李苗春,丁海,焦堃,姚素平
LI Miao-chun,DING Hai,JIAO Kun,YAO Su-ping
摘要:
扬子地区下寒武统广泛发育了1套黑色岩系,被认为是中国南方4套海相烃源岩之一。但由于该套烃源岩时代老、有机质成熟度高,故对其有机岩石学特征探讨还没有定论。通过光片、薄片的对比观察,结合扫描电镜和能谱等分析,详细研究了研究区下寒武统黑色岩系的有机岩石学特征,并尝试性地探讨了其油气地质意义。结果表明湘西三岔地区下寒武统黑色岩系中的有机质可划分为有形态组分、无形态组分。其中有形态组分又可分为植物藻类组(层状藻类体、结构藻类体Ⅰ、结构藻类体Ⅱ)、动物有机组、细菌型的菌类体及混合型海相镜质体;无形态组分主要为微粒体和沥青质体。从观察到的有机质组分反映了该套黑色岩系的生源母质具有多重属性,但从统计的各组分含量上来讲主要为浮游菌藻类、底栖宏观藻类、浮游动物和底栖海绵等,其有机质类型主要为Ⅰ型和Ⅱ型。系统的有机岩石学研究表明有机质差异主要是由母质类型的差异所造成,宏观底栖藻类和大型低等水生植物(如浅海底栖叶状体植物)的发育是形成Ⅱ型有机质的主要因素。对牛蹄塘组有机岩石学特征的分析为该套黑色岩系的油气生成潜力的研究提供了重要基础。
中图分类号:
[1]Wu Chaodong,Chen Qiying,Yang Chengyun.The black shale series and ore-bearing sequences of upper Sinian-lower Cambrian,southwest of China[J].Acta Sedimentologica Sinica,1999,17(2):169-175.[吴朝东,陈其英,杨承运.湘西黑色岩系沉积演化与含矿序列[J].沉积学报,1999,17(2):169-175.][2]Wu Chaodong,Chen Qiying,Lei Jiajin.The genesis factors and organic petrology of black shale series from the upper Sinian to the lower Cambrian,southwest of China[J].Acta Petrologica Sinica,1999,15(3):453-462.[吴朝东,陈其英,雷加锦.湘西震旦—寒武纪黑色岩系的有机岩石学特征及其形成条件[J].岩石学报,1999,15(3):453-462.][3]Zhao Yuanlong,Steiner M,Yang Ruidong,et al .Discovery and significance of the early metazoan biotas from the lower Cambrian Niutitang Formation in Zunyi,Guizhou,China[J].Acta Palaeontologica Sinica,1999,38(supplement):132-144.[赵元龙,Steiner M,杨瑞东,等.贵州遵义下寒武统牛蹄塘组早期后生生物群的发现及意义[J].古生物学报,1999,38(增刊):132-144.][4]Wu Chaodong.Recovery the paleoocean environment in the alternating epoch of late Simian and early Cambrian in the west Hunan[J].Earth Science Frontiers,2000,7(B8):45-57.[吴朝东.湘西震旦—寒武纪交替时期古海洋环境的恢复[J].地学前缘,2000,7(B8):45-57.][5]Chen Xiaohong,Wang Xiaofeng.Biota and organic matter in late Sinian and early Cambrian black rock series of west Hunan and their significance tometallization[J].Geology and Mineral Resources of South China,2000,(1):16-23.[陈孝红,汪啸风.湘西地区晚震旦世—早寒武世黑色岩系的生物和有机质及其成矿作用[J].华南地质与矿产,2000,(1):16-23.][6]Fan Delian,Zhao Tao,Ye Jie,et al .China′s Black Rock and the Relevant Department Deposit[M].Beijing:Science Press,2004.[范德廉,张焘,叶杰,等.中国的黑色岩系及其有关矿床[M].北京:科学出版社,2004.][7]Zeng Qinghui,Qian Ling,Liu Dehan,et al .Organic petrological study on hydrocarbon generation and expulsion from organic-rich black shale and oil shale[J].Acta Sedimentologica Sinica,2006,24(1):113-122.[曾庆辉,钱玲,刘德汉,等.富有机质的黑色页岩和油页岩的有机岩石学特征与生、排烃意义[J].沉积学报,2006,24(1):113-122.][8]Zhou Jie,Hu Kai,Bian Lizeng,et al .Geochemical characteristics and ore-forming processes of Ni-Mo polymetallic deposits in lower Cambrian black shale,Zunyi,Guizhou province[J].Mineral Deposits,2008,27(6):742-750.[周洁,胡凯,边立曾,等.贵州遵义下寒武统黑色岩系Ni—Mo多金属矿地球化学特征及成矿作用[J].矿床地质,2008,27(6):742-750.][9]Yang Jian.Study on the Formation Environment and Geochemistry of Lower Cambrian Black Shale Series,Northern Guizhou Province,China[D].Xi′an:Chang′an University,2009.[杨剑.黔北地区下寒武统黑色岩系形成环境与地球化学研究[D].西安:长安大学,2009.][10]Huang Yan.Sedimentology and Geochemistry of the Black Rock Series in Early Cambrian Niutitang Formation in Zhangjiajie,Hunan[D].Sichuan:Chengdu University of Technology,2011:29-42.[黄燕.湖南张家界地区寒武系牛蹄塘组黑色岩系沉积地球化学研究[D].四川:成都理工大学,2011:29-42.][11]Zhao Zongju,Zhu Yan,Xu Yunjun.Formation rules and prediction of exploration targets of Paleozoic-Mesozoic oil-gas reservoirs in southern China[J].Acta Geologica Sinica,2004,78(5):710-720.[赵宗举,朱琰,徐云俊.中国南方古生界—中生界油气藏成藏规律及勘探方向[J].地质学报,2004,78(5):710 -720.][12][KG*6/7]Tenger,Gao Changlin,Hu Kai,et al .High quality source rocks of lower combination in the northern upper-Yangtze area and their hydrocarbon potential[J].Natural Gas Geoscience,2007,18(2):254-259.[腾格尔,高长林,胡凯,等.上扬子北缘下组合优质烃源岩分布及生烃潜力评价[J].天然气地球科学,2007,18(2):254-259.][13]Chen Bo,Lan Zhengkai.Lower Cambrian shale gas resource potential in upper Yangtze region[J].China Petroleum Exploration,2009,14(3):10-15.[陈波,兰正凯.上扬子地区下寒武统页岩气资源潜力[J].中国石油勘探,2009,14(3):10-15.][14]Yang Zhenheng,Tenger,Li Zhiming.An example of shale gas selected marine area model of lower Cambrian on the middle and upper Yanggtze[J].Natural Gas Geoscience,2011,22(1):8-14.[杨振恒,腾格尔,李志明.页岩气勘探选区模型——以中上扬子下寒武统海相地层页岩气勘探评价为例[J].天然气地球科学,2011,22(1):8-14.][15]Huang Wenming,Liu Shugen,Wang Guozhi,et al .Geological conditions and gas reservior features in lower Paleozoic in Sichuan basin[J].Natural Gas Geoscience,2011,22(3):465-476.[黄文明,刘树根,王国芝,等.四川盆地下古生界油气地质条件及气藏特征[J].天然气地球科学,2011,22(3):465-476.][16]Wang Pengwan,Chen Ziliao,He Xunyun,et al .Accumulation of lower Cambrian Niutitang shale gas and prediction of potential area in Qiannan sag[J].Natural Gas Geoscience,2011,22(3):518-524.[王鹏万,陈子炓,贺训云,等.黔南坳陷下寒武统页岩气成藏条件与有利区带评价[J].天然气地球科学,2011,22(3):518-524.][17]Tang Shirong,Wang Dongan,Li Renwei.Organic petrology of the Cambrian-Sinian chert from the Xiangchuan region[J].Acta Sedimentologica Sinica,1997,15(1):55-60.[唐世荣,王东安,李任伟.湘川地区震旦—寒武系硅岩的有机岩石学研究[J].沉积学报,1997,15(1):55-60.][18]Zhao Ling.Restitution of organic matter type in marine-facing oil source rock in Guizhou-Yunnan-Guangxi area[J].Guizhou Geology,2000,17(2):86-91.[赵陵.滇黔桂地区海相生油岩有机质类型的恢复[J].贵州地质,2000,17(2):86-91.][19]Zhang Miao,Chen Qinghua,Liu Feng,et al .Application of palynofacies to the study of the Paleozoic source rocks in lower Yangtze region[J].Marine Geology and Quaternary Geology,2011,31(3):87-92.[张淼,陈清华,刘峰,等,孢粉相在下扬子古生界烃源岩研究中的应用[J].海洋地质与第四纪地质,2011,31(3):87-92.][20 Liu Guangxiang.Characteristics of middle Paleozoic marine source rock in the northern margin of middle and upper Yangtze region[J].Experimental Petroleum Geology,2005,27(5):490-495.[刘光祥.中上扬子北缘中古生界海相烃源岩特征[J].石油实验地质,2005,27(5):490-495.][21]Dai Hongming,Huang Dong,Liu Xuning,et al .Characteristics and evaluation of marine source rock in southwestern Shunan[J].Natural Gas Geoscience,2008,19(4):503-508.[戴鸿鸣,黄东,刘旭宁,等.蜀南西南地区海相烃源岩特征与评价[J].天然气地球科学,2008,19(4):503-508.][22]Tao Shu,Tang Dazhen,Wu Damao,et al .Organic petrology characteristics of lower assemblage source rocks in upper and middle Yangtze region[J].Journal of China University of Mining and Technology,2010,39(4):575-581.[陶树,汤达祯,伍大茂,等.中、上扬子区下组合烃源岩有机岩石学特征[J].中国矿业大学学报,2010,39(4):575-581.][23]Hu Mingxia,Cao Yin.Classification and application of organic macerals in the lower Paleozoic hydrocarbon source rock[J].Experimental Petroleum Geology,2007,29(4):432-435.[胡明霞,曹寅.下古生界烃源岩有机显微组分分类与应用[J].石油实验地质,2007,29(4):432-435.][24]Liu Wenjun,Lu Jialan.Characteristics of organic geochemistry of lower Cambrian in western Hunan organic-mineralization study on MVT lead-Zinc ore deposits(Ⅲ)[J].Acta Sedimentologica Sinica,2000,18(2):290-296.[刘文均,卢家烂.湘西下寒武统有机地化特征—MVT铅锌矿床有机成矿作用研究(Ⅲ)[J].沉积学报,2000,18(2):290-296.][25]Mao J W,Lehmann B,Du A D,et al .Re-Os dating of polymetallic Ni-Mo-PGE-Au mineralization in lower Cambrian black shales of south China and its geologic significance[J].Economic Geology,2002,97:1051-1061.[26]Tan Junying,Wang Wenlong,Wang Yanbin,et al .Marine source rock assessment for lower Cambrian Niutitang Formation in middle and upper Yangtze region[J].Marine Geology Frontiers,2011,27(3):23-27.[坛俊颖,王文龙,王延斌,等.中上扬子下寒武统牛蹄塘组海相烃源岩评价[J].海洋地质前沿,2011,27(3):23-27.][27]Chen Lan.Sedimentology and Geochemistry of the Early Cambrian Black Rock Series in the Hunan-Guizhou Area,China[D].Beijing:Institute of Geochemistry,Chinese Academy of Sciences,2006:27-29.[陈兰.湘黔地区早寒武世黑色岩系沉积学及地球化学研究[D].北京:中国科学院研究生院,地球化学研究所,2006:27-29.][28]Fan Delian,Liu Tiebing,Ye Jie.Biogeochemistry of black shale series during diagenetic and metallogenetic processes[J].Acta Petrological Sinica,1991,(2):65-72.[范德廉,刘铁兵,叶杰.黑色岩系成岩成矿过程中的生物地球化学作用[J].岩石学报,1991,(2):65-72.][29]Zhou Jie,Hu Kai,Mao Jianren.Metallogenic characteristics and genesis of the Huangjiawan Ni-Mo polymetallic deposit in Zunyi area[J].Contributions to Geology and Mineral Resources Research,2009,24(2):111-116.[周洁,胡凯,毛建仁.遵义黄家湾镍钼多金属矿成矿特征与成因[J].地质找矿论丛,2009,24(2):111-116.][30]Zhou Jie,Hu Kai,Bian Lizeng.Biogenetic mineralization of Ni-Mo polymetallic ores in lower Cambrian black shales,Zunyi,Guizhou province[J].Resources Survey and Environment,2009,30(2):96-101.[周洁,胡凯,边立曾.遵义下寒武统黑色岩系Ni-Mo多金属矿的生物成矿作用[J].资源调查与环境,2009,30(2):96-101.][31]Bian Lizeng,Zhang Yongchang,Zhang Baomin.Red algal fossils discovered from the Neoproterozoic Xiamaling oil shales,Xiahuayuan town of Hebei province[J].Acta Micropalaeontologica Sinica,2005,22(3):209-216.[边立曾,张永昌,张宝民.河北张家口下花园地区新元古代下马岭组油页岩中的红藻化石[J].微体古生物学报,2005,22(3):209-216.][32]Yang Xinglian,Zhao Yuanlong,Zhu Maoyan,et al .Sponges from the early Cambrian Niutitang Formation at Danzhai,Guizhou and their environmental background[J].Acta Palaeontologica Sinica,2010,49(3):348-359.[杨兴莲,赵元龙,朱茂炎,等.贵州丹寨寒武系牛蹄塘组海绵动物化石及其环境背景[J].古生物学报,2010,49(3):348-359.][33]Liu Dameng,Jin Kuili,Ai Tianjie.A petrographic classification and organic petrological characteristics of macerals of the marine hydrocarbon source rocks in the Tarim basin[J].Acta Sedimentologica Sinica,1995,13(A1):124-133.[刘大锰,金奎励,艾天杰.塔里木盆地海相烃源岩显微组分的分类及其岩石学特征[J].沉积学报,1995,13(A1):124-133.][34]Tang Yuegang,Jiang Peng,Hou Huimin,et al .Correlation of bituminite and mineral-bituminous groundmass with sedimentary organic groundmass[J].Journal of China University of Mining & Technology,1999,28(1):33-36.[唐跃刚,姜鹏,侯慧敏,等.沥青质体和矿物沥青基质与沉积有机基质关系[J].中国矿业大学学报,1999,28(1):33-36.][35]Wang Tieguan,Zhong Ningning,Hou Dujie,et al .The role bacteria plays in hydrocarbon generation mechanism in Banqiao sag[J].Science in China:Series B,1995,25(8):882-889.[王铁冠,钟宁宁,侯读杰,等.细菌在板桥凹陷生烃机制中的作用[J].中国科学:B辑,1995,25(8):882-889.][36]Zhang Qu,Tenger,Zhang Zhirong,et al .Oil source of oil seepage and solid bitumen in the Kaili-Majiang area[J].Acta Geologica Sinica,2007,81(8):1118-1124.[张渠,腾格尔,张志荣,等.凯里—麻江地区油苗与固体沥青的油源分析[J].地质学报,2007,81(8):1118-1124.][37]Qin Jianzhong,Fu Xiaodong,Liu Xiaozeng.Solid bitumens in the marine carbonate reservoir of gas field in the northeast area of the Sichuan basin[J].Acta Geologica Sinica,2007,81(8):1065-1071.[秦建中,付小东,刘效曾.四川盆地东北部气田海相碳酸盐岩储层固体沥青研究[J].地质学报,2007,81(8):1065-1071.][38]Jin Juchang,Qin Jianzhong,Zhang Zhirong,et al .Genetic analysis of the high maturated bitumen in Songpan-Aba area[J].Experimental Petroleum Geology,2004,26(4):370-374.[金聚畅,秦建中,张志荣,等.松潘阿坝地区高演化沥青的成因分析[J].石油实验地质,2004,26(4):370-374.][39]Wang Yongquan,Xiong Yongqiang,Li Yun.Investigation of the solid bitumen by chemical degradation method[J].Experimental Petroleum Geology,2007,29(6):609-611.[王涌泉,熊永强,李芸.应用化学降解方法研究固体沥青——以川东北固体沥青为例[J].石油实验地质,2007,29(6):609-611.][40]Wang Yongquan,Xiong Yongqiang,Wang Yanmei.Organic geochemical of solid bitumen from the northeastern Sichuan basin[J].Journal of Jilin University:Earth Science Edition,2008,38(1):76-80.[王涌泉,熊永强,王彦美.川东北固体沥青的有机地球化学[J].吉林大学学报:地球科学版,2008,38(1):76-80.][41]Tissot B P,Welte D H.Petroleum Formation and Occurrence[M].2nd ed.Berlin:Springer-Verlag,1978:1-699.[42]Li Xianqing,Xiong Bo,Ma Anlai,et al .Advancement of organic petrology in oil and gas exploration[J].Journal of Jianghan Petroleum Institute,2002,24(1):15-19.[李贤庆,熊波,马安来,等.有机岩石学在油气勘探评价中的应用进展[J].江汉石油学院学报,2002,24(1):15-19.][43]Li Xianqing,Hu Guoyi,Zhang Aiyun,et al .The sources of lower Paleozoic natural gases in central gas field in Erdos[J].Geoscience,2002,16(2):191-198.[李贤庆,胡国艺,张爱云,等.鄂尔多斯中部气田下古生界天然气的气源研究[J].现代地质,2002,16(2):191-198.][44]Jin Kuili,Liu Dameng,Yao Suping,et al .Genetic classification of organic components of hydrocarbon source rocks in China and its geological features[J].Acta Sedimentologica Sinica,1997,15(2):160-163.[金奎励,刘大锰,姚素平,等.中国油、气源岩有机成分成因划分及地化特征[J].沉积学报,1997,15(2):160-163.][45]Qin Shengfei,Zhong Ningning,Qin Yong,et al .Classification of organic maceral in carbonates[J].Experimental Petroleum Geology,1996,18(3):325-330.[秦胜飞,钟宁宁,秦勇,等.碳酸盐老有机显微组分分类[J].石油实验地质,1996,18(3):325-330.][46]Li Jianguo,David J Batten.Palynofacies:Principles and methods[J].Acta Palaeontologica Sinica,2005,44(1):138-156.[李建国,David J Batten.孢粉相:原理及方法[J].古生物学报,2005,44(1):138-156.][47]He Jinxian,Duan Yi,Zhang Xiaoli,et al .Hydrocarbon generation conditions of the shale in Niutitang Formation of lower Cambrian,southern Chongqing and northern Guizhou[J].Marine Geology Frontiers,2011,27(7):34-40.[何金先,段毅,张晓丽,等.渝南—黔北地区下寒武统牛蹄塘组页岩气成藏的生烃条件[J].海洋地质前沿,2011,27(7):34-40.][48]Li Yanxia,Lin Juanhua,Long Youkang,et al .Exploration prospect of gas-bearing marine mudstone-shale in lower Palaeozoic in the central Yangtze area,China[J].Geological Bulletin of China,2011,31(2):349-356.[李艳霞,林娟华,龙幼康,等.中扬子地区下古生界海相泥—页岩含气勘探远景[J].地质通报,2011,31(2):349-356.][49]Yang Yongjun.The Evaluate of the Source Rocks of Cambrian Niutitang Formation in Songlin,Zunyi Area of Guizhou Province[D].Sichuan:Chengdu University of Technology,2010:49-51.[杨永军.贵州遵义松林地区寒武系牛蹄塘组下部烃源岩评价[D].四川:成都理工大学,2010:49-51.][50]Li Yanjun,Chen Yicai,Yang Yuancong,et al .Source rock evaluation and characteristics of hydrocarbon generation from lower Paleozoic carbonate in Ordos basin[J].Oil and Gas Geology,1999,20(4):349-353.[李延钧,陈义才,杨远聪,等.鄂尔多斯下古生界碳酸盐烃源岩评价与成烃特征[J].石油与天然气地质,1999,20(4):349-353.][51]Zhou Xinke,Xu Huazheng.Features of organic matter and formation environment of marine carbonate rocks[J].Oil and Gas Geology,2009,30(3):337-342.[周新科,许化政.海相碳酸盐岩的形成环境与有机质特征[J].石油与天然气地质,2009,30(3):337-342.][52]Zeng Yantao,Wen Zhigang,Yang Liguo.Discussion on the dual property of organic matter type in marine source rock:A case of Shallowing platform carbonate rock in Nanling-Wuwei area,Anhui[J].Marine Origin Petroleum Geology,2009,14(3):73-78.[曾艳涛,文志刚,杨立国,海相烃源岩有机质类型的“双最属性”初探——以安徽南陵—无为地区浅水台地相碳酸盐岩为例[J].海相油气地质,2009,14(3):73-78.][53]Yao Suping,Hu Wenxuan,Jiao Kun.The geochemical model of petroleum,natural gas and coal multi-resource system[J].Geological Journal of China Universities,2011,17(2):196-205.[姚素平,胡文瑄,焦堃.煤、油、气共存富集的地球化学判识模式[J].高校地质学报,2011,17(2):196-205.][54]Qin Jianzhong,Shen Baojian,Fu Xiaodong,et al .Ultra microscopic organic petrology and potential of hydrocarbon generation and expulsion of quality marine source rocks in south China[J].Oil and Gas Geology,2010,31(6):826-837.[秦建中,申宝剑,付小东,等.中国南方海相优质烃源岩超显微有机岩石学与生排烃潜力[J].石油与天然气地质,2010,31(6):826-837.][55]Wang Feiyu,Bian Lizeng,Zhang Shuichang,et al .Two hydrocarbon generation materials in Ordovician marine hydrocarbon source rocks in Tarim basin(abstract)[J].Marine Origin Petroleum Geology,2000,5(2):144.[王飞宇,边立曾,张水昌,等.塔里木盆地奥陶系海相烃源岩中两类生烃母质(摘要)[J].海相油气地质,2000,5(2):144.][56]Zhao Jingzhou.Conception,classification and resource potential of unconventional hy-drocarbons[J].Natural Gas Geoscience,2012,23(3):393-406.[赵靖舟.非常规油气有关概念、分类及资源潜力[J].天然气地球科学,2012,23(3):393-406.
[57]Liu Shaopeng,Zhou Shixin,Wang Baozhong,et al .Relationship between industrial indexes and sourcerock evaluation parameters of oilshale[J].Natural Gas Geoscience,2012,23(3):561-569.[柳少鹏,周世新,王保忠,等.烃源岩评价参数与油页岩品质指标内在关系探讨[J].天然气地球科学,2012,23(3):561-569.][58]Yang Ruidong,Chen Wei,Zhou Ruxian.Characteristics of organic-rich shale and exploration area of shale gas in Guizhou province[J].Natural Gas Geoscience,2012,23(2):340-347.[杨瑞东,程伟,周汝贤.贵州页岩气源岩特征及页岩气勘探远景分析[J].天然气地球科学,2012,23(2):340-347.\] |
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