Wu Yuan-dong, Zhang Zhong-ning, Ji Li-ming, Sun Li-na, He Cong, Su Long, Xia Yan-qing
In order to investigate the process of thermal evolution and hydrocarbons generation of organic matter.Mudstone source rock from drilling was pyrolyzed in simulation with con-pressure and hetero-pressure experiments in semi-open system high pressure instrument.In con-pressure experiments,peak of bitumen,oil,gaseous hydrocarbon yields appeared at 350℃,520℃ and 520℃ respectively,and yields were,in order,6.17mg/g,12.07mg/g and 4.14mL/g.The corresponding RO of residues were 0.9%,3.0% and 3.0%.Times of expelling hydrocarbon were,in order 4,21 and 21.In hetero-pressure experiments,peak of bitumen,oil,gaseous hydrocarbon yields appeared at 350℃,500℃ and 520℃ respectively,and yields were,in order,12.56mg/g,24.87mg/g and 2.59mL/g.The corresponding RO of residues were 1.1%,3.1% and 3.1%.Times of expelling hydrocarbon were,in order 5,43 and 44.Results demonstrate that the times of expelling hydrocarbon were controlled by temperature and threshold of expulsion hydrocarbon pressure.Increasing simulation temperature might enhance hydrocarbon generation intensity,and causing the pressure in the reactor reached the upper limit of the threshold of expulsion hydrocarbon pressure constantly under the same threshold of expulsion hydrocarbon pressure condition,times of expelling hydrocarbon were enhanced at last.And it might promote source rocks yielding liquid hydrocarbons.Increasing the fluids pressure might enhance ource rocks yielding bitumen and oil,increasing the yield of liquid hydrocarbons.At the same time,increasing fluid pressure might reduce the yield of gaseous hydrocarbons,causing the negative influence of gaseous hydrocarbons generation.The influence of fluids pressure to RO is different in different temperature,400-500℃,enlarging RO of organic matter with increasing fluid pressure may be more obvious.