SONG Qi, WANG Shu-Li, CHEN Yan, ZHENG Zhi, XIE Lei . A New Kinetic Model and Experiment for Natural Gas Hydrate[J]. Natural Gas Geoscience, 2010 , 21(5) : 868 -874 . DOI: 10.11764/j.issn.1672-1926.2010.05.868

［1］Fan S S.Natural Gas Hydrate Storage and Transportation Technology[M].Beijing:Chemical Industry Press,2005:116-153.［樊栓狮.天然气水合物储运与运输技术[M].北京:化学工业出版社,2005:116-153.］
［2］Sloan E D.Clathrate Hydrates of Natural Gases[M].New York:Marcel Dekker,1998.]
［3］Zhou J Q,Yin X,Li Q S,et al.Development and application of simulation experimental apparatus for gas hydrate[J].China Petroleum Machinery,2006,34(7):22-24.［周剑秋,尹侠,李庆生,等.海洋天然气水合物模拟设备的开发及应用[J].石油机械,2006,34(7):22-24.］
［4］Chen G J,Sun C Y,Ma Q L.Gas Hydrates Science and Technology[M].Beijing:Chemical Industry Press,2008:124-184.［陈光进,孙长宇,马庆兰.气体水合物科学与技术[M].北京:化学工业出版社,2008:124-184.］
［5］Kashchiev D,Firoozabadi A.Induction time in crystallization of gas hydrates[J].Journal of Crystal Growth,2003,250:499-515.
［6］Englezos P,Kalogerakis N,Dholabhai P D,et al.Kinetics of formation of methane and ethane gas hydrates[J].Chemical Engineering Science,1987,42(1):2647-2658.
［7］Englezos P,Bishnoi P R.Gibbs free energy analysis for the supersaturation limits of methane in liquid water and the hydrate-gas-liquid water phase behavior[J].Fluid Phase Equil,1988,42:129-140.
［8］Englezos P,Kalogerakis N,Dholabhai P D,et al.Kinetics of gas hydrate formation from mixtures of methane and ethane [J].Chemical Engineering Science,1987,42(1):2659-2666.［9］Sun C Y,Chen G J,Guo T M.The status of the kinetics of hydrate nucleation[J].Acta Petrolei Sinica,2001,22（4）:82-87.［孙长宇,陈光进,郭天民.水合物成核动力学研究现状[J].石油学报,2001,22（4）:82-87.］
［10］Yin D H,Ren L,Fan S S,et al.Improved dynamic model imitation calculations for natural gas hydrate formation[J].Journal of Dalian University of Technology,2004,44（4）:486-489.［殷德宏,任亮,樊栓狮,等.天然气水合物生成动力学模型模拟计算改进[J].大连理工大学学报,2004,44（4）:486-489.］
［11］Shen J D,Wang S J,Hao M L,et al.The kinetics model of hydrate formation in sediments[J].Natural Gas Geoscience,2004,15（4）:436-440.［沈建东,王胜杰,郝妙丽,等.沉积层水合物的生成动力学模型[J].天然气地球科学,2004,15（4）:436-440.］
［12］Hao M L,Wang S J,Shen J D,et al.Kinetic model of shrinking-bubble for gas hydrate formed from gas and water[J].Journal of Xi′an Jiaotong University,2004,38（7）:705-708.［郝妙莉,王胜杰,沈建东,等.水—气体系生成水合物的缩泡动力学模型[J].西安交通大学学报,2004,38（7）:705-708.
［13］Pan Y X,Liu D P,Huang W J,et al.The induction time and the affected factors in gas hydrate formation[J].Natural Gas Geoscience,2005,16（2）:255-260.［潘云仙,刘道平,黄文件,等.气体水合物形成的诱导时间及其影响因素[J].天然气地球科学,2005,16（2）:255-260.］
［14］Andery N S,Takeo H.Post-nucleation conversion of an air bubble to clathrate air-hydrate crystal in ice[J]. Journal of Crystal Growth,1998,193:197-218.
［15］Andrey N S,Vladimir Y L,Tomoko I.Kinetics of air-hydrate nucleation in polar ice sheets[J].Journal of Crystal Growth,2001,223:285-305.
［16］Duarte A R,Peters C,Zevenbergen J.Kinetics of Formation and Dissociation of SⅡ Hydrogen Clathrate Hydrates［C］. 6nd ICGH,Vancouver,BC,Canada,2008.
［17］Quasem A,Lee S,Lee J W.Kinetics of Gas Hydrate Growth［C］.6nd ICGH,Vancouver,BC,Canada,2008.
［18］Peng B Z,Dandekar A,Sun C Y,et al.Hydrate film growth on the surface of a gas bubble suspended in water[J]. Journal of Physical Chemistry,2007,111:12485-12493.
［19］Zhang Y,Li X S,Li G.Study on Formation Kinetics of Methane Hydrate Inporous Media［C］. 6nd ICGH,Vancouver,BC,Canada,2008.
［20］Murshed M,Falenty A,Kuhs W F.Kinetic Studies on Gas Hydrates Forming from Gas Mixtures of Mmethane and Ethane［C］.6nd ICGH,Vancouver,BC,Canada,2008.
［21］Ma Y H,Gou L T,He X X,et al.Study on the formation kinetics of thf hydrate above 0℃[J].Natural Gas Geoscience,2006,17（2）:244-248.［马应海,苟兰涛,何晓霞,等.四氢呋喃水合物零度以上生成动力学研究[J].天然气地球科学,2006,17（2）:244-248.］
［22］Talatori S,Fotland P,Barth T.Kinetics of Hydrate Formation in a Water-Oil-Gas System［C］.6nd ICGH,Vancouver,BC,Canada,2008.