天然气地球科学
高级检索
作者投稿 专家审稿 编辑办公

天然气地球科学 ›› 2006, Vol. 17 ›› Issue (1): 14–18.doi: 10.11764/j.issn.1672-1926.2006.01.14

• 非生物（无机）气 • 上一篇    下一篇

深层及非生物成烃的催化机制

吕功煊1,丑凌军1,张兵1,王先彬2   

  1. (1.中国科学院兰州化学物理研究所，甘肃 兰州 730000；2.中国科学院地质与地球物 理研究所兰州油气研究中心，甘肃 兰州 730000)
  • 收稿日期:2005-12-22 修回日期:2006-01-03 出版日期:2006-02-20 发布日期:2006-02-20
  • 作者简介:吕功煊(1964-)，男，四川长宁人，研究员，博导，长期从事多相催化、环境与能源催化研究.

FORMATION MECHANISM OF ABIOGENIC OF HYDROCARBONS AND ORGANICS GENERATION IN DEEP STRATA

Lü Gong-xuan1,CHOU Lin-jun1, ZHANG Bing1,WANG Xian-bin2   

  1. (1.Lanzhou Institute of Chemic al Physics, CAS, Lanzhou 730000, China;2.Institute of Geology and Geophysics,  CAS, Lanzhou 730000, China)
  • Received:2005-12-22 Revised:2006-01-03 Online:2006-02-20 Published:2006-02-20
  • Contact: 吕功煊gxlu@lzb.ac.cn. E-mail:gxlu@lzb.ac.cn.

PDF (PC)

690

摘要：

讨论了非生物成因烃的可能生成机制。通过对比分析,探讨了在地质条件下碳、氢经历费-托合成和由过渡金属催化产生烃的可能机制。

关键词: 非生物成烃, 费-托合成, 催化

Abstract:

The possible mechanism of abiogenic hydrocarbon formation and organics generation in deep strata via F-T synthesis and catalytic reactions over metals from carbon,hydrogen and methane was discussed in this paper.

Key words: Abiogenic hydrocarbon formation, F-T synthesis, Catalysis.

中图分类号: 

  • TE122.1

[1]GOLD T. Terrestrial sources of carbon and earthquake outgassing[J]. J Petrol Geol, 1979,(1):1-19.
[2]GOLD T, SOTER S. The deep-earth gas hypothesis[J]. Scienti fic Am, 1980,242(6):154-161.
[3] MACDONALD G J. The many origins of natural gas[J].JPG, 1983,5:341 -362.
[4] WANG X B. The natural gas from deep earth[J]. Chinese Sci Bull ,1983,28(11):1515-1518.
[5] KROPOTKIN P N. Degassing of the earth and the origin of hydrocarbon s[J]. International Geol Rev,1985, 27:1261-1275.
[6]JENDEN P D, HILTTON D R, KAPLAN I R, et al. Abiogenic hyd rocarbons and mantle helium in oil and gas fields[C]//HOWELL D G. The future o f energy gases. US Geological Survey Professional Paper 1570,1993:31-56.
[7] GUO Z Q, WANG X B. Discussion on abiogenic natural gas in Songliao  Basin[J]. Sci China: Serial B,1993, 24(3):303-309.
[8] WANG X B. On abiogenic natural gas[J].Chinese Sci Bull, 1997,4 2:1327-1337.
[9] WANG X B. Mantle-derived methane homologue, carbon di-  [KG*7 /8]oxide and helium in natural gas from Songliao Basin[J]. China Magazine, 199 8,62:1665-1666.
[10]HORITA J, BERNDT M E. Abiogenic methane formation and isotopic fra ctionation under hydrothermal conditions[J]. Science,1999, 285:1055-1057.
[11] SHERWOOD LOLLAR B, WESTGATE T D, WARD J A, et al. Lampe-couloume, A biogenic formation of alkanes in the Earth's crust as a minor source for global  hydrocarbon reservoirs[J]. Nature, 2002,416:522-435.
[12] ABRJANO T A, STURCHIO N C, KENNEDY B M, et al.Geochemistry of reduce d gas related to serpentinization of the Zambales ophiolite, Philippines[J]. A ppl Geochem, 1990,5:625-630.
[13] SHERWOOD LOLLAR B, FRAPE S K, WEISE S M, et al. Abiogenic methano genesis in crystalline rocks[J]. Geochem Cosmochem Acta, 1993,57:5087-5097. [14] MCCARTY H B, FELBECK G T JR.High temperture simu-   lation of pet roluem formation-Ⅳ. Stable carbon isotope stud-  ies of gaseous h ydrocarbons[J]. Orgainc Geochemistry, 1986,9:183-192.
[15]JAMES A T. Correlation of natural gas by use of carbon isotopic di stribution between hydrocarbon components[J]. Am Assoc Petrol Geol Bull,1983,  67:1176-1191. [16] SCHOELL M. Genetic characterization of natural gases[J]. Am Asso c Petrol Geol Bull, 1983,67:2225-2238.
[17] PERNATON E, PRINZHOFER A, SCHNEIDER F. Reconsideration of meth ane isotope signature as a criterion for the genesis of natural gas. Revue Inst[J]. Francais Petrole,1996, 51:635-651.
[18]CHUNG H M, GORMLY J R, SQUIRES R M. Origin of gases hydrocarbons i n subsurface environments: theoretical considerations of carbon isotope distribu tion[J]. Chemical Geology, 1988,71:97-103.
[19] DES MARAIS D J, DONCHIN J H, NEHRING N L, et al.Molecular carbon is otopic evidence for the origin of geothermal hydrcarbons[J].Nature, 1981,292:8 26-828.
[20]YUEN G U. Carbon isotope fractionation in Fischer-tropsch type re actions. Lunar Planet[J]. Sci Conf XXI, 1990.1367-1368.
[21] HU G, OUYANG Z, WANG X, et al. Carbon isotopic fractionati on in the process of Fischer-tropsch reaction in primitive solar nebu la[J]. Sci China,1998,41:202-207.
[22] YUEN G, BLARI N, DESMARAIS D J, et al. Carbon isotope comp osition of low molecular weight hydrocarbons and monocarboxylic acids from Murch ison meteorite[J]. Nature,1984,307:252-254.
[23] LANCET H S, ANDERS E. Carbon isotope fractionation in the Fischer-trops ch synthesis of methane[J].Science,1970,170:980-982.
[24] JENDEN P D, DRAZAN D J, KAPLAN I R. Mixing of thermogeni natural gases i n Northern Appalachian Basin[J]. AAPG Bull,1993b,77:980-998.
[25] FUEX A N. The use of stable carbon isotopes in hydrocarbon exploration[J]. J Geochemcial Exploration,1977,7:155-188.
[26]PRINZHOFER A A, HUC A Y. Genetic and post-genetic molecular and i sotopic fractionations in natural gases[J]. Chem Geol,1995,126:281-290. [27] LAUGHREY C D, BALASSARE F J. Geochemistry and origin of some natural ga ses in the Plateau Province, Central Appalachian Basin, Pennsylvania and Ohio[J ]. AAPG Bull,1998,82:317-335.
[28] HUANG H, YANG J, YANG Y, et al. Geochemistry of natural gases in de ep strata of the Songliao Basin, NE China[J].Int J Coal Geol,2004,58:231-244.
[29] DIA J, XIA X, QIN S, et al. Origins of partially reversed alkane & #948;13C values for biogenic gases in China[J]. Org Geochem,2004,35: 405-411.
[30] SABATIER P, SENDERENS J B, ACAD C R. Sci, 1902,134:514.
[31] FISCHER F, TROPSCH H. Brennst Chem, 1923, 4:276.
[32]DRY M E, HOOGENDOORN J C. Catal Rev Sci Eng, 1981, 23:265.
[33]Special Report[R]. Europ Chem News Technol Suppl, 1980, 22:19.
[34] 方学平，李树本.甲烷在W-Mn体系催化剂上氧化偶联制乙烯[J].分子催化，1992 ，6:427.
[35] 翁维正，龙瑞强，陈明树，等.甲烷氧化偶联催化剂和部分氧化反应机理的原位及非原位谱学表征[J].厦门大学学报：自然科学版，2001，40(2)：349.
[36] 陶士振，刘德良，杨晓勇，等.无机成因天然气形成条件分析[J].天然气地球科 学，2000，11(1)：10-18.
[37] 丑凌军，李树本.加压下甲烷氧化偶联反应工艺条件的研究[J].天然气化工：C1 化学与化工，2002，5：1-3.
[1] 马向贤,郑建京,郑国东. 含铁矿物对褐煤生烃演化的催化作用[J]. 天然气地球科学, 2014, 25(7): 1065-1071.
[2] 程斌，王铁冠，常象春. C5—C7轻烃在原油地球化学研究中的应用——以塔北隆起哈拉哈塘凹陷奥陶系原油为例[J]. 天然气地球科学, 2013, 24(2): 398-405.
[3] 吴艳艳,秦勇,刘金钟,王爱宽. 矿物/金属元素在煤成烃过程中的作用——以黔西滇东上二叠统大河边煤矿煤样为例[J]. 天然气地球科学, 2012, 23(1): 141-152.
[4] 高岗, 柳广弟, 黄志龙, 闵忠顺. 兴隆台油气田天然气成因与成藏特殊性分析[J]. 天然气地球科学, 2010, 21(6): 955-960.
[5] 梁婉如,张敏,赵红静. 吐哈盆地原油轻烃地球化学特征[J]. 天然气地球科学, 2009, 20(5): 763-767.
[6] 唐友军, 文志刚. 苏丹裂谷盆地原油轻烃地球化学特征[J]. 天然气地球科学, 2007, 18(5): 756-759.
[7] 杜宏宇;王志勇;金颖;杨爱生;任忠跃;贺永红;. 三塘湖盆地天然气成因及成藏分析[J]. 天然气地球科学, 2006, 17(4): 582-585.
[8] 魏舲钧;. 亚铁离子对碳酸盐岩有机质成烃演化的催化作用模拟实验研究[J]. 天然气地球科学, 2005, 16(3): 306-309.
[9] 宁占武;王卫华;温美娟;李　剑;. 过渡金属对有机质热解生烃过程的影响[J]. 天然气地球科学, 2004, 15(3): 317-319.
[10] 马安来;张水昌;张大江;. 轮南和塔河油田稠油沥青质钌离子催化氧化研究[J]. 天然气地球科学, 2004, 15(2): 144-149.
[11] 徐永昌;. 天然气地球化学研究及有关问题探讨[J]. 天然气地球科学, 1999, 10(3-4): 20-28.
[12] 李术元; 刘洛夫;. 烃源岩催化生烃机制的研究进展[J]. 天然气地球科学, 1996, 7(5): 1-6.
[13] 妥进才; 王随继. 油气形成过程中的催化反应[J]. 天然气地球科学, 1995, 6(2): 37-42.
[14] 刘晓艳. 粘土矿物对有机质演化的影响[J]. 天然气地球科学, 1995, 6(1): 23-26.
[15] 雷怀彦； . 粘土矿物对形成过渡带气作用的研究[J]. 天然气地球科学, 1993, 4(6): 69-79.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!