, Karamay 834000, China
    3.State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
  • Received:2019-07-26 Revised:2019-09-03 Online:2020-02-10 Published:2020-02-28

摘要:

通过研究吉木萨尔凹陷芦草沟组烃源岩母质组成、烃源岩生烃及热演化特征、成藏模式、原油次生作用,揭示了该区页岩油整体偏稠以及纵、横向原油性质差异的原因。结果表明,吉木萨尔凹陷芦草沟组页岩油未遭受生物降解,其油质偏稠的原因主要是:①芦草沟组烃源岩中无定形体、藻类等有机质十分丰富,在咸水环境下生成的原油中异构烷烃、环烷烃含量相对较高,油质相对偏稠,“下甜点”烃源岩比“上甜点”烃源岩处于咸化的更强还原环境,藻类等水生生物更发育,是造成纵向上“下甜点”页岩油较“上甜点”页岩油更稠的主要原因;②芦草沟组烃源岩有机质类型好、早期生烃,在低成熟阶段(0.5%<EASY%RO<0.8%)开始大量生烃,形成大规模低成熟页岩油,胶质和沥青质含量高,造成页岩油偏稠,“下甜点”页岩油黏度随着成熟度指标C29 αββ/(ααα+αββ)值减小逐渐增大,其横向上原油黏度分布差异受控于烃源岩成熟度演化;③芦草沟组储层可溶有机质生物标志物分布特征与其邻近烃源岩生物标志物分布特征相似,反映了芦草沟组页岩油存在近距离运移的特征,形成了源储共生型的页岩油藏,页岩油中的胶质和沥青质未被地层吸附而保留在页岩油中,造成研究区页岩油偏稠。

关键词: 页岩油, 吉木萨尔凹陷, 芦草沟组, 偏稠

Abstract:

By studying parent material composition of source rock, hydrocarbon generation and thermal evolution characteristics of source rock, hydrocarbon accumulation model and secondary oil production of oil in Lucaogou Formation in Jimsar Sag, Junggar Basin, this paper reveals reasons for the overall thickening of shale oil and the difference in longitudinal and lateral distribution of crude oil properties. The results show that shale oil in Lucaogou Formation in Jimsar Sag has not suffered from biodegradation, and the reasons for oil thickening are mainly: (1) Source rocks of Lucaogou Formation are rich in amorphous bodies and algae, and crude oils produced by such source rocks in saline water environment has a relatively high content of isoparaffins and naphthenes. The oil is relatively thick. “Low dessert” source rock is in a more salinized and more reducing environment than “top dessert” source rock, aquatic organisms such as algae are more developed, which is the main reason for “low dessert” shale oil thicker than “top dessert” shale oil. (2) Source rocks of Lucaogou Formation are characterized by good organic matter types and early hydrocarbon generation. At low maturation stage (0.5%<EASY%RO<0.8%), large amount of hydrocarbons are produced and formed large-scale low-mature shale oil, which generated more colloid and asphaltenes and caused shale oil to be thicker. Viscosity of “low dessert” shale oil increases with the decrease of maturity index C29 αββ/(ααα+αββ), indicating that difference in viscosity distribution of crude oil in the lateral direction is controlled by the evolution of source rock maturity. (3) Distribution characteristics of biomarkers in Lucaogou Formation reservoir are similar to those of adjacent source rock, reflecting close migration of shale oil in Lucaogou Formation, forming a source-storage symbiosis type. In shale reservoirs, the shale and asphaltenes are not adsorbed by the formation rocks and remain in shale oil, causing the shale oil to be thicker.

Key words: Shale oil, Jimsar Sag, Lucaogou Formation, Oil thickening

中图分类号: 

  • TE122.1+13

图1

吉木萨尔凹陷芦草沟组页岩油性质"

表1

准噶尔盆地烃源岩热模拟样品信息"

井号层位TOC/%IH /(mg/g)Tmax/℃
风南1P1f1.82506440
吉23P2l7.76663443
石树1P2p5.01698449
滴9J1b5.68209436

图2

准噶尔盆地不同类型烃源岩生烃特征"

图3

吉木萨尔页岩油成熟度分布(a)及“下甜点”页岩油成熟度与黏度关系(b)"

图4

吉木萨尔凹陷J174井“下甜点”粉砂岩及其邻近泥岩抽提物质量色谱"

图5

吉木萨尔凹陷芦草沟组烃源岩显微组成特征"

图6

吉木萨尔凹陷芦草沟组页岩油饱和烃组成特征"

图7

吉木萨尔凹陷芦草沟组页岩油生物标志物特征"

图8

吉木萨尔凹陷芦草沟组页岩油及邻区三台油田生物降解油生物标志物特征"

1 斯春松, 陈能贵, 余朝丰, 等. 吉木萨尔凹陷二叠系芦草沟组致密油储层沉积特征[J]. 石油实验地质, 2013, 35(5): 528-533.
SI C S, CHEN N G, YU C F, et al. Sedimentary characteristics of tight oil reservoir in Permian Lucaogou Formation,Jimsar Sag[J]. Petroleum Geology and Experiment, 2013, 35(5): 528-533.
2 彭永灿, 李映艳, 马辉树, 等. 吉木萨尔凹陷芦草沟组致密油藏原油性质影响因素[J]. 新疆石油地质, 2015, 36(6): 656-659.
PENG Y C, LI Y Y, MA H S, et al. Influencing factors of crude oil properties in Lucaogou tight reservoir in Jimsar Sag,Eastern Junggar Basin[J].Xinjiang Petroleum Geology, 2015,36(6): 656-659.
3 王屿涛, 杨作明, 马万云, 等. 吉木萨尔凹陷芦草沟组致密油地球化学特征及成因[J]. 新疆石油地质, 2017, 38(4): 379-384.
WANG Y T, YANG Z M, MA W Y, et al. Geochemical characteristics and genesis of tight oil in Lucaogou Formation of Jimsar Sag[J].Xinjiang Petroleum Geology, 2017,38(4):379-384.
4 魏彩茹,魏东涛,黄林军,等.新疆吉木萨尔凹陷二叠系稠油地球化学特征及成因[J].天然气地球科学,2012,23(1): 135-140.
WEI C R, WEI D T, HUANG L J, et al. Geochemical characteristics of Permian heavy oil and its origin in Jimsar sag, Xinjiang Province[J]. Natural Gas Geoscience, 2012,23(1):135-140.
5 BEHAR F, VANDENBROUCKE M, TANG Y, et al. Thermal cracking of kerogen in open and closed systems:Determination of kinetic parameters and stoichiometric coefficients foroil and gas generation[J]. Organic Geochemistry,1997, 26, 321-339.
6 HORSFIELD B, SCHENK H J, MILLS N, et al. Closed-system programmed-temperature pyrolysis for simulating the conversion of oil to gas in a deep petroleum reservoir[J]. Organic Geochemistry, 1992, 19: 191-204.
7 PEPPER A S, Dodd T A. Simple kinetic models of petroleum formation. Part II: oil-gas cracking[J]. Marine and Petroleum Geology, 1995, 12: 321-340.
8 马安来, 金之钧, 朱翠山. 塔里木盆地塔河油田奥陶系原油成熟度及裂解程度研究[J]. 天然气地球科学, 2017, 28(2): 313-323.
MA A L, JIN Z J, ZHU C S. Maturity and oil-cracking of the Ordovician oils from Tahe Oilfield, Tarim Basin, NW China[J].Natural Gas Geoscience,2017,28(2):313-323.
9 PETER K E, WALTERS C C, MOLDOWAN M. The Biomarkers Guide Volume 2: Biomarkers and Isotopes in Petroleum Exploration and Earth History[M]. Cambridge: Cambridge University Press,2005.
10 PHILP R P, GILBERT T D. Unusual distribution of biological markers in an australian crude oil[J]. Nature, 1982, 299: 245-247.
11 张枝焕, 杨藩, 李东明, 等. 中国新生界咸化湖相有机地球化学研究进展[J]. 地球科学进展, 2000, 15(1): 65-70.
ZHANG Z H, YANG P, LI D M, et al. The organic geochemistry research progress in Cenozoic salified lake in China[J]. Advance in Earth Sciences, 2000, 15(1): 65-70.
12 何川, 黄海平, 曹军, 等. 柴达木盆地石灰沟地区克鲁克组烃源岩分子地球化学表征[J]. 西安石油大学学报:自然科学版, 2019, 34(3): 1-9.
HE C, HUANG H P, CAO J, et al. Molecular geochemical characterization of source rocks in Carboniferous Keluke formation, Shihuigou area, Qaidam Basin[J]. Journal of Xi'an Shiyou University: Natural Science Edition, 2019, 34(3): 1-9.
13 SUMMONS R E, HOPE J M, SWART R, et al. Origin of Nama Basin bitumen seeps: Petroleum derived from a Permian lacustrine source rock traversing southwestern Gondwana[J]. Organic Geochemistry, 2008, 39: 589-607.
14 PEYERS K E, WALTERS C C, MOLDOWAN J M. The Biomarker Guide: Biomarkers and Isotopes in Petroleum Systems and Earth History[M]. Cambridge: Cambridge University Press, 2005: 475-477.
15 MOLDOWAN J M, SEIFERT W K, GALLEGOS E J. Relationship between petroleum composition and depositional environment of petroleum source rocks[J]. AAPG Bulletin, 1985, 69(8): 1255-1268.
16 GRANTHAM D W. Detection and discrimination of simulated motion of auditory targets in the horizontal plane[J]. The Journal of the Acoustical Society of America, 1986, 79(6): 1939-1949.
17 陈建平, 邓春萍, 王绪龙, 等. 准噶尔盆地南缘凝析油、蜡质油与稠油的形成机理[J]. 中国科学: 地球科学, 2017, 47(5): 567-585.
CHEN J P, DENG C P, WANG X L, et al. Formation mechanism of condensates, waxy and heavy oils in the southern margin of Junggar Basin, NW China[J]. Science China Earth Sciences, 2017, 47(5): 567-585.
18 徐佑德. 车排子凸起东翼石炭系稠油特征及成因分析[J]. 特种油气藏, 2019, 26(1): 50-56.
XU Y D. Characteristics and genesis analysis of Carboniferous heavy oil on east flank of Chepaizi salient[J]. Special Oil and Gas Reservoirs, 2019, 26(1): 50-56.
[1] 王志战. 页岩油储层DT2核磁共振解释方法[J]. 天然气地球科学, 2020, 31(8): 1178-1184.
[2] 陈军, 陈静, 李娜, 王忠泉. 准噶尔盆地东部石炭系天然气勘探潜力[J]. 天然气地球科学, 2020, 31(7): 952-961.
[3] 王倩茹, 陶士振, 关平. 中国陆相盆地页岩油研究及勘探开发进展[J]. 天然气地球科学, 2020, 31(3): 417-427.
[4] 李哲萱, 柳益群, 焦鑫, 周鼎武. 湖相细粒沉积岩中的“斑状”深源碎屑——以准噶尔盆地吉木萨尔凹陷芦草沟组为例[J]. 天然气地球科学, 2020, 31(2): 220-234.
[5] 李书琴, 印森林, 高阳, 张方, 李映艳, 彭寿昌. 准噶尔盆地吉木萨尔凹陷芦草沟组混合细粒岩沉积微相[J]. 天然气地球科学, 2020, 31(2): 235-249.
[6] 梁晓伟,关梓轩,牛小兵,关平,淡卫东,冯胜斌,尤源,周树勋. 鄂尔多斯盆地延长组7段页岩油储层储集性特征[J]. 天然气地球科学, 2020, 31(10): 1489-1500.
[7] 郭旭光, 何文军, 杨森, 王江涛, 冯右伦, 贾希玉, 邹阳, 王霞田, 黄立良. 准噶尔盆地页岩油“甜点区”评价与关键技术应用——以吉木萨尔凹陷二叠系芦草沟组为例[J]. 天然气地球科学, 2019, 30(8): 1168-1179.
[8] 陈旋, 刘小琦, 王雪纯, 马强, 刘俊田, 龚鑫, 杨小东, 石江峰, 白国娟. 三塘湖盆地芦草沟组页岩油储层形成机理及分布特征[J]. 天然气地球科学, 2019, 30(8): 1180-1189.
[9] 刘海涛, 胡素云, 李建忠, 王居峰, 王群一 , 姜文亚, 江涛, 赵长毅 , 张春明, 吴丰成. 渤海湾断陷湖盆页岩油富集控制因素及勘探潜力[J]. 天然气地球科学, 2019, 30(8): 1190-1198.
[10] 黄东, 杨光, 杨智, 杨天泉, 白蓉, 李育聪, 戴鸿鸣. 四川盆地致密油勘探开发新认识与发展潜力[J]. 天然气地球科学, 2019, 30(8): 1212-1221.
[11] 周立宏, 蒲秀刚, 肖敦清, 李洪香, 官全胜, 林伶, 曲宁. 渤海湾盆地沧东凹陷孔二段页岩油形成条件及富集主控因素[J]. 天然气地球科学, 2018, 29(9): 1323-1332.
[12] 石军, 邹艳荣, 余江, 刘家靖. 准噶尔盆地阜康凹陷芦草沟组高有机碳页岩发育的古环境[J]. 天然气地球科学, 2018, 29(8): 1138-1150.
[13] 曹涛涛,邓模,宋之光,刘光祥,黄俨然,Andrew Stefan Hursthouse. 黄铁矿对页岩油气富集成藏影响研究[J]. 天然气地球科学, 2018, 29(3): 404-414.
[14] 张云钊,曾联波,罗群,张晨,吴浩,吕文雅,代全齐,朱德宇. 准噶尔盆地吉木萨尔凹陷芦草沟组致密储层裂缝特征和成因机制[J]. 天然气地球科学, 2018, 29(2): 211-225.
[15] 邱振, 吴晓智, 唐勇, 郑民, 王桂君, 郭秋麟, 王社教, 谢红兵. 准噶尔盆地吉木萨尔凹陷二叠系芦草沟组致密油资源评价[J]. 天然气地球科学, 2016, 27(9): 1688-1698.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
[1] 郑建京;吉利明;孟仟祥;. 准噶尔盆地天然气地球化学特征及聚气条件的讨论[J]. 天然气地球科学, 2000, 11(4-5): 17 -21 .
[2] Seewald J S;Benitez-Netson B C;Whelan J K(美国);刘全有(译). 天然气形成与组成的实验和理论因素[J]. 天然气地球科学, 2000, 11(4-5): 30 -44 .
[3] 陈建阳,张志杰,于兴河 . AVO技术在水合物研究中的应用及应注意的问题[J]. 天然气地球科学, 2005, 16(1): 123 -126 .
[4] 李美俊;卢鸿;王铁冠;吴炜强;刘菊;高黎惠;. 北部湾盆地福山凹陷岩浆活动与CO2 成藏的关系[J]. 天然气地球科学, 2006, 17(1): 55 -59 .
[5] 施立志;林铁锋;王震亮;王卓卓;姚勇;. 库车坳陷下白垩统天然气运聚系统与油气运移研究[J]. 天然气地球科学, 2006, 17(1): 78 -83 .
[6] 王茹;. 胜坨油田两期成藏地球化学特征及成藏过程分析[J]. 天然气地球科学, 2006, 17(1): 133 -136 .
[7] 程同锦,朱怀平,陈浙春. 孔雀1井剖面地球化学特征与烃类的垂向运移[J]. 天然气地球科学, 2006, 17(2): 148 -152 .
[8] 唐友军,文志刚,窦立荣,徐佑德. 一种估算原油成熟度的新方法[J]. 天然气地球科学, 2006, 17(2): 160 -162 .
[9] 朱志敏;沈冰;闫剑飞;. 阜新盆地无机成因气探讨[J]. 天然气地球科学, 2006, 17(3): 418 -421 .
[10] 倪金龙;吕宝凤;夏斌;. 渤海湾盆地八面河缓坡带断裂系统及其对孔店组油气成藏的影响[J]. 天然气地球科学, 2006, 17(3): 370 -373 .