天然气地球科学

• 非常规天然气 • 上一篇    下一篇

考虑水溶气的页岩气藏物质平衡方程及储量计算方法

尚颖雪,李晓平,宋力   

  1. 1.西南石油大学“油气藏地质及开发工程”国家重点实验室,四川 成都 610500;
    2.中国石油川庆钻探工程有限公司钻采工程技术研究院,四川 广汉 618300
  • 收稿日期:2014-09-19 修回日期:2014-11-02 出版日期:2015-06-10 发布日期:2015-06-10
  • 作者简介:尚颖雪(1991-),女,山东东营人,硕士研究生,主要从事油气藏工程及渗流力学研究. E-mail:syxswpu@163.com.
  • 基金资助:

    国家杰出青年科学基金“油气渗流力学”(编号:51125019);教育部“长江学者和创新团队发展计划”(编号:IRT1079)联合资助.

Material Balance Equation and Reserves Calculation Method Considering Water Soluble Gas for Shale Gas Reservoirs

SHANG Ying-xue,LI Xiao-ping,SONG Li   

  1. 1.State Key Laboratory of Oil-Gas Reservoir Geology and Exploitation,Southwest Petroleum University,Chengdu 610500,China;
    2.Drilling and Production Engineering Technology Research Institute,Chuanqing Drilling EngineeringCompany Limited,PetroChina,Guanghan 618300,China
  • Received:2014-09-19 Revised:2014-11-02 Online:2015-06-10 Published:2015-06-10

摘要:

页岩储层在成藏过程中具有含水的可能性,常规的物质平衡方程未考虑水溶气的影响。为此,基于页岩气藏地下储集空间体积平衡原理,将页岩储层划分为基质与裂缝2个系统,利用气体溶解度方程求解了甲烷在水中的溶解度,从而建立了考虑水溶气的页岩气藏物质平衡方程,并通过线性化处理,给出了页岩气藏储量计算的方法。实例计算表明,所建立的物质平衡方程直线相关系数更高,计算的储量结果高于未考虑水溶气时计算的储量,当页岩气藏产水时不能忽视水溶气对页岩储量的影响。

关键词: 页岩气, 水溶气, 物质平衡方程, 储量计算

Abstract:

During the formation process of shale gas reservoirs,there are possibilities to contain water in the formation.However,conventional material balance equations for calculating shale gas reserves rarely consider the influence of water soluble gas.Therefore,a modified material balance equation should be studied for rational prediction of shale gas reserves.Based on the principle of volumetric balance in the formation,the shale gas reservoir was divided into two types,the one with matrix and the one with fracture.With the aid of gas solubility equation,the solubility for methane in the formation water was achieved under different formation pressures.Eventually,a modified material balance equation was established taking into the consideration of water soluble gas and the method for calculating reserves was achieved by means of linearizing the modified equation at the same time.Case study shows that the correlation coefficients of the line regressed by the new model is higher than that regressed by a conventional model in the literature.What′s more,the reserve calculated by the method presented in this article is a bit higher than that predicted by the method in the literature,which can be explained by the ignorance of water soluble gas.In conclusion,the water soluble gas is also an existing gas form of shale gas reservoirs that cannot be neglected during the process of establishing a more reliable material balance equation and better prediction of reserves.

Key words: Shale gas, Water soluble gas, Material balance equation, Reserves calculation

中图分类号: 

  • TE155

[1]Qiu Zhen,Zou Caineng,Li Jianzhong,et al.Unconventional petroleum resources assessment:Progress and future prospects[J].Natural Gas Geoscience,2013,24(2):238-246.[邱振,邹才能,李建忠,等.非常规油气资源评价进展与未来展望[J].天然气地球科学,2013,24(2):238-246.]
[2]Hu Wenrui,Zhai Guangming,Li Jingming.Potential and development of unconventional hydrocarbon resources in China[J].Engineering Sciences,2010,12(5):25-29.[胡文瑞,翟光明,李景明.中国非常规油气的潜力和发展[J].中国工程科学,2010,12(5):25-29.]
[3]Li Yanli.Calculation methods of shale gas reserves[J].Natural Gas Geoscience,2009,20(3):466-470.[李艳丽.页岩气储量计算方法探讨[J].天然气地球科学,2009,20(3):466-470.]
[4]King G R.Material balance techniques for coal seam and Devonian shale gas reservoirs with limited water influx[J].SPE Reservoir Engineering,1993,8(1):67-72.
[5]Moghadam S,Jeje O,Matter L.Advanced gas material balance in simplified format[J].Journal of Canadian Petroleum Technology,2010,50(1):90-98.
[6]Liu Tiecheng,Tang Hai,Liu Pengchao,et al.Material balance equation and reserve calculation method of fractured and closed shale-gas reservoir[J].Natural Gas Exploration & Development,2011,34(2):28-30.[刘铁成,唐海,刘鹏超,等.裂缝性封闭页岩气藏物质平衡方程及储量计算方法[J].天然气勘探与开发,2011,34(2):28-30.]
[7]Wang Delong,Guo Ping,Chen Heng,et al.Derivation of new material balance equation for adsorbed gas reservoir and reserve estimation[J].Lithology Reservoirs,2012,24(2):83-86.[王德龙,郭平,陈恒,等.新吸附气藏物质平衡方程推导及储量计算[J].岩性油气藏,2012,24(2):83-86.]
[8]Zhang Liehui,Chen Guo,Zhao Yulong,et al.A modified material balance equation for shale gas reservoirs and a calculation method of shale gas reserves[J].Natural Gas Industry,2013,33(12):66-70.[张烈辉,陈果,赵玉龙,等.改进的页岩气藏物质平衡方程及储量计算方法[J].天然气工业,2013,33(12):66-70.]
[9]Wang Feiyu,He Zhiyong,Meng Xiaohui,et al.Occurrence of shale gas and prediction of original gas in-place(OGIP)[J].Natural Gas Geoscience,2011,22(3):501-510.[王飞宇,贺志勇,孟晓辉,等.页岩气赋存形式和初始原地气量(OGIP)预测技术[J].天然气地球科学,2011,22(3):501-510.]
[10]Li Taiwei,Guo Hekun,Li Haibo,et al.Research on movable fluids in shale gas reservoirs with NMR technology[J].Special Oil and Gas Reservoir,2012,19(1):107-109.[李太伟,郭和坤,李海波,等.应用核磁共振技术研究页岩气储层可动流体[J].特种油气藏,2012,19(1):107-109.]
[11]Jiang Wenli,Zhao Suping,Zhang Jinchuan,et al.Comparison of controlled factors for coalbed methane and shale gas accumulation[J].Natural Gas Geoscience,2010,21(6):1057-1060.[姜文利,赵素平,张金川,等.煤层气与页岩气聚集主控因素对比[J].天然气地球科学,2010,21(6):1057-1060.]
[12]Qin Yong,Song Quanyou,Fu Xuehai.Discussion on reliability for co-coming the coalbed gas and normal petroleum and natural gas:Absorptive effect of deep coal reservoir under condition of balanced water[J].Natural Gas Geoscience,2005,16(4):492-498.[秦勇,宋全友,傅雪海.煤层气与常规油气共采可行性探讨——深部煤储层平衡水条件下的吸附效应[J].天然气地球科学,2005,16(4):492-498.]
[13]Chen Zuo,Xue Chengjin,Jiang Tingxue,et al.Proposals for the application of fracturing by stimulated reservoir volume(SRV)in shale gas wells in China[J].Natural Gas Industry,2010,30(10):30-32.[陈作,薛承瑾,蒋廷学,等.页岩气井体积压裂技术在我国的应用建议[J].天然气工业,2010,30(10):30-32.]
[14]Gao Shusheng,Hu Zhiming,Guo Wei,et al.Water absorption characteristics of gas shale and the fracturing fluid flowback capacity[J].Natural Gas Industry,2013,33(12):71-76.[高树生,胡志明,郭为,等.页岩储层吸水特征与返排能力[J].天然气工业,2013,33(12):71-76.]
[15]Engelder T,Cathles L M,Bryndzia L T.The fate of residual treatment water in gas shale[J].Journal of Unconventional Oil and Gas Resources,2014,(7):33-48.
[16]Zhou Qin,Tian Hui,Chen Guihua,et al.Geological model of dissolved gas in pore water of gas shale and its controlling factors[J].Journal of China Coal Society,2013,14(1):11-14.[周秦,田辉,陈桂华,等.页岩孔隙水中溶解气的主控因素与地质模型[J].煤炭学报,2013,14(1):11-14.]
[17]Han Hui,Li Dahua,Ma Yong,et al.The original of marine shale gas in the northeastern Sichuan Basin,China:Implications from chemical composition and stable carbon isotope of desorbed gas[J].Acta Petrolei Sinica,2013,34(3):453-459.[韩辉,李大华,马勇,等.四川盆地东北地区下寒武统海相页岩气成因:来自气体组分和碳同位素组成的启示[J].石油学报,2013,34(3):453-459.]
[18]Ambrose R J,Hartman R C,Diaz-Campos,et al.New Pore-scale Considerations for Shale Gas in Place Calculations[R].SPE 131772,2010:23-25.
[19]Cao Tingkuan,Duan Yonggang,Wang Rong,et al.Evaluation of shale gas reserves considering multi-component adsorption[J].Reservoir Evaluation and Development,2011,1(6):68-70.[曹廷宽,段永刚,王荣,等.考虑多组分吸附的页岩气储量计算[J].油气藏评价与开发,2011,1(6):68-70.]
[20]Langmuir I.The adsorption of gases on plane surfaces of Glass,Mica and Platinum[J].Journal of American Chemical Society,1918,40(9):1361-1370.
[21]Guo Ping,Ou Zhipeng.Material balance equation of a condensate gas reservoir considering water soluble gas[J].Natural Gas Industry,2013,33(1):70-74.[郭平,欧志鹏.考虑水溶气的凝析气藏物质平衡方程[J].天然气工业,2013,33(1):70-74.]
[22]Zhang Zhanguo,Bian Congsheng.Category features of water-soluble gas and main controlling factors for its accumulation[J].Natural Gas Geoscience,2008,19(6):876-881.[张占国,卞从胜.水溶气的类型特征及成藏的主控因素探讨[J].天然气地球科学,2008,19(6):876-881.]
[23]Hao Shisheng,Zhang Zhenying.The characteristic of the solubility of natural gas in formation waters and it′s geological significance[J].Acta Petrolei Sinica,1993,14(2):12-22.[郝石生,张振英.天然气在地层水中的溶解度变化特征及地质意义[J].石油学报,1993,14(2):12-22.]
[24]Fu Xiaotai,Lu Shuangfang,Wang Zhenping,et al.Dissolving character for the components of natural gas and its significance[J].Geochimica,1997,26(3):60-66.[付晓泰,卢双舫,王振平,等.天然气组分的溶解特征及其意义[J].地球化学,1997,26(3):60-66.]
[25]Fan Hongche,Huang Zhilong,Yuan Jian,et al.Solubility experiment of methane-rich gas and features of segregation and accumulation[J].Journal of Jilin University:Earth Science Edition,2011,41(4):1033-1039.[范泓澈,黄志龙,袁剑,等.富甲烷天然气溶解实验及水溶气析离成藏特征[J].吉林大学学报:地球科学版,2011,41(4):60-66.]
[26]Su Zheng,Chen Duofu,Feng Dong,et al.Phase equilibrium of gas hydrate system and calculation of methane solubility[J].Progress in Geophysics,2007,22(1):239-246.[苏正,陈多福,冯东,等.天然气水合物体系的相平衡及甲烷溶解度计算[J].地球物理学进展,2007,22(1):239-246.]
[27]Fu Xiaotai,Wang Zhenping,Lu Shuangfang.Mechanism of gas dissolving in water and the dissolving equation[J].Science in China:Series B,1996,26(2):124-130.[付晓泰,王振平,卢双舫.气体在水中的溶解机理及溶解度方程[J].中国科学:B辑,1996,26(2):124-130.]
[28]Fu Xiaotai,Wang Zhenping,Lu Shuangfang,et al.Mechanism of natural gas dissolving in brines and the dissolving equation[J].Acta Petrolei Sinica,2000,21(3):89-94.[付晓泰,王振平,卢双舫,等.天然气在盐溶液中的溶解机理及溶解度方程[J].石油学报,2000,21(3):89-94.]

[1] 赵文韬,荆铁亚,吴斌,周游,熊鑫. 断裂对页岩气保存条件的影响机制——以渝东南地区五峰组—龙马溪组为例[J]. 天然气地球科学, 2018, 29(9): 1333-1344.
[2] 夏鹏,王甘露,曾凡桂,牟雨亮,张昊天,刘杰刚. 黔北地区牛蹄塘组高—过成熟页岩气富氮特征及机理探讨[J]. 天然气地球科学, 2018, 29(9): 1345-1355.
[3] 秦胜飞,李金珊,李伟,周国晓,李永新. 川中地区须家河组水溶气形成及脱气成藏有利地质条件分析[J]. 天然气地球科学, 2018, 29(8): 1151-1162.
[4] 康毅力,豆联栋,游利军,陈强,程秋洋. 富有机质页岩增产改造氧化液浸泡离子溶出行为[J]. 天然气地球科学, 2018, 29(7): 990-996.
[5] 曾凡辉,王小魏,郭建春,郑继刚,李亚州,向建华. 基于连续拟稳定法的页岩气体积压裂水平井产量计算[J]. 天然气地球科学, 2018, 29(7): 1051-1059.
[6] 朱维耀,马东旭. 页岩储层有效应力特征及其对产能的影响[J]. 天然气地球科学, 2018, 29(6): 845-852.
[7] 余川,曾春林,周洵,聂海宽,余忠樯. 大巴山冲断带下寒武统页岩气构造保存单元划分及分区评价[J]. 天然气地球科学, 2018, 29(6): 853-865.
[8] 邱 振,邹才能,李熙喆,王红岩,董大忠,卢斌,周尚文,施振生,冯子齐,张梦琪. 论笔石对页岩气源储的贡献——以华南地区五峰组—龙马溪组笔石页岩为例[J]. 天然气地球科学, 2018, 29(5): 606-615.
[9] 汪道兵,葛洪魁,宇波,文东升,周珺,韩东旭,刘露. 页岩弹性模量非均质性对地应力及其损伤的影响[J]. 天然气地球科学, 2018, 29(5): 632-643.
[10] 龙胜祥,冯动军,李凤霞,杜伟. 四川盆地南部深层海相页岩气勘探开发前景[J]. 天然气地球科学, 2018, 29(4): 443-451.
[11] 贺领兄,宋维刚,安生婷,徐永锋,沈娟,路超,王军. 青海东昆仑地区八宝山盆地烃源岩有机地球化学特征与页岩气勘探前景[J]. 天然气地球科学, 2018, 29(4): 538-549.
[12] 邢 舟,曹高社,毕景豪,周新桂,张交东. 南华北盆地禹州地区ZK0606钻孔上古生界煤系烃源岩评价[J]. 天然气地球科学, 2018, 29(4): 518-528.
[13] 秦胜飞,周国晓. 气田水对甲烷氢同位素分馏作用[J]. 天然气地球科学, 2018, 29(3): 311-316.
[14] 王怒涛,陈仲良,祝明谦,王玉根,张琰. 基于质量守恒原理的凝析气藏单井动态储量计算[J]. 天然气地球科学, 2018, 29(3): 424-428.
[15] 卢文涛,李继庆,郑爱维,梁榜,张谦,杨文新. 涪陵页岩气田定产生产分段压裂水平井井底流压预测方法[J]. 天然气地球科学, 2018, 29(3): 437-442.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!