李广之,胡斌
LI Guang-zhi, HU Bin
摘要:
近年来,中国油气化探分析技术取得了较大的发展,特别是烃类分析技术和方法不断地被更新和完善。在传统分析技术基础上出现了许多改进,并涌现出了一些全新的分析技术,样品采集与现场化分析技术也不断地发展。但仍存在着分析技术精细化程度不高\,高精度分析项目较少等问题。未来油气化探分析技术的发展方向:充实分析技术应用的理论基础;传统技术的改进与完善;借鉴、吸收其他学科先进分析技术;发展精细化分析技术;促进标准化进程与现场化分析技术发展;针对油气源类型进行分析技术有效组合,需重点关注和研究C6—C18烃类、多环芳烃、苯系物的检测技术;走技术综合之路。
中图分类号:
[1]Wu Chuanbi.Talk about oil and gas exploration theory and methods[J].Geophysical and Geochemical Exploration Translations,1992,28(4):140-149.[吴传璧.再谈油气化探的理论和方法[J].物探化探译丛,1992,28(4):140-149.]]
[2]Wu Chuanbi.Fifty years history of Chinese oil and gas geochemical exploration[J].Geological Bulletin of China,2009,28(11):1575-1601.[吴传璧.中国油气化探50年[J].地质通报,2009,28(11):1575-1601.] [3]Cheng Jun,Zhao Kebin,Liu Congxi,et al.Effect and significance of geochemical exploration in oil and gas prospection[J].Petroleum Geology & Experiment,2002,24(2):168-174.[程军,赵克斌,刘崇禧,等.化探在油气勘查中的作用与意义[J].石油实验地质,2002,24(2):168-174.] [4]Cheng Jun,Liu Congxi,Zhao Kebin,et al.Evidence and characteristics oil and gas vertical micro migration[J].Oil & Gas Geology,2000,21(3):226-230.[程军,刘崇禧,赵克斌,等.油气垂向微运移的证据及特点[J].石油天然气地质,2000,21(3):226-230.] [5]Tang Yuping,Zhao Kebin,Wu Chuanzhi,et al.Recent advances and developing trend of hydrocarbon geochemical exploration in China[J].Geological Bulletin of China,2009,28(11):1614-1619.[汤玉平,赵克斌,吴传芝,等.中国油气化探的近期进展和发展方向[J].地质通报,2009,28(11):1614-1619.] [6]Wu Xianghua,Cheng Tongjing,Deng Tianlong.Progress on measure mental techniques for samples of gas-oil chemical reconnaissance[J].Natural Gas Geosciences,2005,16(1):78-81.[吴向华,程同锦,邓天龙.油气化探分析检测技术现状及发展趋势[J].天然气地球科学,2005,16(1):78-81.] [7]Chen Wei,Li Guangzhi,Lu Li,et al.China Oil and Gas Industry Standard:Test Method of Geochemical Exploration for Oil and Gas Part 3:Determination of Light Hydrocarbons in Head Space:Gas Chromatography[S].Beijing:Petroleum Industry Press,2003:1-5.[陈炜,李广之,卢丽,等.中华人民共和国石油天然气行业标准:油气化探试样测定方法第3部分:顶空间轻烃的测定——气相色谱法[S].北京:石油工业出版社,2003:1-5.] [8]Chen Wei,Li Guangzhi,Lu Li,et al.China Oil and Gas Industry Standard:Test Method of Geochemical Exploration for Oil and Gas Part 1:Determination of Acidolysis Hydrocarbons:Gas Chromatography[S].Beijing:Petroleum Industry Press,2003:1-5.[陈炜,李广之,卢丽,等.中华人民共和国石油天然气行业标准:油气化探试样测定方法第1部分:酸解烃的测定——气相色谱法[S].北京:石油工业出版社,2003:1-5.] [9]Li Guangzhi,Wang Linzi.The desorption,analysis and application of adsorbed light hydrocarbon[J].Geophysical and Geochemical Exploration,2000,24(1):32-34.[李广之,汪林自.吸附态轻烃的解吸与分析[J].物探与化探,2000,24(1):32-34.] [10]Li Guangzhi,Hu Bin,Yuan Ziyan,et al.The model of light hydrocarbons adsorption & desorption[J].Natural Gas Geosciences,2006,17(4):552-558.[李广之,胡斌,袁子艳,等.轻烃的吸附与解吸模型[J].天然气地球科学,2006,17(4):552-558.] [11]Li Guangzhi,Yin Hongjun,Yuan Ziyan,et al.Petroleum geological significance of five occurrence modes of light hydrocarbon in the study of related oil and gas reservoirs in China[J].Geophysical and Geochemical Exploration,2010,34(6):772-777.[李广之,尹红军,袁子艳,等.五种赋存状态轻烃在我国相关油气藏上的石油地质意义[J].物探与化探,2010,34(6):772-777.] [12]Suo Xiaodong,Lao Wenjian.Geochemical exploration system for near-surface free hydrocarbon and its application effect[J].Petroleum Explorationist,1999,4(1):52-55.[索孝东,劳文剑.近地表游离烃化探系统及其应用效果[J].勘探家,1999,4(1):52-55.] [13]Suo Xiaodong,Li Dechun,Song Xilin.Shallow oil and gas reservoir exploration in using on-site analysis and interpretation technology of free hydrocarbons in soil[J].Geological Bulletin of China,2009,28(11):1638-1642.[索孝东,李德春,宋喜林.用壤中游离烃现场分析解释技术直接寻找浅层油气藏[J].地质通报,2009,28(11):1638-1642.] [14]Chen Wei,Hu Bin,Lu Li,et al.China Oil and Gas Industry Standard:Test Method of Geochemical Exploration for Oil and Gas Part 5:Determination of Free Hydrocarbons in:Gas Chromatography[S].Beijing:Petroleum Industry Press,2003:1-5.[陈炜,胡斌,卢丽,等.中华人民共和国石油天然气行业标准:油气化探试样测定方法第5部分:游离烃的测定——气相色谱法[S].北京:石油工业出版社,2003:1-5.] [15]Zhang Zongyuan,Wang Guojian.Petroleum geochemical exploration significance of soil free hydrocarbons technique[J].Natural Gas Industry,2004,24(6):30-32.[张宗元,王国建.土壤中游离烃技术的油气化探意义[J].天然气工业,2004,24(6):30-32.] [16]Ren Chun,Sun Changqing,Tang Yuping,et al.The collection and application of soil gas hydrocarbon in oil and gas exploration[J].Geophysical and Geochemical Exploration,2010,34(1):63-66.[任春,孙长青,汤玉平,等.油气勘探中壤气烃的采集与应用[J].物探与化探,2010,34(1):63-66.] [17]Chen Wei,Hu Bin,Lu Li,et al.China Oil and Gas Industry Standard:Test Method of Geochemical Exploration for Oil and Gas Part 4:Determination of Thermal released Hydrocarbons:Gas Chromatography[S].Beijing:Petroleum Industry Press,2003:1-5.[陈炜,胡斌,卢丽,等.中华人民共和国石油天然气行业标准:油气化探试样测定方法第4部分:热释烃的测定——气相色谱法[S].北京:石油工业出版社,2003:1-5.] [18]Feng Xiaoshuang,Li Guiyou.Application of the pyrolysis desorbed hydrocarbon technology to the geochemical exploration of gas and oil[J].Petroleum Geology & Experiment,1999,21(1):91-94.[冯晓双,李贵友.热释烃技术在油气化探中的应用[J].石油实验地质,1999,21(1):91-94.] [19]Chen Wei,Li Guangzhi,Lu Li,et al.China Oil and Gas Industry Standard:Test Method of Geochemical Exploration for Oil and Gas Part 2:Determination of Soluble Hydrocarbons:Gas Chromatography[S].Beijing:Petroleum Industry Press,2003:1-5.[陈炜,李广之,卢丽,等.中华人民共和国石油天然气行业标准:油气化探试样测定方法第2部分:溶解烃的测定——气相色谱法[S].北京:石油工业出版社,2003:1-5.] [20]Dai Jinxing.Natural gas and hydrogen isotope features all kinds of gas differential[J].Natural Gas Geosciences,1993,4(2/3):1-40.[戴金星.天然气碳氢同位素特征和各类天然气鉴别[J].天然气地球科学,1993,4(2/3):1-40.] [21]Liu Congxi,Xu Shirong.Geochemical Prospecting Methods and Applications[M].Hefei:Press of University of Science and Technology of China,1992:74-78.[刘崇禧,徐世荣.油气化探方法与应用[M].合肥:中国科技大学出版社,1992:74-78.] [22]Li Tao,Zhao Luzi,Lu Zhengyuan,et al.Reserch on the gas source of Jialingjiang Formation in south Sichuan Basin[J].Natural Gas Industry,2005,25(12):1-3.[李弢,赵路子,陆正元,等.川南地区嘉陵江组天然气气源研究[J].天然气工业,2005,25(12):1-3.] [23]Gao Xiaokang,Song Yan,Liu Shaobo,et al.A discussion on the comparison of carbon isotope values of coalbed methane[J].Natural Gas Industry,2010,30(6):1-4.[高小康,宋岩,柳少波,等.关于煤层气甲烷碳同位素值对比的探讨[J].天然气工业,2010,30(6):1-4.] [24]Qin Yong,Tang Xiuyi,Ye Jianping,et al.Characteristics and origins of stable carbon isotope in coalbed methane of China[J].Journal of China University of Mining & Technology,2000,29(2):113-119.[秦勇,唐修义,叶建平,等.中国煤层甲烷稳定碳同位素分布与成因探讨[J].中国矿业大学学报:自然科学版,2000,29(2):113-119.] [25]Yang Yichuan.A few questions about coal gas composition and methane carbon isotope[J].Guizhou Geology,1992,9(1):99-108.[杨宜春.关于煤成气组分和甲烷碳同位素的几个问题[J].贵州地质,1992,9(1):99-108.] [26]Li Shaojie.Application of methane carbon isotope in geochemical exploration for oil and gas and the resolution to its existing problems[J].Mineral Resources and Geology,2003,17(1):54-58.[黎绍杰.油气化探中甲烷碳同位素应用、存在问题与对策研究[J].矿产与地质,2003,17(1):54-58.] [27]Wang Guojian,Cheng Tongjin,Tang Yuping,et al.The application of δ13C1 to surface geochemical exploration and its existing problems[J].Geophysical and Geochemical Exploration,2008,32(5):549-551.[王国建,程同锦,汤玉平,等.地表化探中甲烷稳定碳同位素的应用及存在问题[J].物探与化探,2008,32(5):549-551.] [28]Zhang Jinlai.The application of methane stable carbon isotope in oil and gas geochemical exploration[J].Geophysical and Geochemical Exploration,1988,12(2):123-128.[张金来.甲烷稳定碳同位素在油气化探中的应用[J].物探与化探,1988,12(2):123-128.] [29]Tang Junhong,Bao Zhengyu,Xiang Wu,et al.On-line method for measurement of the carbon isotope ratio of atmospheric methane and its application to atmosphere of Yakela condensed gas field[J].Environmental Science,2006,27(1):13-17.[唐俊红,鲍征宇,向武,等.大气甲烷碳同位素测试方法及其在雅克拉凝析气田上方大气中的应用[J].环境科学,2006,27(1):13-17.] [30]Ruan Tianjian,Fei Qi.Oil and Gas Geochemical Exploration[M].Wuhan:China University of Geosciences Press,1992:126-129.[阮天健,费琪.石油天然气地球化学勘探[M].武汉:中国地质大学出版社,1992:126-129.] [31]Sun Yan.The Gas Hydrate Geochemical Exploration in South Sea of China and the Vision Forecast of Xisha Trough-Qiongdongnan Basin[D].Beijing:The China University of Geosciences,2007.[孙艳.南海天然气水合物地球化学勘探及西沙海槽一琼东南盆地远景预测[D].北京:中国地质大学,2007.] [32]Pu Yanping,Sun Chuanyan,Chen Shicheng,et al.Geochemical prospecting of natural gas hydrate and resource evaluation in Qiongdongnan Basin-Xishan Trough of South China Sea[J].Geological Bulletin of China,2009,28(11):1656-1661.[蒲燕萍,孙春岩,陈世成,等.南海琼东南盆地—西沙海槽天然气水合物地球化学勘探与资源远景评价[J].地质通报,2009,28(11):1656-1661.] [33]Li Guangzhi,Cheng Tongjin,Tang Yuping,et al.The petroleum geological significance of geophysical-absorbed-hydrocarbons[J].Petroleum Geology & Experiment,2006,28(5):484-488.[李广之,程同锦,汤玉平,等.物理吸附气的油气指示意义[J].石油实验地质,2006,28(5):484-488.] [34]Belartdi R G,Pawliszyn J.The application of chemically modified fused silica fibers in the extraction of organics from water matrix samples and their rapid transfer to capillary columns[J].Water Pollution,1989,24:179-191. [35]Scott A H,Michael J,Magnus K E.Molecular and isotopic analysis of oils by solid phase microextraction of gasoline range hydrocarbons[J].Organic Geochemistry,1999,30:721-737. [36]Hu Bin,Li Shuanglin,Li Guangzhi,et al.SPME technique and its application in the oil and gas geochemical exploration[J].Marine Geology Letters,2009,25(12):8-13.[胡斌,李双林,李广之,等.固相微萃取技术及其在油气地球化学探测中的应用[J].海洋地质动态,2009,25(12):8-13.] [37]Ministry of Health,the State Environmental Protection Administration.Chinese National Standards.Indoor Air Quality Standard(GB/T18883-2002)[S].Beijing:Standards Press of China,2002:7-12.[卫生部、国家环境保护总局《室内空气质量标准》联合起草小组.中华人民共和国国家标准:室内空气质量标准(GB/T18883-2002)[S].北京:中国标准出版社,2002:7-12.] [38]Hu Bin,Chen Wei,Cheng Gui,et al.China Oil and Gas Industry Standard:Test Method of Geochemical Exploration for Oil and Gas Part 8:Determination of the Polynuclear Aromatic Hydrocarbons:Fluorometry[S].Beijing:Petroleum Industry Press,2003:1-5.[胡斌,陈炜,程桂,等.中华人民共和国石油天然气行业标准:油气化探试样测定方法第8部分:稠环芳烃测定——荧光法[S].北京:石油工业出版社,2003:1-5.] [39]Hu Bin,Chen Wei,Cheng Gui,et al.China Oil and Gas Industry Standard:Test Method of Geochemical Exploration for Oil and Gas Part 9:Determination of the Gross Amount of Aromatic Hydrocarbons and Their Ramifications:Ultraviolet Spectroscopy[S].Beijing:Petroleum Industry Press,2003:1-5.[胡斌,陈炜,程桂,等.中华人民共和国石油天然气行业标准:油气化探试样测定方法第9部分:芳烃及其衍生物总量测定——紫外光谱法[S].北京:石油工业出版社,2003:1-5.] [40]Hu Bin,Li Guangzhi,Wu Xianghua,et al.Discussion on cutting fluorologging technique and quantitative method[J].Natural Gas Geosciences,2007,18(1):121-124.[胡斌,李广之,吴向华,等.岩屑荧光录井技术及荧光指标量化方法[J].天然气地球科学,2007,18(1):121-124.] [41][KG*2/3]Hu Bin,Li Wu,Cheng Gui.The Application of coupling HPLC[JP]-DAD-FD to the test of aromatic hydrocarbon in oil and gas geochemical samples[J].Geophysical and Geochemical Exploration,2003,27(2):101-103.[胡斌,李武,程桂.HPLC-DAD-FD联用检测油气化探样品的芳烃[J].物探与化探,2003,27(2):101-103.] [42]Hu Bin,Yuan Ziyan,Deng Tianlong.Wavelength selection when detected aromatic in HPLC analysis[J].Chemical Analysis and Meterage,2006,15(3):53-54.[胡斌,袁子艳,邓天龙.高效液相色谱法分析芳烃时检测波长的选择[J].化学分析计量,2006,15(3):53-54.] [43]Guan Wenna,Liu Wenmin,Zhao Jinghong,et al.Solid phase extraction technology and its application in pesticide residues and organic contaminants[J].Modern Scientific Instruments,2007,(1):11-1.[观文娜,刘文民,赵景红,等.固相萃取技术及其在农残和有机污染物方面的应用[J].现代科学仪器,2007,(1):11-1.] [44]Li Qingling,Xu Xiaoqin,Li Xianchuan.The determination of polycyclic aromatic hydrocarbons in sediments with ASE/GC-MS[J].Journal of Instrumental Analysis,2006,25(15):33-37.[李庆玲,徐晓琴,黎先春.加速溶剂萃取/气相色谱—质谱测定海洋沉积物中的痕量多环芳烃[J].分析测试学报,2006,25(15):33-37.] [45]Dong Ling,Zhou Ruize,Wu Shuqi,et al.Rapid analysis of polycyclic aromatic hydrocarbons by GC-MS in soil[J].Journal of Instrumental Analysis,2008,27(supplement):124-126.[佟玲,周瑞泽,吴淑琪,等.土壤样品中多环芳烃的GC-MS快速分析方法[J].分析测试学报,2008,27(增刊):124-126.] [46]Sun Chuanyan,Xiao Guiyi,Niu Binghua,et al.Study and application of BTEX molecular tracer for the oil and gas resources prospecting in oceans[J].Earth Science Frontiers,2004,11(4):601-607.[孙春岩,肖桂义,牛滨华,等.芳香族分子示踪在海洋油气勘探中的开发和应用[J].地学前缘,2004,11(4):601-607.] [47]Chu Xiaolu,Yang Zuosheng.The Research on Laser Single Molecule Benthal Oil and Gas Geochemical Peospecting Synthetical Evaluation Technique[D].Qingdao:China Ocean University,2007.[初晓璐,杨作升.激光单分子海洋油气化探综合评价技术研究[D].青岛:中国海洋大学,2007.] [48]Zhang Zhanen,Luo Sanshan,Zhang Lijun,et al.Determination of benzenes in soil by headspace liquid-phase microextraction-GC/MS[J].Modern Scientific Instruments,2010,(3):64-67.[张占恩,罗三姗,张丽君,等.顶空液相微萃取-GC/MS法测定土壤中的苯系物[J].现代科学仪器,2010,(3):64-67.] [49]Dalian Municipal Environmental Monitoring Center.China National Environmental Protection Standards.Ambient Air-Determination of Benzene and its Analogies by Activated charcoal Adsorption Carbon Disulfide Desorption and Gas Chromatography(HJ 584-2010)[S].Beijing:China Environmental Press,2010:1-9.[大连市环境监测中心.中华人民共和国国家环境保护标准.“环境空气苯系物的测定:活性炭吸附/二硫化碳解吸——气相色谱法”(HJ 584-2010)[S].北京:中国环境出版社,2010:1-9.] [50]Fu Jianhua,Ai Xingtao,Liu Haisheng,et al.Determination of trace benzene,toluene,ethylbenzene and xylenes in seabed sediments and seawater by purge and trap gas chromatography[J].Chinese Journal of Analytical Chemistry,2005,33(12):1753-1756.[傅剑华,艾星涛,刘海生,等.吹扫捕集一气相色谱分析海水和沉积物中的苯、甲苯、乙苯及二甲苯[J].分析化学研究简报,2005,33(12):1753-1756.] [51]Liu Haisheng,Ai Xingtao,Ma Wanyun,et al.Geochemical investigation for oil and gas in middle sag of Bohai Basin[J].Journal of China University of Petroleum:Edition of Natural Science,2005,29(1):17-21.[刘海生,艾星涛,马万云,等.渤海盆地中部凹陷油气地球化学勘查[J].石油大学学报:自然科学版,2005,29(1):17-21.] [52]Wang Junqi,Shi Xiangyang,Yang Guangwei,et al.Determination of BTEX compounds in debris samples by micellar electrokinetic capillary chromatography[J].Rock and Mineral Analysis,2000,19(2):93-96.[王俊奇,史向阳,杨光伟,等.胶束电动毛细管色谱法测定岩屑样品中的苯系化合物[J].岩矿测试,2000,19(2):93-96.] [53]Wang Junqi,Shi Xiangyang,Zhang Songwei,et al.Determination of BTEX compounds in marine shallow sediments by micellar electrokinetic capillary chromatography[J].Rock and Mineral Analysis,2001,20(1):20-22.[王俊奇,史向阳,张松伟,等.胶束电动毛细管色谱法测定海底表层沉积物中的苯系化合物[J].岩矿测试,2001,20(1):20-22.] [54]Wang Guojian,Cheng Tongjin,Tang Yuping,et al.The advance in applying the trace element method to near-surface oil and gas geochemical exploration[J].Geophysical & Geochemical Exploration,2006,30(3):236-239.[王国建,程同锦,汤玉平,等.微量元素方法应用于近地表油气化探研究进展[J].物探化探,2006,30(3):236-239.] [55]Li Guangzhi,Chen Yinjie,Yin Hongjun et al.Study on the petroleum geological significance of soluble cation in near-surface soil[J].Natural Gas Geosciences,2011,22(2):198-202.[李广之,陈银节,尹红军,等.近地表土壤中可溶态阳离子的石油地质意义研究[J].天然气地球科学,2011,22(2):198-202.] [56]Li Guangzhi,Chen Yinjie,Yin Hongjun et al.Study on the petroleum geological significance of soluble ation in near-surface soil[J].Geophysical & Geochemical Exploration,2011,35(2):198-202.[李广之,陈银节,尹红军,等.近地表土壤中可溶态阴离子的石油地质意义[J].物探与化探,2011,35(2):198-202.] [57]Chen Wei,Lu Guiyou,Li Guangzhi,et al..China Oil and Gas Industry Standard:Test Method of Geochemical Exploration for Oil and Gas Part 7:Determination of Thermal released Mercury[S].Beijing:Petroleum Industry Press,2003:1-5.[陈炜,李贵友,李广之,等.中华人民共和国石油天然气行业标准:油气化探试样测定方法第7部分:热释汞的测定[S].北京:石油工业出版社,2003:1-5.] [58]Chen Wei,Lu Guiyou,Li Guangzhi,et al..China Oil and Gas Industry Standard:Test Method of Geochemical Exploration for Oil and Gas Part 6:Determination of Alterative Carbnate(ΔC)[S].Beijing:Petroleum Industry Press,2003:1-5.[陈炜,李贵友,李广之,等.中华人民共和国石油天然气行业标准:油气化探试样测定方法第6部分:蚀变碳酸盐(ΔC)测定的测定[S].北京:石油工业出版社,2003:1-5.] [59]Wu Chuanzhi.Microbial oil and gas exploration technique and its application[J].Natural Gas Geosciences,2005,16(1):82-87.[吴传芝.微生物油气勘探技术及其应用[J].天然气地球科学,2005,16(1):82-87.] [60]Mei Bowen,Yuan Zhihua.Application to geo-microbiological techniques to oil and gas exploration and development[J].Natural Gas Geosciences,2004,15(2):156-161.[梅博文,袁志华.地质微生物技术在油气勘探开发中的应用[J].天然气地球科学,2004,15(2):156-161.] [61]Mei Bowen,Yuan Zhihua,Wang Xiuyuan.Microbiological prospecting of oil and gas[J].China Petroleum Exploration,2002,7(3):42-53.[梅博文,袁志华,王修垣.油气微生物勘探法[J].中国石油勘探,2002,7(3):42-53.] [62]Yuan Zhihua,Mei Bowen,She Yuehui,et al.Application of gas microbial prospecting:Take Xiliu structure of Duxian slope as a case study[J].Natural Gas Industry,2003,23(2):26-30.[袁志华,梅博文,佘跃惠,等.天然气微生物勘探研究——以蠡县斜坡西柳构造为例[J].天然气工业,2003,23(2):26-30.] [63]Yuan Zhihua,Mei Bowen,She Yuehui.Microbiological prospecting for oil and gas in manite depression of Erlian Basin[J].Petroleum Exploration and Development,2002,29(3):64-65.[袁志华,梅博文,佘跃惠.二连盆地马尼特坳陷油气微生物勘探[J].石油勘探与开发,2002,29(3):64-65.] [64]Yuan Zhihua,Mei Bowen,She Yuehui,et al.Application of microbial prospecting technology to oil and gas exploration in Xiliu area[J].Acta Petrolei Sinica,2002,23(6):29-31.[袁志华,梅博文,佘跃惠,等 石油微生物勘探技术在西柳地区的应用[J].石油学报,2002,23(6):29-31.] [65]Deng Ping,Wang Guojian,Liu Yunli.Experimental study of microbiological oil and gas exploration techniques[J].Natural Gas Industry,2003,23(1):18-21.[邓平,王国建,刘运黎.微生物油气勘探技术的试验研究[J].天然气工业,2003,23(1):18-21.] [66]Zhang Jianpei,Wang Fei.The effects of microbiological method in the oil and gas exploration within a certain area of the East China Sea[J].Geophysical and Geochemical Exploration,1995,19(6):474-477.[张建培,王飞.微生物方法在东海某区油气勘查中的应用效果[J].物探与化探,1995,19(6):474-477.] [67]Zhang Jianpei,Sheng Zurong,Wang Fei,et al.Technique of microbiological petroleum exploration and its results of application in East China Sea[J].Petroleum Geology & Experiment,1995,19(3):272-295.[张建培,沈祖荣,王飞,等.微生物油气勘查技术及其在东海的应用效果[J].石油实验地质,1995,19(3):272-295.] [68]Wang Guojian,Deng Ping,Xia Xianghua.Experimental study of microbiological petroleum exploration:Taking Shiwu fault depression of the Songliao Basin as an example[J].Natural Gas Geosciences,2006,26(4):8-10.[王国建,邓平,夏响华.微生物方法在油气勘探中的试验研究——以松辽盆地十屋断陷为例[J].天然气地球科学,2006,26(4):8-10.] [69]Ling Renzi,Mei Bowen,Mei Hai.Additional suggestion to hydrocarbon surface geochemistry-national reconnaissance[J].Geological Bulletin of China,2009,28(11):1539-1540.[林壬子,梅博文,梅海.对《油气化探全国扫面计划》的补充建议[J].地质通报,2009,28(11):1539-1540.] [70]Suo Xiaodong.Rapid response multi-parameter application effect of oil and gas geochemical exploration[J].Oil Geophysical Prospecting,1995,30(supplement 1):136-139.[索孝东.多参数快速反应油气化探的应用效果[J].石油地球物理勘探,1995,30(增刊1):136-139.] [71]Chen Dongjiao.RapidSeabed Mineral Resources Exploration Geochemical Techniques[EB/OL].http://tech.tech110.net/html/article_435914.html.[陈东娇.海底矿产资源的地球化学快速探查技术[EB/OL].http://tech.tech110.net/html/article_435914.html] [72]Wu Chuanzhi,Cheng Tongjin,Zhu Huaiping,et al.Advances in offshore geochemical hydrocarbon exploration[J].China Offshore Oil and Gas,2006,18(1):22-27.[吴传芝,程同锦,朱怀平,等.海洋油气化探研究进展[J].中国海上油气,2006,18(1):22-27.] [73]Wang Weixi,Sun Chuanyan,Yang Hui,et al.Investigation to on-site detection system for gaseous hydrocarbon with high sensitivity be used to explore gas and oil in sea[J].Earth Science:Journal of China University of Geosciences,2004,29(2):163-168.[王维熙,孙春岩,杨慧,等.海洋油气勘探中高灵敏度气态烃现场探测系统的研制[J].地球科学:中国地质大学学报,2004,29(2):163-168.] [74]Lei Tianci,Zhu Mingqiang,Zhou Wanpeng.Application on data mining of hyperspectrum to identification and extraction of alteration minerals[J].Resources Environment & Engineering,2005,19(3):213-219.[雷天赐,祝明强,周万蓬.高光谱数据挖掘在蚀变矿物识别与提取中的应用[J].资源环境与工程,2005,19(3):213-219.] [75]Yang Yushan,Li Yuanyuan,Liu Tianyou.Order statistics in seismic weak signal and "magnetic bright spot" recognition[J].Oil Geophysical Prospecting,2005,40(1):103-107.[杨宇山,李媛媛,刘天佑.高阶统计量在地震弱信号及“磁亮点”识别中的应用[J].石油地球物理勘探,2005,40(1):103-107.] [76]Zhu Huaiping,Xia Xianghua,Sun Lichuan,et al.Comprehensive evaluation of trap petroliferous nature using geochemical seismic prospecting method:An example of south Songliao Basin[J].Xinjiang Petroleum Geology,2004,25(8):394-396.[朱怀平,夏响华,孙立春,等.化探—地震法综合评价圈闭含油气性——以松南盆地为例[J].新疆石油地质,2004,25(8):394-396.] [77]Zhao Yuhua,Zhang Mengbo.Hydrocarbon detecting technique of Psh8 gas reservoirs in Orods Basin[J].Natural Gas Industry,2005,25(5):40-42.[赵玉华,张盟勃.鄂尔多斯盆地盒8段气藏烃类检测技术研究[J].天然气工业,2005,25(5):40-42.] [78]Hu Xiaoqiang,Liu Zhenhu.Seismic reservoir prediction and hydrocarbon detection without well for structure A in the north Yellow Sea Basin[J].South China Journal of Seismology,2009,29(2):62-70.[胡小强,刘振湖.无井地震储层预测及烃类检测——以北黄海中部坳陷A构造为例[J].华南地震,2009,29(2):62-70.] [79]Lu Li,Li Wu,Li Jipeng.The development and preparation of the standard sample of acidolysis hydrocarbons for geochemical exploration[J].Geophysical & Geochemical Exploration,2010,34(2):180-184.[卢丽,李武,李吉鹏.油气化探酸解烃标准样品研制[J].物探与化探,2010,34(2):180-184.] [80]Xie Xuejin,Sun Zhongjun.Hydrocarbon surface geochemistry-national reconnaissance(HSGNR Program,a Proposal)[J].Geological Bulletin of China,2009,28(11):1536-1538.[谢学锦,孙忠军.油气化探全国扫面计划[J].地质通报,2009,28(11):1536-1538.] [81]Chen Yinjie,Yao Yaming,Zhao Xin.The application of the three-dimensional fluorescence technique to the recognition of oil and gas properties[J].Geophysical & Geochemical Exploration,2007,31(2):138-142.[陈银节,姚亚明,赵欣.利用三维荧光技术判识油气属性[J].物探与化探,2007,31(2):138-142.][JP] [82]Zhang Yong,Cao Xueqing,Meng Xiangjun,et al.BTEX anomalies used as indicators of submarine oil and gas reservoirs[J].Acta Oceanologica Sinica,2008,30(1):80-85.[张勇,曹雪晴,孟祥军,等.BTEX异常对海域油气藏指示作用的研究[J].海洋学报,2008,30(1):80-85.] [83 ]Jones V T,Burtell S G.Hydrocarbon flux variations in natural and anthropogenic seeps[C]∥Schumacher D,Abrams M A,eds.Hydrocarbon Migration and It s Near-surface Expression.AAPG Memoir 66.Houston:AAPG,1996:203-221. [84]Ma Wanyun,Xiong Jing,Wen Keling,et al.Research on laser-induced single-molecule detection technology[J].Journal of Atomic and Molecular Physics,1995,12(4):357-3621.[马万云,熊京,文克玲,等.激光单分子探测技术的研究[J].原子与分子物理学报,1995,12(4):357-3621.] [85]Hawkins J L,Cal Houn G G.Ground water seems not to influence BTEX surface geochemistry[J].Oil & Gas Journal,2001,8:32-36.
|
[1] | 彭威龙,胡国艺,刘全有,贾楠,房忱琛,龚德瑜,于聪,吕玥,王鹏威,冯子齐. 热模拟实验研究现状及值得关注的几个问题[J]. 天然气地球科学, 2018, 29(9): 1252-1263. |
[2] | 李广之,毕文涛,胡斌,张宗元, 周琼,高伟,俞蓉新. 多环芳烃菲指标在油气化探中的应用[J]. 天然气地球科学, 2016, 27(6): 1067-1073. |
[3] | 杨华敏,王杰,陶成,刘文汇. 储层岩石中稀有气体组分和同位素分析技术[J]. 天然气地球科学, 2016, 27(4): 681-687. |
[4] | 远光辉,操应长,贾珍臻,王艳忠,杨田. 含油气盆地中深层碎屑岩储层异常高孔带研究进展[J]. 天然气地球科学, 2015, 26(1): 28-42. |
[5] | 杨占龙,黄云峰,吴青鹏,黄小鹏,韩小峰,牛慧赟. 吐鲁番坳陷隐伏巨型弧形构造体系与油气勘探[J]. 天然气地球科学, 2014, 25(8): 1156-1163. |
[6] | 蒋涛,汤玉平,吴向华,张恒启. 油气化探在低渗透油气资源勘探中的应用——以英南2气藏、鄂尔多斯盆地某油藏为例[J]. 天然气地球科学, 2013, 24(4): 790-797. |
[7] | 刘文汇,王杰,陶成,胡广,卢龙飞,王萍. 中国海相层系油气成藏年代学[J]. 天然气地球科学, 2013, 24(2): 199-209. |
[8] | 赵克斌,蒋涛,张恒启. 油气化探地球化学场分析及研究[J]. 天然气地球科学, 2012, 23(6): 1090-1096. |
[9] | 付锁堂,关平,张道伟. 柴达木盆地近期勘探工作思考[J]. 天然气地球科学, 2012, 23(5): 813-819. |
[10] | 黄欣, 陈银节. 黄土覆盖区游离烃技术与应用[J]. 天然气地球科学, 2009, 20(3): 436-441. |
[11] | 刘文汇. 海相层系多种烃源及其示踪体系研究进展[J]. 天然气地球科学, 2009, 20(1): 1-7. |
[12] | 王作栋,;陶明信;孟仟祥;李中平;王晓锋;王志勇;杜宏宇 . 吐哈盆地烃源岩研究进展与低演化油气的形成[J]. 天然气地球科学, 2008, 19(06): 754-760. |
[13] | 陶明信, ;解光新 . “煤层气的形成演化、成因类型及资源贡献”课题研究进展[J]. 天然气地球科学, 2008, 19(06): 894-896. |
[14] | 刘小平;杨晓兰. 海底天然气水合物地球化学方法勘探进展[J]. 天然气地球科学, 2007, 18(2): 312-316. |
[15] | 李广之,胡 斌,邓天龙,袁子艳 . 不同赋存状态轻烃的分析技术及石油地质意义[J]. 天然气地球科学, 2007, 18(1): 111-116. |
|