天然气地球科学 ›› 2020, Vol. 31 ›› Issue (9): 12611270.doi: 10.11764/j.issn.1672-1926.2020.05.020
薛培1,2(),张丽霞1,2(),梁全胜1,2,师毅3,曹成1,2,汤延帅4
Pei XUE1,2(),Li-xia ZHANG1,2(),Quan-sheng LIANG1,2,Yi SHI3,Cheng CAO1,2,Yan-shuai TANG4
摘要:
为完善页岩等量吸附热计算方法,明确页岩吸附超临界CH4的热力学特征,选用温度区间为26.85~199.85 ℃、压力范围为0.08~14 MPa的页岩等温吸附数据,系统检验常用吸附相密度计算方法的合理性,并基于绝对吸附量分析等量线标绘法的适用范围及页岩等量吸附热特征。结果表明:①经检验,常用的吸附相密度计算方法中Ozawa经验公式法适用于较宽温压范围内的绝对吸附量校正;②Lnp-1/T曲线在温度区间为149.85~199.85 ℃且nab为0.103 8~0.280 0 mmol/g时不具有线性特征,因此该温度及吸附量范围内等量线标绘法不再适用,同时Lnp-1/T曲线的nab取值应当与Lnp-nab曲线保持一致,以此获得的等量吸附热曲线才能全面地反映吸附过程的热力学特征;③页岩吸附超临界CH4的等量吸附热随着吸附量的增加呈现先增大后减小的非单调变化,表明在吸附早期,CH4分子间的相互作用力对等量吸附热的影响占主导,当吸附量增加到一定程度后,页岩表面的非均一性占主导。
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