Effect of Particle Size of Ice on Methane Hydrate Self-Preservation below Freezing Point
Online published: 2008-04-20
To study the impacts of the ice particle size on the self preservation of methane hydrate, the dissociation experiment of methane hydrates were carried out. It contains six different sizes of ice particles under two different temperatures, aiming at analyzing the impacts of the total release volume of methane and the dissociation rate on the self preservation time. The results show that the size of the ice particle had evident impacts on the dissociation of methane hydrates. The total release volume of methane and the dissociation rate were inversely proportional to the ice particle size, the smaller the ice particle size, the faster the dissociation rate. This feature was very remarkable at the beginning of the dissociation. And, the methane hydrate formed by the bigger size of ice particle had more effective self\|preservation.
Key words: Methane hydrate; Self preservation; Dissociation; Particle size.
ZHAN Jing, TUN Jing-Bai, JIANG Guan-Li . Effect of Particle Size of Ice on Methane Hydrate Self-Preservation below Freezing Point[J]. Natural Gas Geoscience, 2008 , 19(4) : 577 -580 . DOI: 10.11764/j.issn.1672-1926.2008.04.577
[1]Sloan E D.Clathrate Hydrate of Natural Gases[M].2nd ed. New York:Marcel Dekker Inc,1998.
[2] Yakushev V S, Istomin V A. Gas-hydrate self-preservation effect
[M]//Maeno N, Hondoh T.Physics and Chemistry of Ice. Sapporo:Hokkaido University Press,1992:136-139.
[3]Handa Y,Stupin D.Thermodynamic properties and dissociation characteristics of methane and propane hydrates in 70--radius silica gel porest
[J].Phyical Chemistry,1992,96:8599-8603.
[4] Davidson D, Garg S, Gough S, Handa Y,et al. Laboratory analysis of a naturally occurring gas hydrate from sediment of the Gulf of Mexico
[J]. Geochim Cosmochim Acta, 1986, 50:619-623.
[5] Handa Y P. Compositions, enthalpies of dissociation, and heat capacities in the range 85 to 270 K for clathrate hydrates of methane, ethane, and propane, and enthalpy of dissociation of isobutane hydrate, as determined by a heat-flow calorimeter
[J]. Chemical Thermodynamics, 1986, 18: 915-921.
[6]Gudmundsson J S, Parlaktuna M, Levik O I, et al. Laboratory for Continuous Production of Natural Gas Hydrates
[C]. Annals of the New York Academy of Sciences,2000:912,851.
[7] Stern L A, Circone S, Kirby S H,et al. Anomalous preservation of pure methane hydrate at 1 atm
[J]. Journal of Physical Chemistry B, 2001, 105, 1756-1762. [8] Shirota H, Aya I, Namie S, et al. Measurement of methane hydrate dissociation for application to natural gas storage and transportation
[C]//Proceedings of the Fourth International Conference on Gas Hydrates, Yokohama, Japan, 2002:972-977.
[9]林微,陈光进.气体水合物分解动力学研究现状
[J].过程工程学报,2004,4(1):69-74.
[10] Peters D J. A Study of Hydrate Dissociation in Pipelines by the Method of Two-Sided Depressurization:Eperiment and Model
[D].Master of Science Thesis, Colorado School of Mines.1999.
/
〈 |
|
〉 |