天然气地球科学

• 天然气地球化学 • 上一篇    下一篇

塔里木盆地轮南地区天然气地球化学特征和成因类型

吴小奇,陶小晚,刘景东   

  1. 1.中国石化石油勘探开发研究院无锡石油地质研究所,江苏 无锡 214126;
    2.中国石油勘探开发研究院,北京 100083
  • 收稿日期:2013-07-18 修回日期:2013-09-06 出版日期:2014-01-10 发布日期:2014-01-10
  • 通讯作者: 吴小奇xqwu@163.com. E-mail:xqwu@163.com.
  • 作者简介:吴小奇(1982-),男,江苏大丰人,工程师,博士,主要从事天然气地质与地球化学研究. E-mail:xqwu@163.com.
  • 基金资助:

    国家自然科学基金项目(编号:41302118)资助.

Geochemical Characteristics and Genetic Types ofNatural Gas from Lunnan Area in Tarim Basin

WU Xiao-qi,TAO Xiao-wan,LIU Jing-dong   

  1. 1.Wuxi Research Institute of Petroleum Geology,Petroleum Exploration and Production Research  Institute,SINOPEC,Wuxi 214126,China;
    2.Research Institute of Petroleum Exploration and Development,PetroChina,Beijing 100083,China
  • Received:2013-07-18 Revised:2013-09-06 Online:2014-01-10 Published:2014-01-10

摘要:

轮南地区是塔里木盆地重要的油气产区之一,目前已发现了一批大中型油气田。该区含油气层位众多,奥陶系、石炭系和三叠系中均发现了天然气。地球化学特征研究表明,轮南地区天然气以甲烷为主,重烃气含量较低,轮南、塔河、解放渠东等油气田天然气主要为湿气,而轮古东地区、桑塔木地区以干气为主,吉拉克气田三叠系和石炭系天然气主体分别为湿气和干气;甲烷碳\,氢同位素值分别为-46.7‰~-32.0‰和-190‰~-127‰,δ13C2值主体介于-39.6‰~-31.6‰之间,烷烃气碳、氢同位素系列主体表现出正序特征,受同型不同源气混合的影响,部分样品发生了甲烷、乙烷同位素部分倒转。轮南地区天然气为油型气,其中轮南油田、塔河油气田和解放渠东油田天然气主体均为干酪根裂解气,混有部分原油裂解气;而轮古东气田、桑塔木气田天然气则主要为原油裂解气;吉拉克气田三叠系天然气主体为干酪根裂解气,混有部分原油裂解气,而石炭系天然气则为典型原油裂解气。轮南油田和塔河油气田天然气则来源于寒武系—下奥陶统和中上奥陶统烃源岩,而轮古东气田、桑塔木气田、解放渠东油田和吉拉克气田天然气主体来自寒武系—下奥陶统烃源岩。

关键词: 轮南地区, 天然气, 地球化学特征, 成因, 来源

Abstract:

Lunnan area is one of the important oil and gas producing units in the Tarim Basin,and a series of oil and gas fields have been discovered.The oil and gas in the Lunnan area are reservoired in several strata,and natural gas has been found in Ordovician,Carboniferous and Triassic reservoirs.The study on geochemical characteristics of natural gas indicates that the gas in the Lunnan area is dominated by methane with a minor contribution of heavier hydrocarbons.The gases from Lunnan,Tahe and Jiefangqudong fields are wet,whereas those from Lungudong and Sangtamu fields are dry,and gases from Triassic and Carboniferous reservoirs in Jilake Field are wet and dry,respectively.The carbon and hydrogen isotopic values of methane range from -46.7‰ to -32.0‰ and from -190‰ to -127‰,respectively,and the carbon isotopic values of ethane mainly range from -39.6‰ to -31.6‰.The alkane gases generally display positive carbon and hydrogen isotopic series,and several samples display partial reversal between methane and ethane due to the influence by mixing of gases from different source with the same organic type.Gases in Lunnan area are typically oil-associated,and those from Lunnan,Tahe and Jiefangqudong fields are mainly primary kerogen cracking gas with some minor contribution of oil-cracking gas,whereas those from Lungudong and Sangtamu Fields are generally from secondary oil cracking.In Jilake Field,the Triassic-reservoired gas is mainly kerogen-cracking assisted by oil-cracking gas,whereas the Carboniferous-reservoired gas is typically from oil cracking.The gases from Lunnan and Tahe Fields were derived from both Cambrian-Lower Ordovician and Middle-Upper Ordovician source rocks,and those from Lungudong,Sangtamu,Jiefangqudong and Jilake were mainly derived from Cambrian-Lower Ordovician source rocks.

Key words: Lunnan area, Natural gas, Geochemical characteristics, Origin, Source

中图分类号: 

  • TE122.1+1
[1] Dai Jinxing.Major developments of coal-formed gas exploration in the last 30 years in China[J].Petroleum Exploration and Development,2009,36(3):264-279.[戴金星.中国煤成气研究30年来勘探的重大进展[J].石油勘探与开发,2009,36(3):264-279.]

[2] Wu Xiaoqi,Liao Fengrong,Huang Shipeng.Exploration potential of coal-derived gas in Tarim Basin[J].Natural Gas Geoscience,2011,22(6):975-981.[吴小奇,廖凤蓉,黄士鹏.塔里木盆地煤成气勘探潜力分析[J].天然气地球科学,2011,22(6):975-981.]

[3] Liu Quanyou,Jin Zhijun,Zhang Dianwei,et al.Geochemical characteristics and genesis of natural gas in Tarim Basin[J].Natural Gas Geoscience,2008,19(2):234-237.[刘全有,金之钧,张殿伟,等.塔里木盆地天然气地球化学特征与成因类型研究[J].天然气地球科学,2008,19(2):234-237.]

[4] Zhao Mengjun,Lu Shuangfang,Wang Tingdong,et al.Natural Gas Reservoirs and Exploration of Tarim Basin[M].Beijing:Petroleum Industry Press,2003:1-212.[赵孟军,卢双舫,王庭栋,等.塔里木盆地天然气成藏与勘探[M].北京:石油工业出版社,2003:1-212.]

[5] Zhang Shuichang,Liang Digang,Zhang Baomin,et al.Formation of Marine Origin Oil and Gas in Tarim Basin[M].Beijing:Petroleum Industry Press,2004:1-433.[张水昌,梁狄刚,张宝民,等.塔里木盆地海相油气的生成[M].北京:石油工业出版社,2004:1-433.]

[6] Liu Quanyou,Jin Zhijun,Wang Yi,et al.Genetic type and distribution of natural gas in Tarim Basin[J].Acta Petrolei Sinica,2009,30(1):46-50.[刘全有,金之钧,王毅,等.塔里木盆地天然气成因类型与分布规律[J].石油学报,2009,30(1):46-50.]

[7] Zhao Mengjun,Zeng Fangang,Qin Shengfei,et al.Two pyrolytic gases found and proved in Tarim Basin[J].Natural Gas Industry,2001,21(1):35-38.[赵孟军,曾凡刚,秦胜飞,等.塔里木发现和证实两种裂解气[J].天然气工业,2001,21(1):35-38.]

[8] Wang Xiaomei,Zhang Shuichang.Distribution and genesis of natural gas in Lunnan area[J].Oil & Gas Geology,2008,29(2):204-209.[王晓梅,张水昌.轮南地区天然气分布特征及成因[J].石油与天然气地质,2008,29(2):204-209.]

[9] Wang Y,Zhao C,Wang Z,et al.Identification of marine natural gases with different origin sources[J].Science in China:Series D,2008,51(supplement I):148-164.

[10] Miao Zhongying,Chen Jianfa,Zhang Chen,et al.Regularity of distribution and accumulation stages of natural gases in the Lunnan lower uplift of the Tarim Basin[J].Acta Petrolei Sinica,2011,32(3):404-410.[苗忠英,陈践发,张晨,等.塔里木盆地轮南低凸起天然气分布规律与成藏期次[J].石油学报,2011,32(3):404-410.]

[11] Liu Jingjiang,Li Mei,Liu Huirong,et al.Genetic type of Ordovician condensate gas pool in esastern Lunnan buried hill,Tarim Basin[J].Xinjiang Petroleum Geology,2006,27(2):181-183.[刘静江,李梅,刘慧荣,等.塔里木盆地轮古东奥陶系凝析气藏成因类型[J].新疆石油地质,2006,27(2):181-183.]

[12] Gao Bo,Fan Ming,Liu Wenhui,et al.Carbon isotope features and genetic type of natural gas in Tahe Oilfield[J].Oil & Gas Geology,2005,26(5):618-622.[高波,范明,刘文汇,等.塔河油田天然气的碳同位素特征及其成因类型[J].石油与天然气地质,2005,26(5):618-622.]

[13] Wang Jie,Gu Yi,Rao Dan,et al.Geochemistry,genetic type and migration and filling of Ordovician natural gas in Tahe Oilfield[J].Geochimica,2007,36(6):549-558.[王杰,顾忆,饶丹,等.塔河油田奥陶系天然气地球化学特征、成因及运移充注规律研究[J].地球化学,2007,36(6):549-558.]

[14] Mi Jingkui,Zhang Shuichang,Chen Jianping,et al.Carbon isotopic compositions and effect factors of oil from northern Tarim Basin[J].Petroleum Exploration and Development,2010,37(1):21-25.[米敬奎,张水昌,陈建平,等.塔北地区原油碳同位素组成特征及影响因素[J].石油勘探与开发,2010,37(1):21-25.]

[15] Liu Q,Dai J,Li J,et al.Hydrogen isotope composition of natural gases from the Tarim Basin and its indication of depositional environments of the source rocks[J].Science in China:Series D,2008,51(2):300-311.

[16] Liu Quanyou,Dai Jinxing,Jin Zhijun,et al.Geochemistry and genesis of natural gas in the foreland and platform of the Tarim Basin[J].Acta Geologica Sinica,2009,83(1):107-114.[刘全有,戴金星,金之钧,等.塔里木盆地前陆区和台盆区天然气的地球化学特征及成因[J].地质学报,2009,83(1):107-114.]

[17] Qin Shengfei,Li Xianqi,Xiao Zhongyao,et al.Geochemistry,origin and distribution of natural gases in Tarim Basin,NW China[J].Petroleum Exploration and Development,2005,32(4):70-78.[秦胜飞,李先奇,肖中尧,等.塔里木盆地天然气地球化学及成因与分布特征[J].石油勘探与开发,2005,32(4):70-78.]

[18]Wang Xiaofeng,Liu Wenhui,Xu Yongchang,et al.Natural gas carbon and hydrogen isotopic compositions in Tarim Basin,NW China[J].Petroleum Exploration and Development,2005,32(3):55-58.[王晓锋,刘文汇,徐永昌,等.塔里木盆地天然气碳、氢同位素地球化学特征[J].石油勘探与开发,2005,32(3):55-58.]

[19] Qian Zhihao,Cao Yin,Zhang Meizhen.Feature of hydrogen isotope composition of individual hydrocarbon in natural methane gas from the northeast part of Sichuan[J].Marine Origin Petroleum Geology,2008,13(2):17-21.[钱志浩,曹寅,张美珍.川东北天然气单体烃氢同位素组成特征[J].海相油气地质,2008,13(2):17-21.]

[20]Whiticar M J.Carbon and hydrogen isotope systematics of bacterial formation and oxidation of methane[J].Chemical Geology,1999,161(1/3):291-314.

[21] Bernard B B,Brooks J M,Sackett W M.Natural gas seepage in the Gulf of Mexico[J].Earth and Planetary Science Letters,1976,31(1):48-54.

[22] Rooney M A,Claypool G E,Moses Chung H.Modeling thermogenic gas generation using carbon isotope ratios of natural gas hydrocarbons[J].Chemical Geology,1995,126(3/4):219-232.

[23] Jenden P D,Kaplan I R.Origin of natural gas in Sacramento Basin,California[J].AAPG Bulletin,1989,73(4):431-453.

[24] Liu Wenhui,Zhang Jianyong,Fan Ming,et al.Gas generation character of dissipated soluble organic matter[J].Petroleum Geology & Experiment,2007,29(1):1-6.[刘文汇,张建勇,范明,等.叠合盆地天然气的重要来源——分散可溶有机质[J].石油实验地质,2007,29(1):1-6.] 

[25]Liu Wenhui.Research progress on manifold hydrocarbon source and its trace system in marine strata[J].Natural Gas Geoscience,2009,20(1):1-7.[刘文汇.海相层系多种烃源及其示踪体系研究进展 [J].天然气地球科学,2009,20(1):1-7.]

[26] Prinzhofer A A,Huc A Y.Genetic and post-genetic molecular and isotopic fractionations in natural gases[J].Chemical Geology,1995,126(3/4):281-290.

[27] Lorant F,Prinzhofer A,Behar F,et al.Carbon isotopic and molecular constraints on the formation and the expulsion of thermogenic hydrocarbon gases[J].Chemical Geology,1998,147(3/4):249-264.

[28] Chung H M,Gormly J R,Squires R M.Origin of gaseous hydrocarbons in subsurface environments:Theoretical considerations of carbon isotope distribution[J].Chemical Geology,1988,71(1/4):97-103.

[29] Zou Y R,Cai Y,Zhang C,et al.Variations of natural gas carbon isotope-type curves and their interpretation:A case study[J].Organic Geochemistry,2007,38(8):1398-1415.

[30] Dai J,Xia X,Qin S,et al.Origins of partially reversed alkane δ13C values for biogenic gases in China[J].Organic Geochemistry,2004,35(4):405-411.

[31] Dai Jinxing,Pei Xigu,Qi Houfa.Natural Gas Geology in China(vol.1)[M].Beijing:Petroleum Industry Press,1992:1-149.[戴金星,裴锡古,戚厚发.中国天然气地质学(卷一)[M].北京:石油工业出版社,1992 :1-149.]



 
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