天然气地球科学 ›› 2019, Vol. 30 ›› Issue (11): 16081618.doi: 10.11764/j.issn.1672-1926.2019.03.002
摘要:
黄铁矿作为页岩的特征矿物,其结构特征具有重要意义,构成草莓状黄铁矿集合体的微晶在生长过程中受限于周围环境,可将其作为评判沉积环境水体环境的指标。因此,草莓状黄铁矿结构对还原古海洋沉积水体相有着重要意义。以扬子地区龙马溪组页岩中黄铁矿样品为基础,基于氩离子抛光—扫描电镜成像技术,对图像中草莓状黄铁矿集合体粒径,微晶粒径进行测量。结合龙马溪组页岩中有机质含量、硫含量数据,对黄铁矿成因和形成环境方面指示意义进行综合分析,得出以下结论:①研究区草莓状黄铁矿平均粒径、最大粒径(MFD)和集合体平均粒径与微晶平均粒径比值三者均偏小,分析沉积环境为闭塞硫化还原环境,草莓状黄铁矿微晶粒径对沉积环境的氧化还原状态具有指征意义。②草莓状黄铁矿形成于同生—准同生阶段;简单成因自行晶状黄铁矿形成于同沉积时期,复杂成因黄铁矿形成于成岩时期。③龙马溪组页岩中孔隙类型发育,黄铁矿周围伴有大量晶间有机质孔和铸模孔,黄铁矿有助于改善储层孔隙。深水陆棚相页岩中黄铁矿与有机质关系密切,对页岩气成藏开发有积极影响。
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