Natural Gas Geoscience ›› 2020, Vol. 31 ›› Issue (11): 1603-1614.doi: 10.11764/j.issn.1672-1926.2020.05.005

Previous Articles     Next Articles

Characteristics on pore structures on full scale of lignite and main controlling factors in Hailar Basin

Qing YANG1(),Jian LI1,Wen-guang TIAN1,Bin SUN1,Jie ZHU2,Yu-hang YANG2   

  1. 1.PetroChina Research Institute of Petroleum Exploration & Development,Beijing 100083,China
    2.China University of Mining & Technology(Beijing),Beijing 100083,China
  • Received:2020-03-03 Revised:2020-04-28 Online:2020-11-10 Published:2020-11-24

Abstract:

Pore structure characteristics of coal are one of the key factors for gas storage judgement of coal reservoir. The fine characterization of pore structure is of great significance for the identification of high-quality reservoir in thick coal seams. However,it is difficult for lignite reservoir to fully characterize the reservoir space characteristics by a single means. On the basis of scanning electron microscope (SEM), the full pore size structure of lignite samples of the Lower Cretaceous Yimin Formation in Hailaer Basin was characterized by using the complementary analysis of low-temperature liquid nitrogen adsorption experiment and high-pressure mercury injection experiment in pore size detection range and accuracy, and the influencing factors of pore structure of lignite were discussed. The results show: (1) The total pore volume and total pore area of coal samples in the study area are significantly different with the pore size distribution. The contribution of pore volume of coal samples from Yimin Formation is mainly from macropores; and adsorption area is mainly provided by micropores and transition pores. The main contribution of the pore volume of Yakeshi coal samples comes from the micropores and transition pores which contribute 99.73% of the total pore area. (2) The increasing increase of huminite is beneficial to the development of micropores and transit-pores. The increasing increase of inertinite content contributes to the development of mesopore and macropores. (3) The tissue preservation index and vegetation index of coal samples have a positive correlation with the total pore volume, and a negative correlation with the total pore area; the total pore volume decreases with the increase of gelification indices, and the change rule of the total surface area is opposite; the relationship between the groundwater influence and the total pore volume and the total pore area is not obvious. (4) The coal forming environment is dry forest swamp with an oxidation environment, forming a pore structure with abundant plant tissue pores, medium pores and macropores, and the pore morphology is mainly trough pores or slit pores. The coal forming environment with wide scales and deep of overlying water is characterized by high degree of gelatinization and decreasing primary tissue pores of coal seams. Mesopores and macropores are preferentially filled with minerals, contributing to the specific pore structure with lower pore volume and higher specific surface area.

Key words: Lignite coal, Pore characteristics, Pore volume, Specific surface area, Coal facie, Coal-forming environmentFoundation items: The National Science and Technology Major Project (Grant No. 2016ZX05041-004), The Major science and technology projects of Petrochina Co.Ltd.“Research and application of key technologies for coalbed methane exploration and development”(Grant No. 2017E?14)

CLC Number: 

  • TE121.1+3
1 赵力,杨曙光. 新疆煤层气产业发展现状及存在的问题[J].中国煤层气,2018,15(3):3-6.
ZHAO L,YANG S G. Development status and existing problems of Xinjiang’ s CBM industry[J]. Coal Geology of China,2018,15(3):3-6.
2 孙粉锦,李五忠,孙钦平,等. 二连盆地吉尔嘎朗图凹陷低煤阶煤层气勘探[J]. 石油学报, 2017, 38(5):485-492.
SUN F J,LI W J, SUN Q P,et al. Low-rank coalbed methane exploration in Jiergalangtu sag,Erlian Basin[J]. Acta Petrolei Sinica, 2017,38(5):485-492.
3 晋香兰,张培河,吴敏杰. 鄂尔多斯盆地低煤阶煤储层孔隙特征及地质意义[J],煤田地质与勘探,2012,40(10):22-26.
JIN X L,ZHANG P H,WU M J. Pore features and geological significance of low rank coal reservoirs in Ordos Basin[J]. Coal Geology & Exploration,2012,40(10):22-26.
4 秦勇,国外煤层气成因与储层物性研究进展与分析[J],地学前缘,2005,12(3):289-298.
QIN Y. Advances in overseas geological research on coalbed gas:Origin and reservoir characteristics of coalbed gas[J]. Earth Science Frontiers. 2005,12(3):289-298.
5 傅雪海,秦勇,薛秀谦,等. 煤储层孔、裂隙系统分形研究[J]. 中国矿业大学学报:自然科学版,2001,30(5):225-228.
FU X H, QIN Y, XUE X Q,al el. Research on fractals of pore and fracture-structure of coal reservoirs[J]. Journal of China University of Mining & Technology,2001,30(5):225-228.
6 田忠斌,魏书宏,王建青,等. 沁水盆地中东部海陆过渡相页岩微观孔隙结构特征[J]. 煤炭学报,2017,42(7):1818-1827.
TIAN Z B, WEI S H, WANG J Q,et al. Characteristics of micro-scale pore structures of marine-continental transitional shale from the mid-eastern area,Qinshui Basin[J]. Journal of China Coal Society, 2017,42(7):1818-1827.
7 陈贞龙,汤达祯,许浩,等.滇东黔西地区煤层气储层孔隙系统与可采性[J]. 煤炭学报,2010,35(8):158-163.
CHEN Z L, TANG D Z, XU H,et al. The pore system properties of coalbed methane reservoirs and recovery in western Guizhou and eastern Yunnan[J]. Journal of China Coal Society, 2010,35(8):158-163.
8 张慧,李小彦,郝琦,等.中国煤的扫描电子显微镜研究[M]. 北京:地质出版社,2003:64-72.
ZHANG H, LI X Y, HAO Q,et al. Study on Coal in China by Scan Electron Microscope[M]. Beijing:Geological Publishing house,2003:64-72.
9 姚艳斌,刘大锰. 基于核磁共振弛豫谱技术的页岩储层物性与流体特征研究[J]. 煤炭学报, 2018, 43(1):181-189.
YAO Y B,LIU D M. Petrophysical properties and fluids transportation in gas shale:A NMR relaxation spectrum analysis method[J]. Journal of China Coal Society, 2018,43(1):181-189.
10 卢双舫,李俊乾,张鹏飞, 等. 页岩油储集层微观孔喉分类与分级评价[J]. 石油勘探与开发, 2018,45(3): 436-444.
LU S F,LI J Q,ZHANG P F,et al. Classification of microscopic pore-throats and the grading evaluation on shale oil reservoirs[J]. Petroleum Exploration and Development,2018,45(3):436-444.
11 CLARKSON C R,SOLANO N,BUSTINR M, et al. Pore struture characterization of North American shale gas reservoirs using USANS / SANS, gas adsorption,and mercury intrusion[J]. Fuel,2013,103:606-616.
12 肖佃师,卢双舫,陆正元,等. 核磁共振和恒速压汞方法测定致密砂岩孔喉结构[J]. 石油勘探与开发,2016,43(6):962-970.
XIAO D S,LU S F,LU Z Y,et al. Combining nuclear magnetic resonance and rate-controlled porosimetry to probe the pore-throat structure of tight sandstone[J]. Petroleum Exploration and Development,2016,43(6):962-970.
13 张吉振,李贤庆,张学庆,等. 煤系页岩储层孔隙结构特征和演化[J]. 煤炭学报,2019,44(S1):195-204.
ZHANG J Z, LI X Q, ZHANG X Q, et al. Microscopic characteristics of pore structure and evolution in the coal-bearing shale[J]. Journal of China Coal Society, 2019, 44(S1): 195-204.
14 赵迪斐,郭英海,毛潇潇,等.基于压汞、氮气吸附与FE-SEM 的无烟煤微纳米孔特征[J].煤炭学报,2017,42(6):1517-1526.
ZHAO D F,GUO Y H,MAO X X,et al. Characteristics of macro-nanopores in anthracite coal based on mercury injection,nitrogen adsorption and FE-SEM[J]. Journal of China Coal Society,2017,42(6): 1517-1526.
15 李阳,张玉贵,张浪,等. 基于压汞、低温N2吸附和CO2吸附的构造煤孔隙结构表征[J]. 煤炭学报,2019,44 (4):1188-1196.
LI Y, ZHANG Y G, ZHANG L,et al. Characterization on pore structure of tectonic coals based on the method of mercury intrusion,carbon dioxide adsorption and nitrogen adsorption[J]. Journal of China Coal Society,2019,44(4):1188-1196.
16 郭彪,邵龙义,张强,等.内蒙古海拉尔盆地早白垩世含煤岩系层序地层与聚煤规律[J].古地理学报, 2014,5(10):632-640.
GUO B,SHAO L Y,ZHANG Q,et al. Sequence stratigraphy and coal accumulation pattern of the Early Cretaceous coal measures in Hailar Basin, Inner Mongolia[J]. Journal of Paleogeography. 2014,5(10):632-640.
17 孙斌,邵龙义,赵庆波,等. 海拉尔盆地煤层气成藏机理及勘探方向[J]. 天然气工业,2007, 27(7):12-15.
SUN B,SHAO L Y,ZHAO Q B,et al. Reservoiring mechanism of coalbed methane and exploration direction in Hailare Basin[J]. Nature Gas Industry,2007,27(7):12-15.
18 CHALMERS G R, BUSTIN R M,POWER I M. Characterization of gas shale pore systems by porosimetry, pycnometry, surface area, and field emission scanning electron microscopy/transmission electron microscopy image analyses: Examples from the Barnett, Woodford, Haynesville, Marcellus, and Doig unit[J]. AAPG Bulletin,2012,96(6):1099-1119.
19 SING K S W. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)[J]. Pure and Applied Chemistry,1985,57(4):603-619.
20 陈萍,唐修义. 低温液氮吸附法与煤中微孔隙特征的研究[J]. 煤炭学报,2001,26(5):552-556.
CHEN P,TANG X Y. The research on the adsorption of nitrogen in low temperature and micro-pore properties in coal[J]. Journal of China Coal Society,2001,26(5):552-556.
21 祝武权,汤达祯,许浩,等. 褐煤孔隙结构及比表面积特征[J].煤田地质与勘探,2016,44(6):59-63
ZHU W Q,TANG D Z,XU H,et al. Characteristics of pore structure and specific surface area of lignite[J]. Coal Geology & Exploration,2016,44(6):59-63.
22 张松航,汤达祯,唐书恒,等. 鄂尔多斯盆地东缘煤层气储集与产出条件[J].煤炭学报,2009,34(10):1297-1304.
ZHANG S H,TANG D Z,TANG S H,et al. Preservation and deliverability characteristics of coalbed methane in eastern margin of Ordos Basin[J].Journal of China Coal Society,2009,34(10):1297-1304.
23 张松航,汤达祯,唐书恒,等.鄂尔多斯盆地东缘煤储层微孔隙结构特征及其影响因素[J].地质学报,2008,82(10):1341-1349.
ZHANG S H,TANG D Z,TANG S H,et al. The characters of coal beds micropores and its influence factors in the eastern margin of Ordos Basin[J]. Acta Geologica Sinica,2008,82(10):1341-1349.
24 张琴,梁峰,梁萍萍,等. 页岩分型特征及主控因素研究[J]. 中国矿业大学学报,2020,49(1):110-122.
ZHANG Q,LIANG F,LIANG P P,et al. Investigation of fractal characteristics and its main controlling factors of shale reservoir: A case study of the Longmaxi shale in Weiyuan shale gas field[J]. Journal of China University of Mining & Technology,2020,49(1):110-122.
25 杨峰,宁正福,孔德涛,等. 高压压汞法和氮气吸附法分析页岩孔隙结构[J]. 天然气地球科学,2013, 24(3):450-455.
YANG F,NING Z F,KONG D T, et al. Pore structure of shales from high pressure mercury injection and nitrogen adsorption method[J]. Natural Gas Geoscience,2013, 24(3):450-455.
26 HODOT B B,宋世钊,王佑安. 煤与瓦斯突出[M]. 北京:中国工业出版社,1966:27-30.
HODOT B B, SONG S Z, WANG Y A. Outburst of Coal and Coalbed Gas(Chinese Translation)[M].Beijing:China Coal Industry Press,1966:27-30.
27 王博洋,秦勇,申建,等. 二连盆地褐煤矿物质特征及其对孔隙结构的影响[J]. 煤炭科学技术,2017,45(9): 32-41.
WANG B Y,QIN Y,SHEN J,et al. Mineral features of lignite in Erlian Basin and influences to pore structure[J]. Coal Science and Technology,2017,45(9):32-41.
28 LU Y J,LIU D M,CAI Y D,et al. Pore-fractures of coalbed methane reservoir restricted by coal facies in Sangjiang-Muling coal-bearing basins, northeast China[J]. Energies, 2020(13):1196.
29 DIESSEL C F K. On the correlation between coal facies and depositional environments[C]∥ Advances in the Study of the Sydney Basin Newcastle,1986:19-22.
30 DIESSEL C F K. Coal-bearing Depositional Systems[M]. Berlin:Springer,1992:721.
31 OSKAY R G,CHRISTANIS K,INANER H,et al. Palaeoenvironmental reconstruction of the eastern part of the Karapınar-Ayrancı coal deposit(central Turkey)[J]. International Journal of Coal Geology,2016(163):100-111.
32 代世峰,任德贻,李生盛,等.内蒙古准格尔黑岱沟主采煤层的煤相演替特征[J].中国科学,D辑,2007,37(S1):119-126.
DAI S F,REN D Y,LI S S,et al.The evolution and characteristic of coal facies in Heidaigou mine of Junger,Inner Mongolia[J]. Science in China,Series D,2007,37(S1):119-126.
33 ZHANG S H,ANG S H,TAMG D Z,et al. The characteristics of coal reservoir pores and coal facies in Liulin district,Hedong coal field of China[J].International Journal of Coal Geology,2010(81):117-127.
34 张鹏飞,金奎励,吴涛,等. 吐哈盆地含煤沉积与煤成油[M]. 北京:煤炭工业出版社,1997:168-176.
ZHANG P F,JIN K L,WU T,et al. Coal-bearing Sedimentary and Coal Formed Oil,Turpan-Hami Basin[M]. Beijing:China Coal Industry Press,1997:168-176.
35 KALAITZIDIS S,BOUZINOS A, PAPAZISIMOU S, et al. A short-term establishment of forest fen habitat during Pliocene lignite formation in the Ptolemais Basin, NW Macedonia, Greece[J]. International Journal of Coal Geology, 2004,57(3):243-263.
36 CALDER J H,GIBLING M R,MUKHOPADHYAY P. Peat formation in a Westphalian B piedmont setting,Cumberland basin,Nova Scotia:Implications for the maceral-based interpretation of rheotrophic and raised Paleomires[J].Bull De La Societe Geologique De France, 1991,162(2):283-298.
[1] Min-xing LI,Hai-zhou QU,Qi ZENG,Hong YIN,Yun-feng ZHANG,Mao-yao LIU,Yan-feng LI. Pore evolution characteristics and distribution of favorable reservoir area of the Upper Permian Wujiaping Formation in the Northwestern Sichuan [J]. Natural Gas Geoscience, 2020, 31(11): 1574-1584.
[2] Xie Wei-dong, Wang Meng, Dai Xu-guang, Wang Yan-di. Microscopic characteristics of shale gas reservoirs in middle and southern coal measures of Hedong Coalfield,Shanxi Province [J]. Natural Gas Geoscience, 2019, 30(4): 512-525.
[3] Wang Xiang-zeng,Zhang Li-xia,Jiang Cheng-fu,Yin Jin-tao,Gao Chao,Sun Jian-bo,Yin Na,Xue Lian-hua. The effect of differential uplift on pore development of Chang 7 shale in Ordos Basin:Case studies of Ganquan area and Weibei uplift area [J]. Natural Gas Geoscience, 2018, 29(5): 597-605.
[4] Lin Bo-tao,Chen Yuan,Chen Mian,Jin Yan,Jiang Zheng. Application of multi-peak pore size distribution model in pore structure analysis of shale [J]. Natural Gas Geoscience, 2018, 29(3): 397-403.
[5] Chen Yue,Ma Dong-min,Wu Sheng,Li Xin-hu,Fang Shi-yue,Guo Chen. Pore characteristics and main controlling factors of mud shalein coal-bearing strata of eastern Ordos Basin [J]. Natural Gas Geoscience, 2018, 29(2): 189-198.
[6] Yin Na, Xue Lian-hua, Jiang Cheng-fu, Yang Shuang, Gao Chao, Chen Guo-jun. The porous evolution and fractal dimension of the organic-rich shale at the stage of hydrocarbon generation [J]. Natural Gas Geoscience, 2018, 29(12): 1817-1828.
[7] Kang Yi-li,Chen Yi-bin,Li Xiang-chen,You Li-jun,Chen Ming-jun. Effect of particle size on methane sorption capacity of shales [J]. Natural Gas Geoscience, 2017, 28(2): 272-279.
[8] Cao Tao-tao, Song Zhi-guang, Luo Hou-yong, Zhou Yuan-yuan, Wang Si-bo. Pore system characteristics of Permian transitional shale reservoirin the Lower Yangtze region,China [J]. Natural Gas Geoscience, 2016, 27(7): 1332-1345.
[9] XIA Jia,WANG Si-bo,CAO Tao-tao,YANG Jin-zhao,SONG Zhi-guang. The Characteristics of Pore Structure and Its Gas Storage Capability of the Lower Cambrian Shales from Northern Guizhou Province [J]. Natural Gas Geoscience, 2015, 26(9): 1744-1754.
[10] ZHANG Yu,YAN Jian-ping,JIA Xiang-juan,LI Yan-fang,SHAO De-yong,YU Ping,ZHANG Tong-wei. The Pore Size Distribution and Its Relationship with Shale Gas Capacity in Organic-rich Mudstone of Wufeng-Longmaxi Formation,Sichuan Basin [J]. Natural Gas Geoscience, 2015, 26(9): 1755-1762.
[11] LI Xian-qing,WANG Yuan,GUO Man,ZHANG Ji-zhen,ZHAO Pei,XU Hong-wei,YANG Jie,WANG Fei-yu. Pore Characteristics of Shale Gas Reservoirs from the Lower Paleozoic in the South of Sichuan Basin [J]. Natural Gas Geoscience, 2015, 26(8): 1464-1471.
[12] CAO Tao-tao,SONG Zhi-guang,WANG Si-bo,XIA Jia. Physical Property Characteristics and Controlling Factors of Permian Shale Reservoir in the Lower Yangtze Platform [J]. Natural Gas Geoscience, 2015, 26(2): 341-351.
[13] ZHAO Pei,LI Xian-qing,TIAN Xing-wang,SU Gui-ping,ZHANG Ming-yang,GUO Man,DONG Ze-liang,SUN Meng-meng,WANG Fei-yu. Study on Micropore Structure Characteristics of Longmaxi FormationShale Gas Reservoirs in the Southern Sichuan Basin [J]. Natural Gas Geoscience, 2014, 25(6): 947-956.
[14] JI Li-ming,MA Xiang-xian,XIA Yan-qing,QIU Jun-li. Relationship between Methane Adsorption Capacity of Clay Minerals and Micropore Volume [J]. Natural Gas Geoscience, 2014, 25(2): 141-152.
[15] BI He,JIANG Zhen-xue,LI Peng,CHENG Li-jun,ZENG Chun-lin,XU Ye,ZHANG Ying-ying. Adsorption Characteristic and Influence Factors of Longmaxi Shale in Southeastern Chongqing [J]. Natural Gas Geoscience, 2014, 25(2): 302-310.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
[1] YU Jun-feng,XIA Bin,XU Jing. AN UNDERSTANDING OF TENSE-SHEARING AND COMPRESSO-SHEARING STRUCTURES IN BOHAI BAY BASIN[J]. Natural Gas Geoscience, 2006, 17(4): 473 -476 .
[2] .
THE APPLICATION OF MICRO EARTHQUAKE MONITORING THEGAS INJECTION ADVANCING EDGE IN THE YAHA CONDENSATE GAS RESERVOIR
[J]. Natural Gas Geoscience, 2005, 16(3): 390 -393 .
[3] WANG Wan-chun,LIU Wen-hui, LIU Quan-you. ANALYSES OF THE CARBON ISOTOPIC GEOCHEMISTRY OF THEMIX-SOURCED SHALLOW RESERVOIR NATURAL GAS IDENTIFICATION[J]. Natural Gas Geoscience, 2003, 14(6): 469 -473 .
[4] JIANG Hou-shun,BAI Yan-hua,RAN Jian-li . PREDICTION OF HORIZONTAL WELL DELIVERABILITY ANDOPTIMIZATION OF PERFORATION PARAMETERS[HJ0][J]. Natural Gas Geoscience, 2007, 18(6): 891 -893 .
[5] LIU Jian-Feng, PENG Jun, ZHOU Kang, YAN Xiao-Mei, TANG Yong, LIU Jin-KuKu. High Resolution Sequence Stratigraphy Analysis of 2nd Member of Xujiahe Formation in Middle and South Sichuan Transitional Zone[J]. Natural Gas Geoscience, 2009, 20(2): 199 -203 .
[6] CHEN Zong-Qing. Discussion on Gas Exploration of Middle Permian Qixia Formation, Sichuan Basin[J]. Natural Gas Geoscience, 2009, 20(3): 325 -334 .
[7] LI Yan-Li. Calculation Methods of Shale Gas Reserves[J]. Natural Gas Geoscience, 2009, 20(3): 466 -470 .
[8] GUO Zhen-hua, ZHAO Yan-Chao. Logging Evaluation to Tight Gas Reservoir in He-2 Member of Daniudi Gas Field[J]. Natural Gas Geoscience, 2010, 21(1): 87 -94 .
[9] WANG Ming-Yan, GUO Jian-Hua, KUANG Li-Xiong, ZHU Rui. Geochemical Characteristics and Evolution of the Hydrocarbon  Source Rocks from Lianyuan Depression in the Middle of Hunan Province[J]. Natural Gas Geoscience, 2010, 21(5): 721 -726 .
[10] SONG Qi, WANG Shu-Li, CHEN Yan, ZHENG Zhi, XIE Lei. A New Kinetic Model and Experiment for Natural Gas Hydrate[J]. Natural Gas Geoscience, 2010, 21(5): 868 -874 .