Linzhi LI, Yunyan NI, Limiao YAO, Fei WANG, Jianli SUI, Jinchuan ZHANG, Yuan WANG, Guoliang DONG, Li WANG, Tong ZHAO, Jianping CHEN, Dazhong DONG
In recent years, China has carried out fruitful exploration and development of medium and shallow shale gas with a burial depth of 700-2 000 m in Zhaotong Shale Gas Demonstration Zone of Sichuan Basin. However, horizontal well technology and large-scale hydraulic fracturing technology adopted in shale gas development have the risk of water environment pollution, especially in the carbonate rock distribution area in southern China, which has complex geological conditions and fragile ecological environment. The study of water environmental pollution risk is particularly important. In this study, the composition of trace elements, anions, cations, and strontium isotopes in the flowback water of Y105 well area with vertical depth <2 500 m in the Taiyang block, Zhaotong area, Sichuan Basin was analyzed and compared with that of Weiyuan, Changning and Fuling shale gas fields. It is pointed out that shale gas fracturing flowback water in Y105 well area of Taiyang shallow layer has the following three characteristics: (1) The flowback water is high in salts and heavy metals. The average contents of K, Na, Ca and Mg were 153 mg/L,7 473 mg/L,162 mg/L, 34 mg/L, respectively, and the average contents of Cl and Br were 10 912 mg/L and 52 mg/L, respectively. The average contents of Li, B, Sr, Ba and Rb were 21.9 mg/L, 14.3 mg/L, 27.8 mg/L, 37.4 mg/L and 0.25 mg/L respectively, which could not be directly discharged. The average Br/Cl ratio is 0.002 1, it is relatively rich in Ca and poor in Mg compared with evaporative seawater, the content of Sr, Ba and Rb is positively correlated with the content of Cl. All of them indicate that the flowback water is the mixture product of the fracturing injected fluid and entrapped brine of the host shale formation. The high salt end of the flowback water has the characteristics of evaporative seawater, but it also experiences water-rock reaction. (2) The 87Sr/86Sr ratio ranges from 0.716 5 to 0.717 2 (with an average value of 0.716 7), indicating that there is a strong water-rock interaction between fracturing injected fluid and shale formations with high strontium isotope ratios. Compared with the flowback water in Weiyuan, Changning and Fuling shale gas fields, flowback water in the Taiyang block has relatively low 87Sr/86Sr ratios, but still much higher than that of surface water and biocides, which is a good identification index. (3) The element composition of the flowback water has a certain correlation with the vertical burial depth of the shale. For example, when the vertical depth of the Y105H3 platform increases from 2 245.16 m to 2 406.16 m, the content of cations, ions, and trace elements has varying degrees of change, and shows a certain change law, which may reflect the influence of temperature, pressure and other factors.