Different Factors on the Thickness of Gas Hydrate Stability Zone
Received date: 2009-09-07
Revised date: 2009-12-14
Online published: 2010-06-10
Gas hydrate has important research significances in future energy, natural environment and disaster. The thickness of gas hydrate stability zone (GHSZ) shows the possible range of hydrate development and distribution. It is greatly related with geothermal gradient, sea bottom temperature and water depth. Based on hydrate phase equilibrium formula of Dickens and Quinby, we quantitatively calculated the thickness of GHSZ in different conditions of geothermal gradient, water depth and sea bottom temperature. When the two parameters in three parameters are assumed unchanged, the thickness of GHSZ decreases with the increase of geothermal gradient regularly, the thickness of GHSZ increase with water depth, and the thickness of GHSZ decrease with increasing of sea bottom temperature as a good liner relationship. If the temperature of the sea bottom is a constant, the thickness of GHSZ will increase gradually from the regions with the larger geothermal gradient and shallower water depth to the smaller geothermal gradient and deeper water depth. If the water depth is unchanged, the thickness of GHSZ will increase gradually from the region with the larger geothermal gradient and higher sea bottom temperature to the smaller geothermal gradient and lower temperature. In addition, we also discussed the differences among the three hydrate phase equilibrium formulas for calculating the thickness of GHSZ. The maximize result of GHSZ thickness was gotten by Dickens-Quinby′s phase equilibrium formula gets, and the smaller values was done by the two others.
XU Wei, QIU Nan-Sheng, SUN Chang-Yu, CHEN Guang-Jin . Different Factors on the Thickness of Gas Hydrate Stability Zone[J]. Natural Gas Geoscience, 2010 , 21(3) : 528 -534 . DOI: 10.11764/j.issn.1672-1926.2010.03.528
[1]Sloan E D,Koh C A.Overview and historical perspective[M]//Sloan E D,Koh C A.Clathrate Hydrates of Natural Gases.3rd Edition.Boca Raton,London:CRC Press,2007:1- 29.
[2]Udachin K A,Ripmeester J A.A complex clathrate hydrate structure showing bimodal guest hydration[J].Nature,1999,397:420-423.
[3] Matsumoto R,Uchida T,Waseda A,et al.Occurrence,structure and composition of natural gas hydrate recovered from the Blake Ridge,northwest Atlantic[R].Proceedings of Ocean Drill Program Science Results,2000,164:13-28.
[4]Kvenvolden K A,Lorenson T D.The global occurrence of natural gas hydrates[J].American Geophysical Union,2001,(124):3- 18.
[5] Fan Shuanshi,Liu Feng,Chen Duofu.The research of the origin mechanism of marine gas hydrate[J].Natural Gas Geoscience,2004,15(5):524- 530.[樊栓狮,刘锋,陈多福.海洋天然气水合物的形成机理探讨[J].天然气地球科学,2004,15(5):524- 530.][6]Kvenvolden K A.Gas hydrates geological perspective and global change[J].Reviews of Geophysics,1993,31(2):173- 187.
[7]Max M D,Johnsen H K,Dillon W P.Why gas hydrate ?[M]// Max M D,Johnsen H K,Dillon W P,ed.Economic Geology of Natural Gas Hydrate.Berlin:Springer,2006:17- 44.
[8] Paull C K,Normark W R,Ussler W,et al.Association among active seafloor deformation,mound formation,and gas hydrate growth and accumulation within the seafloor of the Santa Monica basin,offshore California[J].Marine Geology,2008,250(3/4):258-275.
[9] Sultan N,Cochonat P,Foucher J P,et al.Effect of gas hydrates melting on seafloor slope instability[J].Marine Geology,2004,213:379-401.
[10] Xu Wenshi,Yu Xinghe,Liu Nina,et al.The development perspective and environmental problems of nature gas hydrates[J].Natural Gas Geoscience,2005,16(5):680- 683.[ 徐文世,于兴河,刘妮娜,等.天然气水合物开发前景和环境问题[J].天然气地球科学,2005,16(5):680- 683.]
[11]Wang Hongbin,Liang Jin,Gong Yuehua,et al.Estimation of the heat flow in the northern of the South China Sea based on the seismic data of gas hydrate[J].Geoscience,2005,19(1):67- 73.[王宏斌,梁劲,龚跃华,等.基于天然气水合物地震数据计算南海北部陆坡海底热流[J].现代地质,2005,19(1):67- 73.]
[12] Xu W,Ruppel C.Predicting the occurrence,distribution,and evolution of methane gas hydrate in porous marine sediments[J].Geophysical Research,1999,104(B3):5081- 5095.
[13] Dickens G R,Quinby H M S.Methane hydrate stability in seawater[J].Geophysical Research Letters,1994,21(19):2115- 2118.
[14] Dillon W P,Max M D.Oceanic gas hydrate[M]//Max M D.Natural Gas Hydrate in Oceanic and Permafrost Environments.Dordrecht:Kluwer Academic Publishers,2003:61- 63.
[15] Handa Y P.Effect of hydrostatic pressure and salinity on the stability of gas hydrates[J].Journal of Physical Chemistry,1990,94:2652- 2657.
[16] Dickens G R,Quinby H M S.Methane hydrate stability in pore water:A simple theoretical approach for geophysical applications[J].Journal of Geophysical Research- Solid Earth,1997,102(B1):773- 784.
[17] Zatsepina O Y,Buffett B A.Phase equilibrium of gas hydrate:Implications for the formation of hydrate in the deep sea floor[J].Geophysical Research Letters,1997,24(13):1567- 1570.
[18]Bishnoi P R,Dholabhai P D.Equilibrium conditions for hydrate formation for a ternary mixture of methane,propane and carbon dioxide,and a natural gas mixture in the presence of electrolytes and methanol[J].Fluid Phase Equilibria,1999,160:821- 827.
[19] Wang Shuhong,Song Haibin,Yan Wen.The change of external conditions effects on the phase equilibrium curve of gas hydrate and the thickness of hydrate stability zone[J].Progress in Geophysics,2005,20(3):761- 768.[王淑红,宋海斌,颜文.外界条件变化对天然气水合物相平衡曲线及稳定带厚度的影响[J].地球物理学进展,2005,20(3):761- 768.]
[20] Jin Chunshuang,Wang Jiyang,Zhang Guangxue.Factors affecting natural gas hydrate stability zone in the South China Sea[J].Mineral Deposits,2005,24(4):388- 397.[ 金春爽,汪集旸,张光学.南海天然气水合物稳定带的影响因素[J].矿床地质,2005,24(4):388- 397.]
[21]Brown K M,Bangs N L,Froelich P N,et al.The nature,distribution,and origin of gas hydrate in the Chile Triple Junction region[J].Earth and Planetary Science Letters,1996,139(3/4):471- 483.
[22] Peltzer E T,Brewer P G.Practical chemistry and empirical Predictions of methane hydrate stability[M]//Max M D.Natural Gas Hydrate in Ocean and Permafrost Environments.Dordrecht:Kluwer Academic Publishers,2003:17-28.
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