Natural Gas Geoscience

Previous Articles     Next Articles

Influences of the deep fluid on organic matter during the hydrocarbon generation and evolution process

Liu Jia-yi1,2,Liu Quan-you1,2,Zhu Dong-ya1,2,Meng Qing-qiang1,2,Huang Xiao-wei   

  1. 1.State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development,Beijing 100083,China;2.Research Institute of Petroleum Exploration and Production,SINOPEC,Beijing 100083,China;3.China University of Geoscience(Beijing),Beijing 100083,China
  • Received:2018-11-23 Revised:2019-01-02 Online:2019-04-10

Abstract: As the formation and development of organic-inorganic interaction,people came to realize the important role of inorganic matter during the process of organic matter maturation and hydrocarbon generation.Deep fluids act as a carrier of inner earth substances,and it carried massive inorganic matter from deep earth.The injection of deep fluids provide sedimentary basin with hydrogen sources and catalyst,which would promote the maturation and evolution of organic matters with basins.By providing essential carbon sources for inorganic reaction,deep fluids also took a part in inorganic hydrocarbon generation reaction.This paper collects recent achievements about organic matter hydrogenation reaction and inorganic hydrocarbon generation reaction such as F-T synthesis.By giving a detailed analysis of the effect extraneous hydrogen sources and catalyst exerted on organic maturation and hydrocarbon-producing process,this paper confirms the “increasing hydrocarbon yield” effect of deep fluid.

Key words: Deep fluid, Organic-inorganic interaction, “Increasing hydrocarbon yield” effect, Extraneous hydrogen sources, Catalyst, Carbon sources

CLC Number: 

  • TE122.1+1
[1]Liu Wenhui,Wang Wanchun.The organic(biogenic) and inorganic(non-biogenic) sources of hydrocarbons-thought on theory of oil and gas formation[J].Bulletin of Mineralogy,Petrology and Geochemistry,2000,19(3):179-186.
刘文汇,王万春.烃类的有机(生物)与无机(非生物)来源——油气成因理论思考之二[J].矿物岩石地球化学通报,2000,19(3):179-186.
[2]Liu Quanyou,Zhu Dongya,Meng Qingqiang,et al.The basic connotation of oil and gas formation under deep fluid and organic-inorganic interaction[J].Science China Earth Sciences,2018.
刘全有,朱东亚,孟庆强,等.深部流体及有机—无机相互作用下油气形成的基本内涵[J].中国科学地球科学,2018.
[3]Chen Feng.Hydrogen-the important source offluid in earth interior[J].Earth Science Frontiers,1996,3(3/4):72-79.
陈丰.氢—地球深部流体的重要源泉[J].地学前缘,1996,3(3/4):72-79.
[4]Lu Fengxiang.Deep mantle and its fluids[J].Earth Science Frontiers,1996,3(3):181-186.
路凤香.深部地幔及深部流体[J].地学前缘,1996,3(3):181-186.
[5]Hu Wenxuan.Origin and indicators of deep-seated fluids in sedimentary basins[J].Bulletin of Mineralogy,Petrology and Geochemistry,2016,35(5):817-826.
胡文暄.盆地深部流体主要来源及判识标志研究[J].矿物岩石地球化学通报,2016,35(5):817-826.
[6]Jin Zhijun,Zhang Liuping,Yang Lei,et al.Primary study of geochemical features of deep fluids and their effectiveness on oil/gas reservoir formation in sedimental basins[J],Earth Science,2002,27(6):659-665.
金之钧,张刘平,杨雷,等.沉积盆地深部流体的地球化学特征及油气成藏效应初探[J].地球科学,2002,27(6):659-665.
[7]Peter J M,Peltonen P,Scott S D,et al.14C ages of hydrothermal petroleum and carbonate in Guaymas Basin,Gulf of California:Implications for oil generation,expulsion and migration[J].Geology,1991,19(3):253-256.
[8]Simoneit B R T,Kvenvolden K A.Comparison of 14C ages of hydrothermal petroleums[J].Organic Geochemistry,1994,21(5):525-529.
[9]Simoneit B R T,Aboul-Kassim T A T,Tiercelin J J.Hydrothermal petroleum from lacustrine sedimentary organic matter in the East African Rift[J].Applied Geochemistry,2000,15:355-368.
[10]Didyk B M,Simoneit B R T.Petroleum characteristics of the oil in a Guaymas Basin hydrothermal chimney[J].Applied Geochemistry,1990,5(1/2):29-40.
[11]Simoneit B R T,Lonsdale P F.Hydrothermal petroleum in mineralized mounds at the seabed of Guaymas Basin[J].Nature,1982,295:198-202.
[12]Kvenvolden K A,Rapp J B,Hostettler F D,et al.Petroleum associated with polymetallic sulfide in sediment from Gorda Ridge[J].Science,1986,234(4781):1231-1234.
[13]Simoneit B R T,Grimalt J O,Hayes J M,et al.Low temperature hydrothermal maturation of organic matter in sediments from the AtlanticⅡ deep Red Sea[J].Geochimica Et Cosmochimica Acta,1987,51:879-894.
[14]Clifton C G,Walters C C,Simoneit B R T.Hydrothermal petroleums from Yellowstone National Park,Wyoming,USA[J].Applied Geochemistry,1990,5:169-191.
[15]Tiercelin J J,Thourin C,Kalala T,et al.Discovery of sublacustrine hydrothermal activity and associated massive sulfides and hydrocarbons in the north Tanganyika trough,East African Rift[J].Geology,1993,17:1053-1056.
[16]Bazhenova O K,Arefiev O A,Frolov E B.Oil of the volcano Uzon Caldera,Kamchatka[J].Organic Geochemistry,1998,29(1-3):421-428.
[17]Yamanaka T,Mizota C,Murae T,et al.A currently forming petroleum associated with hydrothermal mineralization in a submarine caldera,Kagoshima Bay,Japan[J].Geochemical Journal,1999,33(6):355-367.
[18]Guo Zhanqian.Mineralized hydrothermal liquid and petroleum generation[J].Xinjiang Petroleum Geology,2001,22(3):181-184.
郭占谦.成矿热液与石油生成[J].新疆石油地质,2001,22(3):181-184.
[19]Montacer M,Disnar J R,Orgeval J J,et al.Relationship between Zn-Pb ore and oil accumulation processes:Example of the Bou Grine Deposit(Tunisia)[J].Organic Geochemistry,1988,13:423-431.
[20]Anderson G M.Organic maturation and ore precipitation in southeast Missouri[J].Economic Geology,1991,86(5):909-926.
[21]Oliver J.Fluids expelled tectonically from orogenic belts:Their role in hydrocarbon migration and other geologic phenomena[J].Geology,1986,14:99-102.
[22]Gu Xuexiang,Zhang Yongmei,Li Baohua,et al.The coupling relationship between metallization and hydrocarbon accumulation in sedimentary basins[J].Earth Science Frontiers,2010,17(2):83-105.
顾雪祥,章永梅,李葆华,等.沉积盆地中金属成矿与油气成藏的耦合关系[J].地学前缘,2010,17(2):83-105.
[23]Berndt M E,Allen D E,Seyfried W E.Reduction of CO2 during serpentinization of olivine at 300℃ and 500 bar[J].Geology,1996,24(4):351-354.
[24]Rona P A,Widenfalk L,Bostr M K.Serpentinized ultramafics and hydrothermal activity at the Mid-Atlantic Ridge crest near 15°N[J].Journal of Geophysical Research,1987,92(B2):1417-1428.
[25]Blackman D K,Karson J A,Kelley D S,et al.Geology of the Atlantis Massif(Mid-Atlantic Rifge,30°N):Implications for the evolution of an ultramafic oceanic core complex[J].Marine Geophysical Researches,2002,23(5):443-469.
[26]Dick H J B,Lin J,Schouten H.An ultraslow-spreading class of ocean ridge[J].Nature,2003,426(6965):405-412.
[27]Warren J M,Shimizu N,Sakaguchi C,et al.Large local-scale isotopic heterogeneities of the MORB source mantle:A case study on the SWIR[J].Geochimica Et Cosmochimica Acta,2006,70(18,Supplement 1):A585.
[28]German C R,Baker E T,Mevel C,et al.Hydrothermal activity along the southwest Indian ridge[J].Nature,1998,395(6701):490-493.
[29]Dick H J B.Abyssal peridotites,very slow spreading ridges and ocean ridge magmatism[J].Geological Society,1989,42(1):71-105.
[30]Parkinson I J,Pearce J A.Peridotites from the Izu-Bonin-Mariana forearc(ODP Leg 125):Evidence for mantle melting and melt-mantle interaction in a supra-subduction zone setting[J].Journal of Petrology,1998,39(9):1577-1618.
[31]Chen Junbing,Zeng Zhigang.Metasomatism of the Harburgites from the southern Mariana forearc:Characteristics of the trace elements from Clinopyroxene and Hornblende[J].Science in China:Series D,2007,37(6):720-727.
陈俊兵,曾志刚.马里亚纳岛弧南部前弧方辉橄榄岩的交代作用:单斜辉石和角闪石的微量元素特征[J].中国科学:D辑,2007,37(6):720-727.
[32]Wang Xiaomei,Zeng Zhigang,Chen Junbing.Serpentinization of Peridotites from the southern Mariana forearc[J].Progress in Nature Science,2009,19(8):859-867.
汪小妹,曾志刚,陈俊兵.马里亚纳前弧南部橄榄岩的蛇纹石化[J].自然科学进展,2009,19(8):859-867.
[33]Bonatti E,Seyler M,Channell J,et al.Peridotites drilled from the Tyrrhenian Sea,ODP Leg 107[J].Proceedings of Ocean Drilling Program:Scientific Results,1990,107:37-47.
[34]Pearce J A,Barker P F,Edwards S J,et al.Geochemistry and tectonic significance of peridotites from the South Sandwich arc-basin system,South Atlantic[J].Contributions to Mineralogy and Petrology,2000,139(1):36-53.
[35]Biollot G,Grimaud S,Mauffret A,et al.Ocean-continent Boundary off the Iberian margin:A serpentinite diapir west of the Galicia Bank,Earth Planet[J].Earth and Planetary Science Letters,1980,48:23-24.
[36]Biollot G,Feraud G,Recq M,et al.undercrusting by serpentinite beneath rifted margins[J].Nature,1989,341:523-525.
[37]Vovk I F.Radiolysis of underground waters as the mechanism of geochemical transformation of the energy of radioactive decay in sedimentary rocks[J].Lithology and Mineral Resource,1982,16,328-334.
[38]Lin L H,James H,Lippmann-Pieke J.Radiolytic H2 in continental crust:Nuclear power for deep subsurface microbial communities[J].Geochemistry Geophysics Geosystems,2005,6:1-13.
[39]Liu Chiyang,Mao Guangzhou,Qiu Xinwei,et al.Organic-inorganic energy minerals interactions and the accumulation and mineralization in the same sedimentary basins[J].Journal of Nature,2013,35(1):47-55.
刘池洋,毛光周,邱欣卫,等.有机-无机能源矿产相互作用及其共存成藏(矿)[J].自然杂志,2013,35(1):47-55.
[40]Liu Chiyang,Tan Chengqian,Sun Wei,et al.Research Progress on the Coexistence and Accumulation of Integrated Minerals(Mines) in Various Energy Minerals in the Basin[M].Bejing:Science Press,2005:1-16.
刘池洋,谭成仟,孙卫,等.盆地多种能源矿产共存富集成藏(矿)研究进展[M].北京:科学出版社,2005:1-16.
[41]Chen Feng,Ding Zhenhua,Guo Jiugao,et al.Hydrogen molecule in diamond[J].Chinese Science Bulletin,1994,39(15):1403-1404.
陈丰,丁振华,郭九皋,等.金刚石中的分子氢[J].科学通报,1994,39(15):1403-1404.
[42]Lewan M D.Experiments on the role of water in petroleum formation[J].Geochimica Et Cosmochimica Acta,1997,61(17):3691-3723.
[43]Wang Xiaofeng,Liu Wenhui,Xu Yongchang,et al.Pyrolytic simulation experiments on the role of water in natural gas generation[J].Progress in Nature Science,2006,16(10):1275-1281.
王晓锋,刘文汇,徐永昌,等.水在有机质形成气态烃演化中作用的热模拟实验研究[J].自然科学进展,2006,16(10):1275-1281.
[44]Pan C,Geng A,Zhong N,et al.Kerogen pyrolysis in the presence and absence of water and minerals.1.Gas components[J].Energy & Fuel,2008,22(1):416-427.
[45]Lewan M D,Roy S.Role of water in hydrocarbon generation from Type-I kerogen in Mahogany oil shale of the Green River Formation[J].Organic Geochemistry,2011,42:31-41.
[46]Seewald J S.Organic-inorganic interaction in petroleum-producing sedimentary basins[J].Nature,2003,436(20):327-333.
[47]Wang Xiaofeng,Liu Wenhui,Xu Yongchang,et al.Influences of water media on the hydrogen isotopic composition of natural gas/methane in the processes of gaseous hydrocarbon generation and evolution[J].Science China Press:Earth Science,2012,42(1):103-110.
王晓锋,刘文汇,徐永昌,等.水介质对气态烃形成演化过程氢同位素组成的影响[J].中国科学:地球科学,2012,42(1):103-110.
[48]Sun Lina,Zhang Mingfeng,Wu Chenjun,et al.The effect of water medium on the products of different pyrolysis system[J].Natural Gas Geoscience,2015,26(3):525-532.
孙丽娜,张明峰,吴陈君,等.水对不同生烃模拟实验系统产物的影响[J].天然气地球科学,2015,26(3):525-532.
[49]Gao Gang,Jiang Zhenxue,Zhao Zhe,et al.Influence of temperature increase veocity to the hydrocarbon formation of source rock by hydropyrolysis[J].Natural Gas Geoscience,2004,15(5):461-464.
高岗,姜振学,赵喆,等.加水模拟条件下升温速率对烃源岩成烃特征的影响[J].天然气地球科学,2004,15(5):461-464.
[50]Castelli A,Chiaramonte M A,Beltrame P L,et al.Thermal degradation of kerogen by hydrous pyrolysis-a kinetic study[J].Organic Geochemistry,1990,16(1-3):75-82.
[51]Qin Jianzhong,Liu Jingwang,Liu Baoquan,et al.Hydrocarbon yield and geochemical parameters affected by heating time and added water amount in the simulation test[J].Petroleum Geology & Experiment,2002,24(2):152-157.
秦建中,刘井旺,刘宝泉,等.加温时间、加水量对模拟实验油气产率及地化参数的影响[J].石油实验地质,2002,24(2):152-157.
[52]Fu Q,Sherwood Lollar B,Horita J,et al.Abiotic formation of hydrocarbons under hydrothermal conditions:constraints from chemical and isotope data[J].Geochimica et Cosmochimica Acta,2007,71:1982-1998.
[53]Pan C C,Geng A S,Zhong N N,et al.Kerogen pyrolysis in the presence and absence of water and minerals:Amounts and compositions of bitumen and liquid hydrocarbons[J].Fuel,2009,88:909-919.
[54]Pan C C,Jiang L L,Liu J Z,et al.The effects of calcite and montmorillonite on oil cracking in confined pyrolysis experiments[J].Organic Chemistry,2010,41(7):611-626.
[55]Tannenbaum E,Kaplan I R.Role of minerals in the thermal alteration of organic matter
-Ⅰ:Generation of gases and condensates under dry condition[J].Geochimica et Cosmochimica Acta,1985,49(12):2589-2604.
[56]Liu Chiyang,Mao Gunagzhou,Qiu Xinwei,et al.Organic-inorganic energy minerals interactions and the accumulation and mineralization in the same sedimentary basins[J].Chinese Journal of Nature,2013,35(1):47-54.
刘池洋,毛光周,邱欣卫,等.有机-无机能源矿产相互作用及其共存成藏(矿)[J].自然杂志,2013,35(1):47-54.
[57]Lu Hongxuan,Meng Zifang,Li Bin,et al.Effect of uranium substance on hydrocarbon generation from lignite by hydrous pyrolysis[J].Xinjiang Petroleum Geology,2007,28(6):718-720.
卢红选,孟自芳,李斌,等.含铀物质对褐煤有机质热模拟生烃的影响[J].新疆石油地质,2007,28(6):718-720.
[58]Lu Hongxuan,Meng Zifang,Li Bin,et al.Effect of uranium substance on hydrocarbon generation from mudstone by hydrous pyrolysis[J].Acta Sedimentologica Sinica.2008,26(2):324-329.
卢红选,孟自芳,李斌,等.含铀物质对泥岩有机质热模拟生烃产物的影响[J].沉积学报,2008,26(2):324-329.
[59]Li Bin,Meng Zifang,Xia Bin,et al.Hydrocarbon-generating thermal simulation of uranium-bearing minerals[J].Acta Petrologica et Mineralogica,2008,27(1):52-58.
李斌,孟自芳,夏斌,等.含铀矿物对烃源岩生烃影响的热模拟研究[J].岩石矿物学杂志,2008,27(1):52-58.
[60]Mao Guangzhou,Liu Chiyang,Liu Baoquan,et al.Effects of uranium on hydrocarbon generation of low-mature hydrocarbon source rocks containing kerogen typeⅠ[J].Journal of China University of Petroleum.2012,36(2):172-181.
毛光周,刘池洋,刘宝泉,等.铀对(Ⅰ型)低熟烃源岩生烃演化的影响[J].中国石油大学学报,2012,36(2):172-181.
[61]Mao Guangzhou,Liu Chiyang,Zhang Dongdong,et al.Effects of uranium(type Ⅱ) on evolution of hydrocarbon generation of source rocks[J].Acta Geologica Sinica.2012,86(11):1834-1840.
毛光周,刘池洋,张东东,等.铀对(Ⅱ型)低熟烃源岩生烃演化的影响[J].地质学报,2012,86(11):1834-1840.
[62]Mao Guangzhou,Liu Chiyang,Zhang Dongdong,et al.Effects of uranium  on  hydrocarbon generation of hydrocarbon source rocks with type-Ⅲ kerogen[J].Science China Press:Earth Science.2014,44(8):1740-1750.
毛光周,刘池洋,张东东,等.铀在Ⅲ型烃源岩生烃演化中作用的实验研究[J].中国科学:地球科学,2014,44(8):1740-1750.
[63]Wu Yanyan,Qin Yong.Catalysis of mineral /metal elements during coal bed gas generation[J].Advances in Earth Science,2009,24(8):882-890.
吴艳艳,秦勇.煤中矿物/金属元素在生气过程中的催化作用[J].地球科学进展,2009,24(8):882-890.
[64]Wu Yanyan,Qin Yong,Liu Jinzhong,et al.Catalysis action of mineral/metal elements during coal-derived hydrocarbons process:An example of the Late Permian coal from Dahebian coal mine in eastern Yunnan and western Guizhou[J].Natural Gas Geoscience,2012,23(1):141-152.
吴艳艳,秦勇,刘金钟,等.矿物/金属元素在煤成烃过程中的作用——以黔西滇东上二叠统大河边煤矿为例[J].天然气地球科学,2012,23(1):141-152.
[65]Lamber J M.Alternative interpretation of coal liquefaction catalysis by pyrite[J].Fuel,1982,61:777.
[66]Ma X X,Zheng J J,Zheng G D,et al.Influence of pyrite on hydrocarbon generation during pyrolysis of type-Ⅲ kerogen[J].Fuel,2015,167:329-336.
[67]Ma X X,Zheng G D,Wasim Sajjad,et al.Influence of minerals and iron on natural gases generation during pyrolysis of type-Ⅲ kerogen[J].Marine and Petroleum Geology,2018,89:216-224.
[68]Weng Sihao,Wu Youqing,Gao Jinsheng,et al.Mossbauer spectroscopic study of iron catalyst in coal hydroliquefaction:Ⅰ.on the tranformation and the action mechanism of iron sulphide in hydrogeneration[J].Journal of Fuel Chemistry and Technology,1990,18(2):97-102.
翁斯灏,吴幼青,高晋生,等.煤加氢液化铁催化剂的穆斯堡尔谱研究:Ⅰ.铁硫化物在加氢反应中的转化及活性机理[J].燃料化学学报,1990,18(2):97-102.
[69]Zu Xiaojing,Tuojincai,Zhang Mingfeng,et al.The roles of inorganic minerals on the oil and gas generation processes[J].Acta Sedimentologica Sinica,2007,25(2):299-306.
祖小京,妥进才,张明峰,等.矿物在油气形成过程中的作用[J].沉积学报,2007,25(2):299-306.
[70]Cai Yuwen,Zhang Shuichang,He Kun,et al.The effect of magnetite on the products and isotopic fractions of gaseous hydrocarbons[J].Natural Gas Geoscience,2017,28(2):331-340.
蔡郁文,张水昌,何坤,等.磁铁矿对有机质生烃及同位素分馏的影响[J].天然气地球科学,2017,28(2):331-340.
[71]Ma Xiangxian,Zheng Jianjing,Zheng Guodong.Catalysis of iron-bearing minerals on hydrocarbon generation and evolution of Brown coal[J].Natural Gas Geoscience,2014,25(7):1065-1071.
马向贤,郑建京,郑国东.含铁矿物对褐煤生烃演化的催化作用[J].天然气地球科学.2014,25(7):1065-1071.
[72]Mango F D,Hightawer J W,James A T.Role of transition-metal catalysis in the formation of natural gas[J].Nature,1994,368:536-538.
[73]Mango F D.Transition metal catalysis in the generation of natural gas[J].Organic Geochemistry,1996,24:977-984.
[74]Mango F D,Hightower J.The catalytic decomposition of petroleum into natural gas[J].Geochimica et Cosmochimica Acta,1997,61(24):5347-5350.
[75]Medina J C,Butala S J,Bartholomew C H,et al.Low temperature iron and nickel catalyzed reactions leading to coal bed gas formation[J].Geochimica et Cosmochimica Acta,2000,64(4):643-649.
[76]Foustoukos D I,Seyfried W E Jr.Hydrocarbons in hydrothermal vent fluids:the role of chromium-bearing catalysts[J].Science,2004,304(5673):1002-1005.
[77]Yang Chun,Wang Jinghong,Mi Jingkui,et al.Carbon isotope fractionation mechanism of alkane gases in Fischer-Tropsch synthesis experiments[J].Natural Gas Geoscience,2011,22(2):206-223.
杨春,王京红,米敬奎.费—拖合成实验中烷烃气碳同位素分馏机理[J].天然气地球科学,2011,22(2):206-223.
[78]Lipsch J,Schuit G C A.The CoO,MoO3,Al2O3 catalyst:Ⅰ.Cobalt molybdate and the cobalt oxide mdybdemum oxide system[J].Journal of Catalysis,1969,15(2):163-173.
[79]Voorhoeve R J H,Stuiver J C M.The mechanism of the hydrogenation of cyclohexene and benzene on nickel-tungsten sulfide catalysts[J].Journal of Catalysis,1971,23:243-252.
[80]Topse H,Clausen B S.Active sites and support effects in hydrodesulfurization catalysts[J].Applied Catalysis,1986,25(1/2):273-293.
[81]Burton M R,Sawyer G M,Granieri D.Deep carbon emissions from volcanoes[J].Reviews in Mineralogy & Geochemistry,2013,75(1):323-354.
[82]Ague J J.Release of CO2 from carbonate rocks during regional metamorphism of lithologically heterogeneous crust[J].Geology,2000,28(12):1123-1126.
[83]Kerrick D M,Connolly J A D.Metamorphic devolatilization of subducted marine sediments and the transport of volatiles into the Earth's mantle[J].Nature,2001,411(6835):293-296.
[84]Ague J J,Nicolescu S.Carbon dioxide released from subduction zones by fluid-mediated reactions[J].Nature Geoscience,2014,7(5):355-360.
[85]Frezzotti M L,Huizenga J M,Compagnoni R,et al.Diamond formation by carbon saturation in C-O-H fluids during cold subduction of oceanic lithosphere[J].Geochimica et Cosmochimica Acta,2014,143:68-86.
[86]Dasgupta R,Hirschmann M M,Withers A C.Deep global cycling of carbon constrained by the solidus of anhydrous,carbonated eclogite under upper mantle conditions[J].Earth and Planetary Science Letters,2004,227(1/2):73-85
[87]Dasgupta R,Hirschmann M M,Stalker K.Immiscible transition from carbonate-rich to silicate-rich melts in the 3 GPa melting interval of eclogite+CO2 and genesis of silica-undersaturated ocean island lavas[J].Journal of Petrology,2006,47(4):647-671.
[88]Zhang Lifei,Tao Renbiao,Zhu Jianjiang.Some problems of deep carbon cycle in subduction zone[J].Bulletin of Mineralogy,Petrology and Geochemistry,2017,36(2):185-196.
张立飞,陶仁彪,朱建江.俯冲带深部碳循环:问题与探讨[J].矿物岩石地球化学通报,2017,36(2):185-196.
[89]Zhao Feiyu,Jiang Suhua,Li Sanzhong,et al.Correlation of inorganic CO2 gas reservoir in East China to  subduction of(paleo) Pacific plate[J].Earth Science Frontiers,2017,24(4):370-384.
赵斐宇,姜素华,李三忠,等.中国东部无机CO2气藏与(古)太平洋板块俯冲关联[J].地学前缘,2017,24(4):370-384.
[90]McCollom T M,Seewald J S.Abiotic synthesis of organic compounds in deep-sea hydrothermal environments[J].Chemical Reviews,2007,107(2):382-401.
[91]McCollom T M,Seewald J S.Carbon isotope composition of organic compounds produced by abiotic synthesis under hydrothermal conditions[J].Earth Planetary Science Letter,2006,243(1/2):74-84.
[92]Sherwood Lollar B,Frape S K,Weise S M,et al.Abiogenic methanogenesis in crystalline rocks[J].Geochimica et Cosmochimica Acta,1993,57(23/24):5087-5097.
[93]Dai Jinxing,Li Jian,Luo Xia,et al.Stable carbon isotope compositions and source rock geochemistry of the giant gas accumulations in the Ordos Basin China[J].Organic Geochemistry,2005,36(12):1617-1635.
[94]Zhu Zhimin,Shen Bing,Yan Jianfei.Discuss on inorganic natural gas in the Fuxin Basin[J].Natural Gas Geoscience,2006,17(3):418-421.
朱志敏,沈冰,闫剑飞.阜新盆地无机成因气探讨[J].天然气地球科学,2006,17(3):418-421.
[95]Hosgormez H,Yalcin M N,Cramer B,et al.Molecular and isotopic composition of gas occurrences in the Thrace basin(Turkey):Origin of the gases and characteristics of possible source rocks[J].Chemical Geology,2005,214:179-191.
[96]Dai Jinxing.Composition characteristics and origin of carbon isotope of Liuhuangtang natural gas in Tengchong county,Yunnan province[J].Chinese Science Bulletin,1989,34(12):1027-1030.
[97]Hu G,Ouyang Z,Wang X,et al.Carbon isotopic fractionation in the process of Fischer-Tropsch reaction in primitive solar nebula[J].Science in China:Series D,1998,41(2):202-207.
[98]Taran Y A,Kliger G A,Sevastianov V S.Carbon isotope effects in the open-system Fischer-Tropsch synthesis[J].Geochimica et Cosmochimica Acta,2007,71:4474-4487.
[99]Des Marais D J,Donchin J H,Nehring N L,et al.Molecular carbon isotopic evidence for the origin of geothermal hydrocarbons[J].Nature,1981,292(5826):826-828.]
[100]Williams L B,Canfield B,Vogelsonger K M,et al.Organic molecules formed in a “primordial womb”[J].Geology,2005,33(11):913-916.

[1] Liu Jia-yi,Liu Quan-you,Zhu Dong-ya,Meng Qing-qiang,Liu Wen-hui,Qiu Deng-feng,Huang Zhen-kai. The role of deep fluid in the formation of organic-rich source rocks [J]. Natural Gas Geoscience, 2018, 29(2): 168-177.
[2] JIANG Hou-Shun, CAI Cheng, YE Cui, WANG Ying. Pilot Test of Deep Fluid Diversion in SⅡ13-16 Layer of East Beierxi of Daqing Placanticline [J]. Natural Gas Geoscience, 2012, 23(2): 375-380.
[3] ZHOU Shi-xin; ZOU Hong-liang; XIE Qi-lai, JIA Xin-liang. ORGANIC-INORGANIC INTERACTIONS DURING THE FORMATION OF OILS IN S EDIMENTARY BASIN [J]. Natural Gas Geoscience, 2006, 17(1): 42-47.
[4] WANG Qi, SHI Ji-an. ADVANCES IN EXTRACTION OF ORGANIC-INORGANIC INTERACTIONINFORMATION WITHIN OIL RESERVOIR AND PRECISE  CORRELATIONTECHNIQUE WITH SOURCE ROCK [J]. Natural Gas Geoscience, 2005, 16(5): 564-570.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
[1] HE Jia-xiong, XIA Bin,SHI Xiao-bin,YAO Yong-jian,LIU Hai-ling, YAN Pin, ZHANG Sh. PROSPECT AND PROGRESS FOR OIL AND GAS IN DEEP WATERS OF THE WORLD  AND THE POTENTIAL AND PROSPECT FOREGROUND FOR OIL AND GAS  IN DEEP WATERS OF THE SOUTH CHINA SEA[J]. Natural Gas Geoscience, 2006, 17(6): 747 -752 .
[2] SUN De-qiang ; ZHANG Tao ;LIANG Bin ;QI Wen-zhen ;LIU Jian ;ZHAI Zhi-feng ;YANG LIAN-xi ;LIU Zhi-Zhou ;ZHAO Fan . Reservoir-forming Features of Oil and Gas in North of Qaidam Basin[J]. Natural Gas Geoscience, 2008, 19(05): 652 -656 .
[3] JIANG Hou-shun,BAI Yan-hua,RAN Jian-li . PREDICTION OF HORIZONTAL WELL DELIVERABILITY ANDOPTIMIZATION OF PERFORATION PARAMETERS[HJ0][J]. Natural Gas Geoscience, 2007, 18(6): 891 -893 .
[4] SONG Qi, WANG Shu-Li, CHEN Yan, ZHENG Zhi, XIE Lei. A New Kinetic Model and Experiment for Natural Gas Hydrate[J]. Natural Gas Geoscience, 2010, 21(5): 868 -874 .
[5] CHEN Shi-Jia, CHEN Xue, LU Jun-Gang, LIU Lin-Chao, YANG Guo-Ping, WANG Yi. Characteristics of Natural Gas Sources and Accumulation in Dibei Uplift of Junggar Basin[J]. Natural Gas Geoscience, 2011, 22(1): 97 -101 .
[6] ZHU Chun-Jun, WANG Yan-Bin. Hydrocarbon-generating Potential in Mesozoic Suibin Depression of Sanjiang Basin[J]. Natural Gas Geoscience, 2011, 22(2): 307 -314 .
[7] HUANG Lin-Jun, YANG Wei, WANG Yan-Jun, WANG Bin. Application of Forward Solution Model in Identifying Volcanic Reservoir:A Case of Permian Volcanic Reservoir in Wuxia Area of Junggar Basin[J]. Natural Gas Geoscience, 2011, 22(3): 539 -542 .
[8] ZHAO Meng-Jun, WANG Xu-Long, DA Jiang, XIANG Bao-Li, SONG Yan, QIN Sheng-Fei. Genetic Origin of Natural Gas and Its Filling Historyin Dinan Uplift-Wucaiwan of Junggar Basin[J]. Natural Gas Geoscience, 2011, 22(4): 595 -601 .
[9] CHEN Guo-Jun, LI Chao, LIANG Jian-She, WANG Qi, LV Cheng-Fu, ZHANG Jin-Wei, DU Gui-Chao, TIAN Bing. Sedimentary Facies of Mingyuefeng Formation in Oujiang Sag,East China Sea Basin[J]. Natural Gas Geoscience, 2011, 22(5): 760 -769 .
[10] TANG You-Jun, WEN Zhi-Gang, ZHANG Chao-Mo, LI Jun, SHU Cui-Shan. Evaluation of Source Rock of Well Tian 2, Tiancao Sag of Yinggen-Ejinaqi Basin[J]. Natural Gas Geoscience, 2008, 19(4): 530 -536 .